Bridgestone Corporation

Other

Tetsuya Omura

Yoichi Ozawa

Takuo Sone

Iwakazu Hattori

Tatsuo Fujimaki

Koichi Morita

Koji Masaki

H Jerrold Miller

Eiju Suzuki

Uchu Mukai

Kouichi Morita

In general the present invention provides a functionalized polymer prepared by a process comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with a functionalizing agent defined by the formula (I)A-R&#x2014;Z&#x2003;&#x2003; (I)where Ris a divalent bond or divalent organic group comprising from 0 to about 20 carbon atoms, A is a substituent that will undergo an addition reaction with a pseudo-living polymer, and Z is a substituent that will react or interact with silica or carbon black reinforcing fillers, with the proviso that A, R, and Z are substituents that will not protonate a pseudo-living polymer.

[object Object]

A method for preparing a functionalized polymer comprising the steps of preparing a polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, wherein the lanthanide-based catalyst comprises (a) a lanthanide compound, (b) an alkylating agent, and (c) a source of halogen, and reacting the pseudo-living polymer with at least one amide-containing functionalizing agent.

The present invention relates to an activated silane compound obtained by reacting a hydrocarbyloxysilane compound with an organic metal compound in an organic solvent, and enhancing interaction of silica with carbon black and improving the fracture characteristic, the abrasion resistance and the low heating property provide an activated silane compound which can be reduced in a blending amount, a rubber composition prepared by blending it as a silane coupling agent and a pneumatic tire prepared by using the above rubber composition, which is excellent in a durability, a low heating property and the like.

Activated silane compound, rubber composition using the same and tire

The present invention provides a modified polymer, which is obtained by reacting, with an active metal bonded to a polymer, a modifier represented by the general formula (I) (where Xto Xeach represent a hydrogen atom or a specific monovalent functional group, and at least one of those is other than a hydrogen atom, Rto Reach represent a single bond or a divalent hydrocarbon group having 1 to 18 carbon atoms, and a plurality of aziridine rings may be bonded through any of Xto Xand Rto R). More particularly, the present invention provides a novel modified polymer which has excellent interaction with carbon black and enables improvement in dispersibility of the carbon black when used in a rubber composition blended with the carbon black, a rubber composition containing the modified polymer and capable of providing a tire excellent in low heat generating property, rupture characteristics, and abrasion resistance, and a tire made of the rubber composition and having the above-mentioned characteristics.

Modified polymer, rubber composition, and tire

A functionalized polymer prepared by a process comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with a functionalizing agent defined by the formula (I)A-R-Z&#x2003;&#x2003;(I)where Ris a divalent bond or divalent organic group comprising from 0 to about 20 carbon atoms, A is a substituent that will undergo an addition reaction with a pseudo-living polymer, and Z is a substituent that will react or interact with silica or carbon black reinforcing fillers, with the proviso that A, R, and Z are substituents that will not protonate a pseudo-living polymer.

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Kodaira, Japan

Tetsuya Omura