Nippon Kayaku Kabushiki Kaisha

Other

Teruhisa Inoue

Koichiro Shigaki

Masaaki Ikeda

Masayoshi Kaneko

Takayuki Hoshi

Akira Maenosono

Shozo Yanagida

Tsutomu Namiki

Disclosed is a photoelectric conversion device wherein a methine dye represented by the formula (1) below is supported by a thin film of oxide semiconductor particles arranged on a substrate. Also disclosed is a solar cell manufactured by using such a photoelectric conversion device.  (In the formula (1), n represents an integer of 0-5; m represents an integer of 0-5; R-Rindependently represent a hydrogen atom, an optionally substituted aromatic residue, an optionally substituted aliphatic hydrocarbon residue or the like; X and Y independently represent a hydrogen atom; an optionally substituted aromatic residue, an optionally substituted aliphatic hydrocarbon residue or the like; Z represents an oxygen atom, a sulfur atom or the like; A, A, A, Aand Aindependently represent a hydrogen atom, an optionally substituted aromatic residue, an optionally substituted aliphatic hydrocarbon residue or the like; and rings a, b and c may be substituted.).

Dye-sensitized photoelectric conversion device

Disclosed is a dye-sensitized photovoltaic device in which a metal complex dye represented by Formula (1), or a salt thereof, is carried on a thin film of oxide semiconductor micrograins disposed on a substrate. (In Formula (1), mrepresents an integer from 1 to 2 and nrepresents an integer from 1 to 3. Xrepresents an oxygen atom or sulfur atom. Yand Yeach independently represent a thiocyanate group (&#x2014;SCN) or isothiocyanate group (&#x2014;NCS). Mand Mrepresent hydrogen atoms. Rand Rrepresent hydrogen atoms. Rand Reach independently represent a straight-chain alkyl group with 1 to 6 carbons. Further, when mis 2 and there are multiple of each of Rand R, each of Rand Rmay be the same as or different from one another.)

Dye-sensitized photovoltaic device comprising a ruthenium metal complex

A photoelectric conversion device using a semiconductor fine material such as a semiconductor fine particle sensitized with a dye carried thereon, characterized in that the dye is a methine type dye having a specific partial structure, for example, a methine type dye having a specific carboxyl-substituted hetero ring on one side of a methine group and an aromatic residue substituted with a dialkylamino group or an organic metal complex residue on the other side of the methine group, or a methine type dye having a carboxyl-substituted aromatic ring on one side of a methine group and a heteroaromatic ring having a dialkylamino group or an organic metal complex residue on the otherside of the methine group; and a solar cell using the photoelectric conversion element. The photoelectric conversion element exhibits a conversion efficiency comparable or superior to that of a conventionally known photoelectric conversion element sensitized with a methine type dye.

A photoelectric conversion device using a semiconductor fine material such as a semiconductor fine particle sensitized with a dye carried thereon, characterized in that the dye is a methine type dye having a specific partial structure, for example, a methine type dye having a specific carboxyl-substituted hetero ring on one side of a methine group and an aromatic residue substituted with a dialkylamino group or an organic metal complex residue on the other side of the methine group, or a methine type dye having a carboxyl-substituted aromatic ring on one side of a methine group and a heteroaromatic ring having a dialkylamino group or an organic metal complex residue on the other side of the methine group; and a solar cell using the photoelectric conversion element. The photoelectric conversion element exhibits a conversion efficiency comparable or superior to that of a conventionally known photoelectric conversion element sensitized with a methine type dye.

The present invention relates to an organic dye-sensitized photoelectric conversion device and a solar cell utilizing the same. In accordance with a demand to now for development of an organic dye-sensitized photoelectric conversion device with high conversion efficiency and high practicability using an inexpensive dye, there is provided in the present invention, a photoelectric conversion device with high conversion efficiency by producing a photoelectric conversion device by sensitizing fine semiconductor particles with a methine dye having specified skeleton.

Disclosed is a photoelectric conversion device comprising a first conductive support having a layer containing a semiconductor, a second conductive support arranged opposite to the first conductive support and having a counter electrode, and a charge transfer layer interposed between the first conductive support and the second conductive support at a certain distance from the supports, and a sealing agent which is arranged around the charge transfer layer in the form of a single or more than single layer for bonding the first conductive support and the second conductive support together.

Dye-sensitized photoelectric conversion device and method for manufacturing same

The present invention relates to photoelectric conversion devices, characterized by using oxide semiconductor particles sensitized with a methine dye represented by the Formula (1): (KA 1) (in the Formula (1), m represents 1 to 4; n1 represents 1 to 7; p1 represents 1 to 4; X1 represents an optionally substituted aromatic residue, an optionally substituted aliphatic hydrocarbon residue, a cyano group, a phosphoric acid group, a sulfonic acid group, or a carboxyl group, a carbonamide group, and the like; L1 represents an optionally substituted aromatic residue and the like; A1 and A2 each independently represent an optionally substituted aromatic residue, a hydroxyl group, a phosphoric acid group, a cyano group, a hydrogen atom, a halogen atom and the like; the ring a1 has 1 or a plurality of halogen atoms, amide groups, hydroxyl groups, cyano groups, nitro groups, alkoxy groups, acyl groups and the like.), and solar cells made by using the same. The devices and the cells are characterized by relatively low cost, high stability, and high photoelectric conversion efficiency.

Dye-sensitized photoelectic conversion devices

The present invention relates to a photoelectric conversion device sensitized by supporting a methine based dye represented by the following formula (1): (in the above formula, n represents an integer of 0 to 7; X and Y each represent a hydrogen atom, an optionally substituted aromatic residue, an optionally substituted aliphatic hydrocarbon residue and the like. In addition, X and Y may combine together to form an optionally substituted ring. A, Aand Arepresent each independently an optionally substituted aromatic residue, an optionally substituted aliphatic hydrocarbon residue and the like. In addition, when n is other than 0, a plural number of Aand/or Aand/or Amay form an optionally substituted ring. The benzene ring 'a' may have substituent selected from a halogen atom, an amide group, a hydroxyl group, a cyano group and the like);on a thin film of oxide semiconductor fine particles provided on a substrate, and has features that the device can be manufactured at low cost and has high conversion efficiency.

The invention relates to a photoelectric conversion device, using oxide semiconductor fine particles sensitized with a methine dye represented by the following formula (1) and a solar cell using the same, and a solar cell high in conversion efficiency can be obtained at low cost: in the formula (1), n represents an integer of 0 to 7; Rrepresents an optionally-substituted aromatic residue or optionally-substituted aliphatic hydrocarbon residue, or an acyl group; X represents an optionally-substituted hydrocarbon residue which has 2 to 4 carbon atoms; Y represents a hydrogen atom, an optionally-substituted aromatic residue or aliphatic hydrocarbon residue, a carboxyl group or the like, and preferably represents a carboxyl group; Z represents an optionally-substituted aromatic residue or aliphatic hydrocarbon residue, or an acyl group; A, Aand Aeach independently represent a hydrogen atom, an optionally-substituted aromatic residue or aliphatic hydrocarbon residue or the like, and preferably represent a hydrogen atom; and a benzene ring a may have substituent(s) other than those shown in the above formula.

A sealing agent for a photoelectric conversion device which comprises one or more of a compound having a glycidyl structure, a compound having a cyclohexene oxide structure, a compound having an oxetane structure and a compound having a vinyl ether structure, and a cationic polymerization initiator; a photoelectric conversion device using the sealing agent; and a solar cell comprising the photoelectric conversion device. The sealing agent for a photoelectric conversion device can be used for pasting together upper and lower electroconductive glass substrates at an ordinary temperature in the manufacture of a photoelectric conversion device, and is excellent with respect to adhesion strength and the reliability in moisture resistance.

Sealing agent for photoelectric conversion device and photoelectric conversion device using the same

A photoelectric conversion device comprising an organic dye-sensitizing semiconductor fine particle thin film is prepared by using a dye having a barbituric acid structure as a partial structure and by adsorbing the dye on a semiconductor thin film electrode, and thereby a low-cost photoelectric conversion device having high conversion efficiency, and a solar cell using the device are provided.

The present invention relates to an organic dye-sensitized semiconductor device and to a solar cell using it and, particularly, to a photoelectric conversion device using semiconductor fine particles sensitized with a dye having an acrylic acid part and a solar cell using it. According to the present invention, a low-cost photoelectric conversion device having favorable conversion efficiency and a solar cell can be obtained.

Growing community of inventors

Tokyo, Japan

Teruhisa Inoue