W.c. Heraeus Gmbh

Heraeus Elektroden Gmbh

Theo Muller

Peter Fabian

A composite electrode comprising an electroconductive base with an electrolyte inert, electroconductive electrocatalytic layer applied by thermal spraying, the said layer being a powder of a matrix material selected from the group consisting of oxides, nitrides, phosphides, silicides, borides and carbides of a metal selected from the group consisting of boron, valve metals and iron group metals having uniformly deposited thereon electrocatalytically active particles of a metal selected from the group consisting of platinum group metals and iron group metals and oxides thereof with a particle size smaller by at least one order of magnitude of the matrix particles and electrolytic cells containing the same and electrolytic processes using the same.

Novel electrode

A roto-gravure printing base cylinder is made by providing a cylindrical body (1), for example of steel, and applying thereover a cover layer (2) by thermal spraying, for example plasma-spraying, or arc-spraying. The cover layer is made of a material which is inert with respect to electrolytes used in applying a further copper layer over the cover layer to form a finished roto-gravure cylinder for optical engraving, for example an electrochemical valve metal, preferably tantalum, niobium or, most desirably, titanium oxide, forming a matrix in which, before application of the material as a layer on the steel cylinder, electrochemically active materials are applied made of a metal, preferably of the platinum group or other noble metal, and uniformly distributed over the surface, settled on the matrix material.

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Wuustwezel, Belgium

Theo Muller