Daikin Industries, Ltd.

Tatsuya Otsuka

Hirokazu Aoyama

Fumihiko Yamaguchi

Eiji Seki

Tatsuya Hirata

Yoshinori Tanaka

Masayuki Yamana

Ikuo Yamamoto

Daisuke Karube

Satoshi Ide

Masato Kashiwagi

Hirotoshi Sakashita

Yoshitaka Honda

Katsuki Fujiwara

Satoshi Ishida

Keiko Washino

Kyohiro Kan

Koutarou Nakagawa

Shintaro Ogata

A method for dehydrating an aqueous composition comprising lithium bis(pentafluoroethanesulfonyl)imide and at least one organic solvent, wherein a part of solvent is distilled off by distillation.

Method for dehydrating composition comprising lithium bis(pentafluoroethanesulfonyl)imide

The present invention provides a method for isolating and purifying 1,1,1,2,2-pentafluoroethyl iodide or hydrogen fluoride from a mixture of 1,1,1,2,2-pentafluoroethyl iodide and hydrogen fluoride, characterized by distilling an azeotropic mixture of 1,1,1,2,2-pentafluoroethyl iodide and hydrogen fluoride from a mixture containing 1,1,1,2,2-pentafluoroethyl iodide and hydrogen fluoride either after liquid&mdash;liquid separation when the mixture is heterogeneous or directly when the mixture is homogeneous to obtain 1,1,1,2,2-pentafluoroethyl iodide or hydrogen fluoride from the bottom of the distillation column.

Azeotropic mixture of perfluoroalkyl iodide and hydrogen fluoride, and method for isolating and purifying perfluoroalkyl iodides

The present invention provides a method for isolating and purifying 1,1,1,2,2-pentafluoroethyl iodide or hydrogen fluoride from a mixture of 1,1,1,2,2-pentafluoroethyl iodide and hydrogen fluoride, characterized by distilling an azeotropic mixture of 1,1,1,2,2-pentafluoroethyl iodide and hydrogen fluoride from a mixture containing 1,1,1,2,2-pentafluoroethyl iodide and hydrogen fluoride either after liquid-liquid separation when the mixture is heterogeneous or directly when the mixture is homogeneous to obtain 1,1,1,2,2-pentafluoroethyl iodide or hydrogen fluoride from the bottom of the distillation column.

The present invention provides a new industrial process for producing perfluoroalkanes in order to overcome the problems of processes for producing perfluoroalkanes in the prior art. The process of the present invention is a process for producing a perfluoroalkane corresponding to a general formula Rf-F (wherein Rf- is a perfluoroalkyl group represented by F(CF,),&mdash; and n is an integer of 2 to 10) by contacting a perfluoroalkyl iodide with gaseous fluorine to cause a reaction therebetween, wherein the contact is made in the presence of the liquid compound which is at least one liquid which is substantially inert to the perfluoroalkyl iodide and gaseous fluorine under the condition of the process and which is selected from a perfluoro-compound, a chlorofluoro-compound, and hydrogen fluoride.

Processes for the preparation of perfluoroalkanes and iodine pentafluoride

This invention provides a process for preparing 1,1,1,2,3,3,3-heptafluoropropane, which comprises reacting 2-trifluoromethyl-3,3,3-trifluoropropionic acid with fluorine gas. The process according to this invention produces 1,1,1,2,3,3,3-heptafluoropropane with high selectivity and is an industrially efficient and economical method.

Process for preparing 1,1,1,2,3,3,3-heptafluoropropane

Fluorinated hydrocarbon compound and process for its preparation, and

The present invention provides processes for preparing 2,2,3,3,4-pentafluorooxetane and/or 2,2,3,3,4,4-hexafluorooxetane which comprises reacting 2,2,3,3-tetrafluorooxetane with fluorine gas, the process inhibiting decomposition of the oxetane ring during the reaction and producing a reduced amount of by-products.

Fluorooxetane compound and process for its preparation

Fluorosilicone compound and composition containing the same

Chlorotrifluoroethylene is prepared in high yield by reacting tetrafluoroethylene with hydrogen chloride in the presence of a metallic catalyst without using 1,1,2-trichlorotrifluoroethylene, which destroys the ozone layer.

Process for preparing chlorotrifluoroethylene

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Settsu, Japan

Tatsuya Otsuka