Asahi Denka Kogyo K.k.

Tamiji Kamakura

Noriyoshi Tanaka

Yukio Tatsumi

Kimiyoshi Namiwa

Masato Namiki

Aritoshi Fukushima

Kazuhisa Morita

Yoshikazu Shoji

Hideo Yokobori

Takuro Handa

Hidekatsu Katoh

Yuji Baba

Yuzi Baba

Shigeru Katsumata

Lubricated refrigerant composition containing fluorocarbon-type refrigerant, synthetic oil and molybdenumoxysulfide derivatives

Refrigerant incorporating a polyoxyalkylene glycol monomethylether

The objective of the present invention resides in providing a lubricant for refrigerators that reacts rapidly with free acids and contains a stabilizer that has good compatibility with a chlorine-free Flon-thpe coolant such as Flon 134a and the like whose molecules do not contain chlorine. The lubricant for refrigerators employing a chlorine-free Flon-type coolant in accordance with the present invention 100 parts by weight of a synthetic oil and is compounded with 0.05 to 15 parts by weight of an alicyclic epoxy compound having one or more functional groups represented by the following formula: ##STR1## (wherein R.sub.1 and R.sub.2 independently represent a hydrogen or methyl group, and may be the same or different).

Lubricated refrigerant composition containing alicyclic epoxy compounds

A grease composition comprising 0.1 to 10 parts by weight of a powdered molybdenum oxysulfide dithiocarbamate composition which comprises a compound represented by the following formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independent hydrocarbyl groups and may be the same or different groups, and the total number of carbon atoms contained in R.sup.1 to R.sup.4 is 4 to 36; and wherein X is sulfur or oxygen and the composition of the total of all Xs is given as S.sub.m and O.sub.n in which m and n satisfy the ranges of 1.7.ltoreq.m.ltoreq.3.5 and 0.5.ltoreq.n.ltoreq.2.3, respectively, in which the constituent particles have diameters of not larger than 50 .mu.m, based on 100 parts by weight of a base grease.

Powdery molybdenum oxysulfide dithiocarbamate composition, a process for

The present invention relates to a lubricated refrigerant for use in refrigerators employing hydrofluorocarbon coolants such as R 134a, R 32, R 125 and the like. The lubricated refrigerant contains fluorocarbon coolant, synthetic oil and a carbodiimide compound represented by the following general formula. R.sub.1 --N.dbd.C.dbd.N--R.sub.2, wherein R.sub.1 and R.sub.2 represent hydrogen atoms or hydrocarbly groups or nitrogen and/or oxygen containing hydrocarbly groups, and R.sub.1 and R.sub.2 may be the same or different groups. The refrigerant composition according to the present invention preferably contains said hydrofluorocarbon coolant and said lubricant at a given blending ratio.

Refrigerant composition containing carbodiimide

A powdery molybdenum oxysulfide dithiocarbamate composition which comprises a compound represented by the following general formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independent hydrocarbyl groups and may be the same or different groups, and the total number of carbon atoms contained in R.sup.1 to R.sup.4 is 4 to 36; and wherein X is sulfur or oxygen and the composition of the total of all Xs is given as S.sub.m O.sub.n in which n and m satisfy the ranges of 1.7.ltoreq.m.ltoreq.3.5 and 0.5.ltoreq.n.ltoreq.2.3, respectively, and in which the constituent particles have diameters of not larger than 50 .mu.m. The present invention also relates to a process for production of the composition and a grease composition containing the same.

A lubricant composition for refrigerators using Flon 134a comprises at least 80 percent by weight of a specific type of polyoxethylene glycol dialkyl ether having a kinematic viscosity of 6 to 500 cSt at 40 degree centigrade.

Lubricant for refrigerant

Disclosed is a novel sulfidoxymolybdenum dialkylphosphorodithioate represented by the following general formula (I): ##STR1## wherein R stands for a secondary alkyl group having 4 to 30 carbon atoms and four R's may be the same or different, and X stands for O or S and four X's may be the same or different. This compound is very valuable as the lubricant additive.

Growing community of inventors

Tokyo, Japan

Tamiji Kamakura