Brewer Science, Inc.

Other

Nissan Chemical Industries Limited

Terry Lowell Brewer

Tony D Flaim

Mary G Moss

Xie Shao

James E Lamb, Iii

Jim D Meador

Ram W Sabnis

Dan W Hawley

James F Lamb

James J Kaufmann

Douglas J Guerrero

Ryan E Giedd

Colin Hester

Ruth M Cuzmar

Kimberly A Moeckli

Mary J Spencer

Yoshitane Watanabe

Kiyomi Ema

Vandana Krishnamurthy

Akira Yanagimoto

Earnest C Murphy

Yasuhisa Sone

William J Latham

John W Arnold

Sumalee Punyakumleard

Gregg Barnes

J Michael Mori

Edith G Hays

Michael D Stroder

Lynn K Stichnote

Jeffry Hunninghake

Yih-Wen Chen

Jeffery Hunninghake

Yongqiang Wang

Jonathan W Mayo

Robert E Nichols

An improved method for applying organic antireflective coatings to substrate surfaces and the resulting precursor structures are provided. Broadly, the methods comprise chemical vapor depositing (CVD) an antireflective compound on the substrate surface. In one embodiment, the compound is highly strained (e.g., having a strain energy of at least about 10 kcal/mol) and comprises two cyclic moieties joined to one another via a linkage group. The most preferred monomers are [2.2](1,4)-naphthalenophane and [2.2](9,10)-anthracenophane. The CVD processes comprise heating the antireflective compound so as to vaporize it, and then pyrolizing the vaporized compound to form stable diradicals which are subsequently polymerized on a substrate surface in a deposition chamber. The inventive methods are useful for providing highly conformal antireflective coatings on large substrate surfaces having super submicron (0.25 &#x3bc;m or smaller) features.

Organic polymeric antireflective coatings deposited by chemical vapor deposition

Anti-reflective compositions are prepared from cellulosic binders with improved etch rates.

Fast-etching, thermosetting anti-reflective coatings derived from cellulosic binders

Thermosetting, bottom-applied polymeric anti-reflective coatings exhibiting high optical density, rapid plasma etch rates, high solubility in preferred coating solvents, excellent feature coverage, and improved stability in solution are disclosed. The principal component of these new anti-reflective coatings is a polyester resin produced by the reaction of one or more difunctional aliphatic carboxylic acids with a stoichiometric excess of a di- and/or a trifunctional aliphatic primary alcohol, wherein at least one of the dicarboxylic acids may contain a reactive methylene (--CH.sub.2 --) group. The resulting polyester resin reaction product is further modified by attaching light-absorbing groups to some or all of the reactive methylene groups (if present) and/or hydroxy groups present on the resin. The dye-attached polyester resin is combined with an aminoplast crosslinking agent and acid catalyst in a suitable solvent system to form the final anti-reflective coating.

Thermosetting polyester anti-reflective coatings for multilayer

A high optical density, i.e., .gtoreq.3.0, at 1 micron or less film thickness, black matrix is disclosed having improved stability and shelf life as a consequence of admixing Pigment Black 7 and organic dye or dye mixtures on a polyimide polymer vehicle.

High optical density ultra thin organic black matrix system

A method for making multilayer resist structures for microlithographic processing using a thermosetting anti-reflective coating is disclosed for a broad range of exposure wavelengths, said coating containing an active curing catalyst, ether or ester linkages derived from epoxy functionality greater than 3.0, a dye-grafted hydroxyl-functional oligomer, and an alkylated aminoplast crosslinking agent, all present in a low-to-medium alcohol-containing solvent.

Method for making multilayer resist structures with thermosetting

Mid-UV dyes enabling ultra thin antireflection coatings for multi-layer i-line photoetching are produced from bichalcones; bis-a-cyanoacrylates/bis-cyanoacrylamides; and 1.4 divinylbenzenes. The dyes are nonsubliminal and differentially insoluble in standard photoresist solvents.

Non-subliming mid-UV dyes and ultra-thin organic arcs having

An organic black matrix having high resistivity (.gtoreq.10.sup.11 ohm/square), high optical density (.gtoreq.2.0) at ultra thin film thicknesses (.ltoreq.1.0 microns) for improved STN and TFT pixel display applications is made possible by combining polyimide/dye solutions and mixed metal oxide pigment dispersions at a weight/weight ratio of dye to pigment of 1:15 to 3:15. The need for low resistivity carbon black, as a replacement for sputtered chrome, is negated.

Ultra thin photolithographically imageable organic black matrix coating

Organic films are applied from solvent solution to a substrate, then are ion implanted to have resistivity in the kilohm/square to gigaohm/square range. The films are then patterned by standard lithographic procedures, with surprisingly little loss of conductivity, in spite of contact with organic solvents or acidic or basic etchant solutions during the patterning process. Both structures which contact the substrate, and freestanding conductive polymer bridges, can be formed. The invention provides a method of producing electrical devices which does not require the use of single crystal semiconductor substrates or deposition of inorganic semiconductors. The resulting devices are highly resistant to damage from abrasion, solvents, acids, bases, and moisture.

Method for making airbridge from ion-implanted conductive polymers

A thermosetting anti-reflective coating and method for making and using the same is disclosed for a broad range of exposure wavelengths, said coating containing an active curing catalyst, ether or ester linkages derived from epoxy functionality greater than 3.0, a dye-grafted hydroxyl-functional oligomer, and an alkylated aminoplast crosslinking agent, all present in a low-to-medium alcohol-containing solvent.

Thermosetting anti-reflective coatings compositions

Non-subliming Mid-UV dyes and ultra-thin organic arcs having

A light absorbing medium to be interposed under photosensitive layers, such as a photo-resist for integrated circuit 'chips' to eliminate defects caused by reflected light, has a polymer vehicle which can penetrate into small depressions of a substrate and form a thin, smooth and uniform coating. The coating includes a light absorbing dye. This light absorbing layer is imageable in the process. The light absorbing material eliminates many of the defects caused by reflected light resulting in increased sharpness of the images in the photo-resist. The material reduces the losses due to defects and increases the yield of useable product.

Anti-reflective coating

Growing community of inventors

Rolla, MO, United States of America

Terry Lowell Brewer