Sakata Inx Corporation

Takuya Myose

Okinori Nakashima

Kazuhiro Fuke

Jun Kawabata

Tadashi Hirose

Shinya Mizutani

Takuya Okamoto

Yoichi Sato

Ryoichi Nitta

Koki Ogasahara

Jun Kinjoh

Yuki Yoshida

Daigo Shiozaki

An active energy ray-curable inkjet ink composition contains: (A) hydroxy group-containing monofunctional (meth)acrylates by 20.0 to 60.0% by mass in the total amount of all polymerizable components; (B) polyfunctional monomers having ether bonds; (C) amine-modified oligomers by 10.0 to 50.0% by mass in the total amount of all polymerizable components; (D) ethyl phenyl(2,4,6-trimethylbenzoyl)phosphinate as a polymerization initiator; and (E) polymeric sensitizers. The active energy ray-curable inkjet ink composition allows for printing on films used for food packaging that are subject to more stringent property requirements.

Active energy ray-curable inkjet ink composition

An active energy ray-curable inkjet ink composition contains a pigment which contains Pigment Orange 71 and Pigment Violet 19 which is 30.0 to 85.0% by mass relative to a total mass of Pigment Violet 19 and Pigment Orange 71, and a photopolymerizable compound which contains, in a total amount of all polymerizable components,(A) 0.20 to 15.0% by mass of a multifunctional amine-modified oligomer; (B) 50.0% by mass or more of a monofunctional monomer; (C) 35.0% by mass or more of a monofunctional monomer whose glass transition temperature is 20° C. or more; (D) 35.0% by mass or more of a monofunctional monomer whose glass transition temperature is 10° C. or less; (E) 2.0 to 11.0% by mass of a multifunctional monomer whose glass transition temperature is 10° C. or less; and (F) 10.0 to 25.0% by mass of a nitrogen-containing monofunctional monomer.

An active energy ray-curable inkjet printing ink composition satisfies requirements A to E below is provided: (A) the content of amine-modified oligomer is 1.0 to 20.0% by mass; (B) alkoxy group-containing (meth)acrylate monomers are contained by 2.0 to 20.0% by mass; (C) (meth)acrylate monomers having an alkyl group with 6 to 20 carbon atoms is contained by 2.0 to 25.0% by mass; (D) at least one type selected from the group that consists of 1,6-hexanediol diacrylate, 3-methyl-1,5-pentanediol diacrylate, dipropylene glycol diacrylate, 1,10-decanediol diacrylate, propoxylated(2)neopentyl glycol diacrylate, and hydroxypivalic acid neopentyl glycol diacrylate is contained by 30.0 to 60.0% by mass; (E) as photopolymerization initiators, ethoxy(2,4,6-trimethylbenzoyl)phenylphosphine oxide is contained by 3.0 to 15.0% by, and oligo(2-hydroxy-2-methyl-1-(4-(1-methylvinyl)phenyl)propanone) and/or 2-hydroxy-1-{4-[4-(2-hydroxy-2-methylpropionyl)phenoxy]phenyl}-2-methylpropanone is/are contained by 2.0 to 10.0% by mass, where the total content of photopolymerization initiators is 6.0 to 25.0% by mass.

Active energy ray-curable inkjet printing ink composition

Provided is a photo-curable inkjet printing ink composition, comprising (A) an acrylicated amine compound having two photopolymerizable functional groups and two amino groups in a molecule, (B) a (meth)acrylic monomer having an alkoxy group, and (C) at least one selected from the group consisting of hexanediol acrylate, 3-methyl-1,5-pentanediol diacrylate, dipropylene glycol diacrylate, and neopentyl glycol diacrylate hydroxypivalate, wherein a content of the component (A) is 3 to 18% by mass in the ink composition, wherein a content of the component (B) is 5 to 35% by mass in the ink composition, and wherein a content of the component (C) is 30 to 60% by mass in the ink composition.

Ink composition for photo-curable inkjet printing

An object is to obtain a photocurable inkjet printing ink composition that demonstrates excellent preservation stability and discharge property, while also presenting curability under ultraviolet light from a light-emitting diode (LED) light source, as well as good adhesion, flexibility and tackiness. As a solution, a photocurable inkjet printing ink composition containing photopolymerizable compounds and photopolymerization initiator is provided, wherein the photocurable inkjet printing ink composition satisfies A to D: A. 2-(allyloxy methyl) methyl acrylate is contained by 5 to 40 percent by mass in all photopolymerizable compounds; B. multifunctional monomers and/or multifunctional oligomers of 0° C. or lower in glass transition temperature are contained by 5 to 20 percent by mass in all photopolymerizable compounds; C. amino group and/or amide group-containing monomers and/or oligomers are contained; and D. the ink composition has a viscosity of 30 mPa·s or lower at 25° C.

Photocurable inkjet printing ink composition

Disclosed is an ink composition for photo-curable ink jet printing, comprising (A) at least one selected from the group consisting of hexanediol acrylate, 3-methyl-1,5-pentanediol diacrylate, dipropylene glycol diacrylate, and hydroxy pivalic acid neopentyl glycol diacrylate, (B) at least one of vinyl amide monomer and acryloyl amine monomer, (C) an acrylated amine compound having two photopolymerizable functional groups and two amino groups in a molecule, (D) a monofunctional monomer (excluding vinyl amide monomer which is the (B) component), and a photopolymerization initiator, wherein a content of the (A) component is 40 to 70% by mass, wherein a content of the (B) component is 5 to 30% by mass, wherein a content of the (C) component is 0.1 to 15% by mass, and wherein a viscosity is 200 mPa·s or less.

Ink composition for photo-curable ink jet printing

An inkjet printing device for multi-color printing includes: multi-color inkjet nozzles that move in the direction perpendicular to the moving direction of the target base printing material and also in the direction parallel to the surface of the target base printing material; plasma ejection ports provided downstream of the multi-color inkjet nozzles in a manner oriented facing the surface of the multiple colored inks printed on the target base printing material; and an electron beam irradiation part located on the downstream side of the inkjet nozzles and plasma ejection ports, in a manner oriented facing the printed surface of the target base printing material.

Plasma electron beam treatment inkjet printing device

An object is to obtain a photocurable inkjet printing ink composition that demonstrates excellent preservation stability and discharge stability, good adhesion, bending tolerance property, and tackiness, and high hardness. As a solution, a photocurable inkjet printing ink composition containing photopolymerizable compounds and photopolymerization initiator is provided, wherein the photocurable inkjet printing ink composition satisfies the requirements of A to E:

Clear inks are prone to heat-induced micro-gelling that can cause their storage stability to drop, and micro-gelling may also occur in clear inks with the passage of time, in which case their inkjet discharge property may drop. As a solution, a photocurable clear ink composition for inkjet printing is provided, which contains a photopolymerizable compound, a photopolymerization initiator, and an inorganic filler of 1 to 200 nm in average grain size accounting for 0.05 to 5.0 percent by mass in the composition, and whose visible light transmission factor is 30% or higher.

Photocurable clear ink composition for inkjet printing

An object is to provide an ink composition for inkjet printing that permits inkjet printing, particularly on metal surfaces, wherein such ink composition possesses sufficiently high adhesion and heat resistance with respect to metal surfaces. As a means for achieving the object, a photocurable inkjet printing ink composition is provided, which contains, relative to the entire ink composition, 0.1 percent by mass or more of an acid-modified acrylic monomer and 10 to 30 percent by mass of a monofunctional monomer with a Tg of 100&#xb0; C. or above, wherein the monofunctional monomer accounts for 80 percent by mass or more of all monomers.

A photocurable inkjet printing ink composition contains a photopolymerizable compound and a photopolymerization initiator, wherein in 100 percent by mass of the photocurable inkjet printing ink composition, included are: an acrylamide-based monomer by 5.0 to 50 percent by mass; a monofunctional monomer other than acrylamide-based monomer by 15 to 70 percent by mass; a polymerizable compound having two or more functionalities by 5.0 to 30.0 percent by mass; vinyl caprolactam by 0.1 to 15 percent by mass and/or an acrylated amine compound having two photopolymerizable functional groups and two amino groups in the molecule by 0 to 10 percent by mass; and the percentage of monofunctional monomers in the photopolymerizable compound is 60 to 99.5 percent by mass.

A light-curable inkjet printing ink composition contains a light-polymerizable component and a light-polymerization initiator, where the light-curable inkjet printing ink composition contains 70 to 100 percent by mass of monofunctional monomers relative to the total mass of the light-polymerizable component; wherein the monofunctional monomers comprise: (A) a monofunctional monomer whose homopolymer has a glass transition temperature of 20&#xb0; C. or above; and (B) a monofunctional monomer whose homopolymer has a glass transition temperature of below 20&#xb0; C.; and (A) is contained by 30 to 90 percent by mass, while (B) is contained by 10 to 70 percent by mass, relative to the total mass of the light-polymerizable component.

Light-curable inkjet printing ink composition

Provided is an ink set having excellent curing properties under LED light, providing printed matter that does not fade or discolor due to a photopolymerization initiator, suppressing color bleeding during image forming, exhibiting favorable adhesion towards a polyvinyl chloride sheet, enabling cock ring to be efficiently suppressed, and demonstrating an extremely low viscosity, high flash point and low skin irritation. The present invention pertains to an ink set containing at least two compositions selected from the group consisting of a yellow ink composition, a magenta ink composition, a cyan ink composition, a black ink composition, a white ink composition, and a clear ink composition, the compositions having the predetermined structure as specified in claim, wherein the flash point of the ink compositions is 70&#xb0; C. or higher, and the viscosity (25&#xb0; C.) is 5 mPa-s or lower.

Ink set and printed material

Provided is a photocurable ink composition for inkjet printing which is favorably cured with light from a light-emitting diode (LED), favorably adheres to a polyvinyl chloride sheet such as a tarpaulin and a vinyl chloride resin sheet, suppresses the occurrence of cockling, and has both safety and favorable ejection stability at room temperature when ejected from an inkjet head for low-viscosity ink, and a printed material. The present invention is a photocurable ink composition for inkjet printing containing photopolymerizable compounds and a photopolymerization initiator. The photopolymerizable compounds are vinyloxyethoxyethyl acrylate and benzyl acrylate, and contained in specific amounts. The photopolymerization initiator is a compound that expresses an initiator function when irradiated with light having a wavelength within the range of 450 to 300 nm. The photocurable ink composition has a flash point of 70&#xb0; C. or higher and a viscosity at 25&#xb0; C. of 5 mPa&#xb7;s or lower, and further contains 50% by mass or more of a monofunctional monomer.

Photocurable ink composition for injet printing and printed material

A photocurable inkjet printing ink composition includes at least a photopolymerizable compound component and a photopolymerization initiator, wherein in the photopolymerizable compound component, a monofunctional monomer is included in a content of 91.0 to 99.5% by mass and a multifunctional monomer is included in a content of 0.5 to 9.0% by mass; in the monofunctional monomer component, acryloylmorpholine is included in a content of 30.0 to 85.0% by mass; the monofunctional monomer component includes at least one selected from benzyl acrylate, ethyl carbitol acrylate, tetrahydrofurfuryl acrylate and phenoxyethyl acrylate in a content of 5.0 to 40.0% by mass in the monofunctional monomer component; and the stretching rate at 180&#xb0; C. of the cured coating obtained by photopolymerizing the photocurable inkjet printing ink composition is 120% or more.

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Osaka, Japan

Takuya Myose