Stella Chemifa Corporation

Otsuka Chemical Co., Ltd.

Mitsubishi Chemical Corporation

Stella Chemifa Kabushiki Kaisha

Cataler Corporation

Tetsuo Nishida

Kazutaka Hirano

Megumi Tomisaki

Akihiro Nabeshima

Masashi Yamamoto

Sojiro Kon

Hiroaki Tokuda

Yasutaka Tashiro

Toshitaka Sakaguchi

Yoshifumi Katsura

Akinori Oka

Yoshinobu Abe

Kazuhiko Shogami

Takashi Fujii

Kenji Sato

Hideki Nakashima

Takashi Higono

Hirofumi Suzuki

Yoshinori Sato

Naoki Yahata

Hirohisa Kikuyama

Masahide Waki

Shinji Hashiguchi

Tomoya Satoh

Tetsuya Kume

Kenji Aoki

Kazuaki Yanagi

Rui Hasebe

Hitoshi Tsurumaru

Masanori Uraya

Shuichi Minamigawa

Megumi Tornisaki

Hiroya Yamamoto

Hiroaki Takatori

Shinya Kumazawa

Tetsuya Arakawa

Akira Ishimaru

Hironori Matsushita

Yoshinobu Sakakibara

Natsuki Mine

Akihiro c/o Otsuka Chemical Co Ltd Nabeshima

Hiroaki c/o Otsuka Chemical Co Ltd Tokuda

Provided are a liquid dispersion of fluoride particles, which has low viscosity and excellent dispersibility, and is suitable for producing an optical film such as an antireflection film; a method for producing the same; and an optical film using the same. The liquid dispersion of fluoride particles according to the present invention is that in which particles of a fluoride represented by the chemical formula ACF(wherein A represents sodium or potassium, C represents silicon or boron, x is 1 or 2, and y is 4 or 6) are dispersed in an aprotic organic solvent having a relative permittivity of 5 to 40, and the optical film according to the present invention is produced by using the liquid dispersion of fluoride particles.

Liquid dispersion of fluoride particles and method for producing same, and optical film

Provided are a nonaqueous electrolytic solution for a secondary battery that exhibits excellent cycle characteristics even in high temperature environment, and a secondary battery including the same. The nonaqueous electrolytic solution for a secondary battery of the present invention is a nonaqueous electrolyte solution for a secondary battery which is used for a secondary battery, including at least one component (A) represented by the following chemical formula (1):

Nonaqueous electrolyte solution for secondary battery, and secondary battery provided with said solution

To provide a novel immobilized product in which a carbon material and/or a silicon material is/are immobilized on a base material surface by a chemical bond via a linking group, and a method for producing the same. The immobilized product is an immobilized product in which a carbon material is immobilizing on a surface of a base material, wherein the carbon material is chemically bonded on the surface of the base material via a linking group, and the linking group is at least one selected from the group consisting of a —NH group, a —NH—R—NH group, a —SO group, a Rgroup, a —O—R—O group, and a Rgroup (in which the Rto Reach independently represent at least one selected from the group consisting of a chain alkyl group, a cyclic alkyl group, a chain alkenyl group, a cyclic alkenyl group, a chain alkynyl group, etc.).

Immobilized product and method for producing same

A red phosphor that has optical characteristics and durability under high-temperature and high-humidity environments, and a method for producing the same. The red phosphor includes a Mn-activated complex fluoride represented by the following general formula (1) and bismuth:A2MF6:Mn4+  (1)wherein A represents at least one alkali metal element selected from the group consisting of lithium, sodium, potassium, rubidium and cesium, and M represents at least one tetravalent element selected from the group consisting of silicon, germanium, tin, titanium, zirconium and hafnium.

Red phosphor and method for producing same

A fuel cell catalyst which has high power output characteristics and suppresses degradation of power generation performance due to starting, stopping or load variation; a manufacturing method thereof; a membrane electrode assembly for fuel cell; and a fuel cell including the same. The fuel cell catalyst includes at least catalytically active species and a carrier supporting the catalytically active species. The catalytically active species are at least one selected from the group consisting of platinum, a platinum alloy, and a core-shell catalyst in which a core of a metal different from platinum is coated with a shell containing platinum, the carrier is a carbon material, and at least one of the catalytically active species and the carrier contain(s) fluorine atoms.

Fuel cell catalyst, membrane electrode assembly for fuel cell, and fuel cell including the same

A non-aqueous electrolytic solution includes a phosphoric acid diester salt, which can suppress deterioration of charge-discharge characteristics of a power storage element, and can suppress the rise in internal resistance after storage at high temperature. The phosphoric acid diester salt is represented by the following chemical formula (1): in which Mrepresents a hydrogen ion, an alkali metal ion, an alkali earth metal ion, an aluminum ion, a transition metal ion, or an onium ion, Rand Rare different from each other and represent a hydrocarbon group having 1 to 10 carbon atoms, or a hydrocarbon group having 1 to 10 carbon atoms and having at least one of a halogen atom, a heteroatom, and an unsaturated bond, and n represents a valence.

Non-aqueous electrolytic solution for power storage element

A nonaqueous electrolytic solution for a secondary battery exhibits excellent cycle characteristics even in high-temperature environments. The solution includes at least one of boric acid esters, acid anhydrides, cyclic carbonates having an unsaturated bond, cyclic carbonates having a halogen atom, cyclic sulfonic acid esters, and amines having an acetoacetyl group. A secondary battery having a positive electrode and a negative electrode makes use of this electrolytic solution.

Nonaqueous electrolyte solution for secondary batteries and secondary battery provided with same

A phosphodiester salt is added to the electrolytic solution to form a nonaqueous electrolytic solution for a secondary battery. The nonaqueous electrolytic solution has excellent storage characteristics in a temperature load environment. Deterioration of the charge-discharge characteristics of the nonaqueous electrolytic solution and increase in internal resistance of the nonaqueous electrolytic solution are suppressed during storage. A secondary battery having a positive electrode and a negative electrode makes use of this electrolytic solution.

Disclosed is a phosphoric acid diester salt which can suppress deterioration of charge-discharge characteristics of a power storage element, and can suppress the rise in internal resistance after storage at high temperature, a production method therefor, a non-aqueous electrolytic solution for a power storage element, and a power storage element. Disclosed is a phosphoric acid diester salt represented by the following chemical formula (1): wherein Mrepresents a hydrogen ion, an alkali metal ion, an alkali earth metal ion, an aluminum ion, a transition metal ion, or an onium ion; Rand Rare different from each other and represent a hydrocarbon group having 1 to 10 carbon atoms, or a hydrocarbon group having 1 to 10 carbon atoms and having at least one of a halogen atom, a heteroatom, and an unsaturated bond; and n represents a valence.

Phosphoric acid diester salt, production method therefor, non-aqueous electrolytic solution for power storage element, and power storage element

Provided is a method for purifying a difluorophosphate, in which a difluorophosphate is purified to a high purity. The method includes a method for purifying a difluorophosphate, comprising bringing hydrogen fluoride into contact with a difluorophosphate containing an impurity and subsequently heating and drying the difluorophosphate, or bringing the hydrogen fluoride into contact with the difluorophosphate containing the impurity while heating and drying the difluorophosphate containing the impurity, thereby removing the impurity.

Method for purifying difluorophosphate

Provided is a method for producing a difluorophosphate, which can easily and industrially advantageously produce a high-purity difluorophosphate. The method includes a step of producing a difluorophosphate in the fluorophosphoric acid solution by reacting hydrofluoric acid anhydride containing no solvent with an oxoacid and/or the like of phosphorous to produce a fluorophosphoric acid solution; a step of adding a hexafluorophosphate to the fluorophosphoric acid solution in the absence of respective halides, carbonates, borates, phosphates, hydroxides, and oxides of an alkali metal and the like; and a step of heating and drying the fluorophosphoric acid solution containing the difluorophosphate to distill away a fluorophosphoric acid, or a step of depositing the difluorophosphate in the fluorophosphoric acid solution by crystallization, subsequently separating the difluorophosphate by solid-liquid separation, and distilling away a fluorophosphoric acid contained in the difluorophosphate after the solid-liquid separation.

Method for producing difluorophosphate

A process for preparing difluorophosphate comprising reacting difluorophosphoric acid with at least one salt, as a raw material, selected from a halide salt, a carbonate, a phosphate, a hydroxide and an oxide of an alkali metal, an alkaline earth metal or an onium in the difluoraphosphoric acid, then separating a precipitate from the difluorophosphoric acid by solid-liquid separation, the precipitate being precipitated by crystallization operation in the difluorophosphoric acid, and removing the difluorophosphoric acid contained in the precipitate by distillation to obtain difluorophosphate.

Provided is a method for producing a difluorophosphate, which can simply and easily produce a high-purity difluorophosphate in an industrially advantageous manner. The method includes steps of: reacting an aqueous hydrofluoric acid solution with an oxyhalide of phosphorous (except phosphoric trifluoride) to produce a crude difluorophosphoric acid; reacting the crude difluorophosphoric acid with a halide of an alkali metal, an alkaline earth metal, aluminum or an onium to produce a difluorophosphate in the crude difluorophosphoric acid; and heating and drying the crude difluorophosphoric acid containing the difluorophosphate to distill away the crude difluorophosphoric acid, or precipitating the difluorophosphate in the crude difluorophosphoric acid by crystallization, subsequently separating the difluorophosphate by solid-liquid separation, and further distilling away the crude difluorophosphoric acid contained in the difluorophosphate after solid-liquid separation.

To provide a technique for simply and easily producing a high-purity difluorophosphate and provide a production process of an electrolytic solution using the obtained difluorophosphate, an electrolytic solution and a secondary battery. A process for producing a difluorophosphate, comprising the following step (1) or (2): Also, a nonaqueous electrolytic solution containing the obtained difluorophosphate, and a nonaqueous electrolytic secondary battery containing the nonaqueous electrolytic solution.

Production process of difluorophosphate, nonaqueous electrolytic solution and nonaqueous electrolytic secondary battery

Growing community of inventors

Osaka, Japan

Tetsuo Nishida