Nippon Steel & Sumitomo Metal Corporation

Sumitomo Metal Industries, Inc.

Nippon Steel Corporation

Taro Ohe

Hideki Takabe

Kunio Kondo

Hisashi Amaya

Yohei Otome

Tomohiko Omura

Keiichi Nakamura

Yusaku Tomio

Masakatsu Ueda

Masanao Seo

Toshiharu Abe

Shinjiro Nakatsuka

Tomoki Mori

A stainless steel for oil wells which has excellent high-temperature corrosion resistance and can stably obtain a strength of not less than 758 MPa is provided. The stainless steel for oil wells contains, by masse, C: not more than 0.05%, Si: not more than 1.0%, Mn: 0.01 to 1.0%, P: not more than 0.05%, S: less than 0.002%, Cr: 16 to 18%, Mo: 1.8 to 3%, Cu: 1.0 to 3.5%, Ni: 3.0 to 5.5%, Co: 0.01 to 1.0%, Al: 0.001 to 0.1%, O: not more than 0.05%, and N: not more than 0.05%, the balance being Fe and impurities, and satisfies Formulas (1) and (2):Cr+4Ni+3Mo+2Cu&#x2267;44&#x2003;&#x2003;(1)Cr+3Ni+4Mo+2Cu/3&#x2266;46&#x2003;&#x2003;(2)

Stainless steel for oil wells and stainless steel pipe for oil wells

The chemical composition of a stainless steel in accordance with the present invention consists of C: not more than 0.05%, Si: not more than 0.5%, Mn: 0.01 to 0.5%, P: not more than 0.04%, S: not more than 0.01%, Cr: more than 16.0 and not more than 18.0%, Ni: more than 4.0 and not more than 5.6%, Mo: 1.6 to 4.0%, Cu: 1.5 to 3.0%, Al: 0.001 to 0.10%, and N: not more than 0.050%, the balance being Fe and impurities, and satisfies Formulas (1) and (2). Also, the micro-structure thereof contains a martensitic phase and a ferritic phase having a volume ratio of 10 to 40%, and the ferritic phase distribution ratio is higher than 85%.Cr+Cu+Ni+Mo &#x2267;&#x2003;&#x2003;()&#x2212;(C+N)+Mn+Ni+Cu/(Cr+Mo) &#x2266;&#x2212;&#x2003;&#x2003;()

Stainless steel for oil well, stainless steel pipe for oil well, and method of manufacturing stainless steel for oil well

A high-strength stainless steel for oil well having corrosion resistance excellent in a high-temperature environment, having excellent SSC resistance at normal temperature, and having better workability than 13% Cr steels has a chemical composition containing, by mass percent, C: at most 0.05%, Si: at most 1.0%, Mn: at most 0.3%, P: at most 0.05%, S: less than 0.002%, Cr: over 16% and at most 18%, Mo: 1.5 to 3.0%, Cu: 1.0 to 3.5%, Ni: 3.5 to 6.5%, Al: 0.001 to 0.1%, N: at most 0.025%, and O: at most 0.01%, the balance being Fe and impurities, a microstructure containing a martensite phase, 10 to 48.5%, by volume ratio, of a ferrite phase and at most 10%, by volume ratio, of a retained austenite phase, yield strength of at least 758 MPa and uniform elongation of at least 10%.

High-strength stainless steel for oil well and high-strength stainless steel pipe for oil well

The chemical composition of a stainless steel in accordance with the present invention consists of C: not more than 0.05%, Si: not more than 0.5%, Mn: 0.01 to 0.5%, P: not more than 0.04%, S: not more than 0.01%, Cr: more than 16.0 and not more than 18.0%, Ni: more than 4.0 and not more than 5.6%, Mo: 1.6 to 4.0%, Cu: 1.5 to 3.0%, Al: 0.001 to 0.10%, and N: not more than 0.050%, the balance being Fe and impurities, and satisfies Formulas (1) and (2). Also, the micro-structure thereof contains a martensitic phase and a ferritic phase having a volume ratio of 10 to 40%, and the ferritic phase distribution ratio is higher than 85%.Cr+Cu+Ni+Mo&#x2267;25.5&#x2003;&#x2003;(1)&#x2212;8&#x2266;30(C+N)+0.5Mn+Ni+Cu/2+8.2&#x2212;1.1(Cr+Mo)&#x2266;&#x2212;4&#x2003;&#x2003;(2)

The problem to be solved is the provision of a high-strength stainless steel pipe having a sufficient corrosion resistance in a high-temperature carbonic acid gas environment and having an excellent sulfide stress cracking resistance at normal temperature. A high-strength stainless steel pipe consist of, by mass %, C: 0.05% or less, Si: 1.0% or less, P: 0.05% or less, S: less than 0.002%, Cr: more than 16% and 18% or less, Mo: more than 2% and 3% or less, Cu: 1% to 3.5%, Ni: 3% or more and less than 5%, Al: 0.001% to 0.1% and O: 0.01% or less, Mn: 1% or less and N: 0.05% or less, and Mn and N in the above ranges satisfy formula (1), and the balance being Fe and impurities; and the metal micro-structure of the stainless steel pipe mainly includes a martensitic phase and comprises 10 to 40% of a ferritic phase by volume fraction and 10% or less of a retained &#x3b3;-phase by volume fraction.[Mn]&#xd7;([N]&#x2212;0.0045)&#x2266;0.001&#x2003;&#x2003;(1)wherein the symbols of elements in formula (1) respectively represent the contents (unit: mass %) of the elements in the steel.

High-strength stainless steel pipe excellent in sulfide stress cracking resistance and high-temperature carbonic-acid gas corrosion resistance

An oil country tubular good for expansion according to the invention is expanded in a well. The oil country tubular good for expansion has a composition containing, in percentage by mass, 0.05% to 0.08% C, at most 0.50% Si, 0.80% to 1.30% Mn, at most 0.030% P, at most 0.020% S, 0.08% to 0.50% Cr, at most 0.01% N, 0.005% to 0.06% Al, at most 0.05% Ti, at most 0.50% Cu, and at most 0.50% Ni, and the balance consisting of Fe and impurities, and a structure having a ferrite ratio of at least 80%. The oil country tubular good for expansion has a yield strength in the range from 276 MPa to 379 MPa and a uniform elongation of at least 16%. Therefore, the oil country tubular good according to the invention has a high pipe expansion characteristic.

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Izumiotsu, Japan

Taro Ohe