Dic Corporation

Dainippon Ink and Chemicals, Incorporated

Nippon Paper Industries Co., Ltd.

Seiko Pmc Corporation

Tetsuya Harada

Jianye Jiang

Kenichi Hamada

Takahito Ikuma

Takashi Yasumura

Takeshi Yamazaki

Mitsuyuki Kanzaki

Takashi Kawamura

Akihiro Sato

Takayuki Miki

Takayuki Kanematsu

Takashi Tomiyama

Satoshi Katano

Toshiya Kato

Masakazu Yoshizawa

Mari Minowa

Kazuya Miyamoto

Hironobu Takizawa

Tetsuya Yamazaki

Provided herein is a cellulose nanofiber-containing composition producing method for producing a cellulose nanofiber-containing composition that can be easily combined with compounds having a reactive double-bond group, and that contains only a small amount of uncured material that acts as a plasticizer in a molded product, using a simple producing method that does not require any process involving solvent displacement or solvent removal. A high-strength molded body prepared by using the cellulose nanofiber-containing composition is also provided. In refining cellulose in a mixture containing a compound having a reactive double-bond group and a hydroxyl group of 10 KOHmg/g or less and a defibrating resin as essential components, the cellulose has a moisture content of 4 to 25 parts by mass with respect to 100 parts by mass of the amount of the cellulose converted on the assumption that the percentage moisture of the cellulose is 0%.

Molded body and method for producing cellulose-nanofiber-containing resin composition

Provided herein is a cellulose nanofiber that can be easily combined with a compound having a reactive double-bond group and that can provide a molded article which contains only a small amount of an uncured material that acts as a plasticizer in a molded product, using a simple producing method that does not require any process involving solvent displacement or solvent removal. A high-strength resin composition or molded body prepared by using the cellulose nanofiber is also provided. In refining cellulose in the presence of a compound having a reactive double bond and a hydroxyl value of 200 KOHmg/g or more, the cellulose has a moisture content of 4 to 25 parts by mass with respect to 100 parts by mass of the amount of the cellulose converted on the assumption that the percentage moisture of the cellulose is 0%.

Molded body and method for producing cellulose-nanofiber-containing composition

The present invention provides a method for producing cellulose nanofibers, the method including fibrillating cellulose in a modified epoxy resin (A) having a hydroxyl value of 100 mgKOH/g or more. Also, the present invention provides cellulose nanofibers produced by the production method and a master batch containing the cellulose nanofibers and the modified epoxy resin (A). Further, present invention provides a resin composition containing the master batch and a curing agent (D), and provides a molded product produced by molding the resin composition.

Method for producing cellulose nanofiber, cellulose nanofiber, master batch, and resin composition

The present invention relates to modified cellulose nanofibers obtained by neutralizing cationic groups of cationic cellulose nanofibers with an anionic additives. Moreover, the present invention relates to a resin composition containing the aforementioned modified cellulose nanofibers and a molding resin, and to a molded body obtained by molding the resin composition. Furthermore, the present invention relates to a production method of modified cellulose nanofibers comprising neutralizing cationic groups of cationic cellulose nanofibers with an anionic additives.

Modified cellulose nanofibers, production method thereof, and resin composition using same

The present invention provides a method for manufacturing a cellulose nanofiber, characterized by comprising the step of fibrillating cellulose in a polyester based resin, preferably in a polyester based resin having an ester group concentration of 6.0 mmol/g or more and a cellulose nanofiber produced by the manufacturing method concerned. In addition, the present invention provides a masterbatch composition containing the cellulose nanofibers and the polyester based resin. Furthermore, the present invention provides a resin composition containing the masterbatch composition and a diluent resin and a processed product thereof.

Method for fibrillating cellulose, cellulose nanofiber, masterbatch, and resin composition

A modified microfibrillated cellulose, a resin composition and a resin composite material that contain the modified microfibrillated cellulose are provided. In a modified microfibrillated cellulose according to the present invention, a hydrolyzable-silyl-group-containing resin (A) bonds to or adheres to a cellulose surface and a silicon atom content is 0.01 to 0.5 atomic percent. A resin composition containing 0.1% to 10% by weight of the modified microfibrillated cellulose is also provided.

Modified microfibrillated cellulose and resin composite material containing the same

The present invention provides a separator for a fuel cell comprising a resin and a conductive material as constituting components, and sulfonic acid groups imparted to at least one portion at the surface of gas channels by a treatment using a sulfuric acid-containing gas, wherein the resin and the sulfonic acid groups, which are on the surface of the gas channels, are bonded, and a ratio of sulfur atoms in the sulfonic acid groups at the surface of the gas channels as determined by energy-dispersive X-ray spectroscopy is in a range from 0.1 to 4.0 at %, and a method for producing the separator. The separator for a fuel cell of the present invention is excellent in the wettability to water, since sulfonic acid groups are imparted to the resin at the surface of gas channels in the sulfuric acid-containing gas.

Separator for fuel cell, method for producing the same, and fuel cell

The present invention offers sheet molding material for obtaining a thin fuel cell bipolar plate with excellent conductivity and thickness precision, production method thereof, and a fuel cell bipolar plate made by molding the sheet molding material. It relates to sheet molding material for a fuel cell bipolar plate and production method thereof, wherein the sheet molding material has carbon particle layer on at least one surface of the resin sheet, and the percentage of particles of carbon layer in the sheet molding material is 70% to 90% by weight.

Sheet molding material for fuel cell bipolar plate, method of producing same and bipolar plate or fuel cell

An object of the present invention is to provide a conductive resin composition which does not cause problems with regard to moldability such as occurrence of separation between a resin component and a conductive filler, voids and warp on molding, and is excellent in filling of a resin into a mold, and is also capable of being used for various electrical and electronic materials, including a separator for a fuel cell having excellent properties. To achieve the above object, the present invention provides a conductive resin composition comprising a conductive filler (A); a urethane-modified epoxy (meth)acrylate (B) obtained by reacting an epoxy (meth)acrylate (b-1), which is obtained by the addition reaction of an epoxy resin having an aromatic cyclic structural unit and/or an aliphatic cyclic structural unit and a (meth)acrylic acid, with a polyisocyanate (b-2); a (meth)acrylate (C) having a number average molecular weight of 500 to 10,000, which contains 20 to 80% by weight of an aromatic cyclic structural unit and/or an aliphatic cyclic structural unit and contains no active hydrogen atom; and the other ethylenically unsaturated monomer (D) which is copolymerizable with the urethane-modified epoxy (meth)acrylate (B) and the (meth)acrylate (C).

Conductive resin composition, process for production thereof, and fuel cell separators

A fuel cell bipolar plate has a front surface and a rear surface opposite to each other, and flash and a receding portion. The flash is provided on the front surface at an outer peripheral portion of the bipolar plate and projects in a direction crossing the front surface. The receding portion is provided on the rear surface at an outer peripheral portion of the bipolar plate in a geometry capable of accommodating flash.

Fuel cell bipolar plate, and fuel cell

A curable resin composition, which is a solid resin at ordinary temperatures obtained by reacting an epoxy resin with a (meth)acrylic anhydride, contains an unsaturated resin having a (meth)acryloyl group (A) which has a double bond equivalent weight of 200 to 500, an ester number of 100 to 300, and a hydroxyl number of no more than 130, an ethylenically unsaturated monomer (B), and a radical polymerization initiator (C).

Curable resin composition

A fuel cell bipolar plate that while retaining its mechanical strength, has its electrical conductivity enhanced; a process for producing the same; and a fuel cell including the bipolar plate. There is provided a fuel cell bipolar plate comprising laminated molded item formed by a sheet-shaped molding material, wherein the sheet-shaped molding material contains a resin and a carbon material, and wherein the laminated molded item has a laminate structure of, arranged in sequence, surface layer C/inner layer B/central layer A/inner layer B'/surface layer C&#x2032;, and wherein each of the central layer A, inner layer B, inner layer B&#x2032;, surface layer C and surface layer C&#x2032; consists of a single layer or multilayer of the sheet-shaped molding material, and wherein when the carbon material content of central layer A is referred to as a, the carbon material content of inner layer B as b, the carbon material content of inner layer B&#x2032; as b&#x2032;, the carbon material content of surface layer C as c and the carbon material content of surface layer C&#x2032; as c&#x2032;, there are satisfied the relationships 55&#x2266;a&#x2266;85, 55&#x2266;c&#x2266;85, 55&#x2266;c&#x2032;&#x2266;85, 10&#x2266;a&#x2212;b&#x2266;30, 10&#x2266;c&#x2212;b&#x2266;30, 10&#x2266;a&#x2212;b&#x2032;&#x2266;30 and 10&#x2266;c&#x2032;&#x2212;b&#x2032;&#x2266;30 (the unit of each of a, b, b&#x2032;, c and c&#x2032; is % by volume).

Growing community of inventors

Sakura, Japan

Tetsuya Harada