Mitsui Coke Co. Ltd.

Toyo Engineering Corporation

New Japan Chemical Co., Ltd.

Mitsui Mining Co., Ltd.

Mitsui Miike Machinery Co., Ltd.

Toko Kasei Ltd.

Tetsuo Wada

Toshiaki Kobayashi

Tomio Nobe

Shoichi Oi

Isao Kubo

Masao Sakurai

Shigemi Nagayoshi

Hiroshi Niimi

Futao Sakata

Disclosed herein is an improved method for continuous thermal cracking of heavy petroleum oil, which can achieve a high degree of cracking in a column-like reactor of relatively small size and provides residual pitch rich in .beta.-resin components and lean in gas mixed therein. The above method comprises charging preheated heavy oil into an upper reaction zone of an upright cylindrical continuous reactor, which is divided into upper and lower reaction zones by means of a partition plate, drawing the resultant cracked gas and oil vapor from the upper reaction zone, and discharging residual pitch through the bottom of the lower reaction zone. Also disclosed are a first improvement to the above thermal cracking method through the provision of a cooling chamber and a defoaming chamber adjacent to the lowermost portion of the reactor so as to respectively terminate the reaction and subject the resultant pitch to defoaming, and another improvement through the provision of a rotary scraper in the reactor, which scraper has blades contiguous to their corresponding reactor walls or partition plates.

Method for continuous thermal cracking of heavy petroleum oil

Disclosed is a process for the treatment of water-containing coal which comprises mixing the water-containing coal with a hydrocarbon oil having a specific gravity higher than that of water at temperatures in the range of 100.degree. to 350.degree. C.; heating the resulting mixture at a temperature in the range of 100.degree. to 350.degree. C. and a pressure not lower than the saturated vapor pressure of water at that temperature; and then allowing the heated mixture to settle at a temperature in the range of 100.degree. to 350.degree. C. and a pressure not lower than the saturated vapor pressure of water at that temperature, whereby an upper layer consisting of the water separated from the water-containing coal is formed on a lower layer consisting of the mixture of the dehydrated coal and the hydrocarbon oil.

Treatment of water-containing coal

The invention provides: a fuel composition comprising 100 parts by weight of a coal-liquid fuel mixture and 0.02 to 1.0 part by weight of at least one additive selected from the group consisting of dibenzylidene sorbitol, ditoluylidene sorbitol, tribenzylidene sorbitol, tritoluylidene sorbitol and hydrogenated castor oil; and a fuel composition comprising 100 parts by weight of a coal-liquid fuel mixture, 0.02 to 1.0 part by weight of at least one additive selected from the group consisting of dibenzylidene sorbitol, ditoluylidene sorbitol, tribenzylidene sorbitol, tritoluylidene sorbitol and hydrogenated castor oil, and 1 to 10 parts by weight of water. The composition shows high stability over a prolonged period of time, preventing the separation into layers of the components.

Fuel compositions comprising coal-liquid fuel mixture

Growing community of inventors

Oomuta, Japan

Tetsuo Wada