Daicel Chemical Industries, Ltd.

Takuya Miho

Shoji Watanabe

Yoshiyuki Ikemoto

Naoki Nakashima

Tomohisa Isobe

Takaaki Murai

Michio Nakanishi

Kimio Inoue

Toshio Endo

Tatsumi Fujii

Koichi Okumura

Yoshinobu Mizutani

Shunichi Endo

Genichiro Ochiai

The invention provides polyester dials suitable for preparation of polyurethanes, and provides polyurethanes derived therefrom. The invention also provides spandex filaments prepared from these polyurethanes, which exhibit improved elasticity, tensile strength, and resistance to hydrolysis. The present invention also provides dialkyl amino group-containing polyol additives having a high solubility in dimethylacetamide solvent, which when incorporated into a polyurethane protect the polyurethane and derived spandex filaments from deterioration or discoloration, and confer an improved modulus of elasticity. The polyurethanes and spandex filaments of the invention provide fabrics having a soft feeling, excellent hydrolysis resistance, wrinkle resistance, and adhesive properties, and which are particularly suitable for preparation of an artificial leather.

Polyester diol and derived polyurethane and acrylic copolymer

In the present invention, the No. I invention relates to a regenerated PET resin composition which comprises formulating 0.5-100 part by weight of a lactone polymer (B) with 100 parts by weight of a regenerated PET resin (A), in which there is improved a molding processability such as an injection moldability and extruding molding, and relates to a molded article therefrom and, the No. II invention relates to a flame retardant resin composition containing a thermoplastic resin (E) and a flame retardant (F), in which bleeding of the flame retardant is suppressed without a decline of a flame retardancy, and relates to a molded article therefrom.

Reclaimed pet resin composition, molded article thereof, and flame-retardant resin composition and molded article thereof

A composition for producing a metallic sintered body consisting essentially of a mixture of a powdered metal having an average particle size of not more than 50 microns with a lactone resin having a relative viscosity value in the range of from 1.15 to 3.20 is disclosed. The composition has excellent properties such as mechanical strength of a green body thereof, and only a short time being necessary for removal or elimination of binder in comparison with conventional sintering compositions. Furthermore, the binder in the present composition is substantially composed of a single component; accordingly, manufacturing process control can be simplified by use of the lactone resin. Furthermore, a method for producing a metallic sintered body using such composition is also disclosed.

Method for producing a metallic sintered body

A composition for producing a metallic sintered body consisting essentially of a mixture of a powered metal having an average particle size of not more than 50 microns with a lactone resin having a relative viscosity value in the range of from 1.15 to 3.20 is disclosed. The composition has excellent properties such as mechanical strength of a green body thereof, and only a short time being necessary for removal or elimination of binder in comparison with conventional sintering compositions. Furthermore, the binder in the present composition is substantially composed of a single component; accordingly, manufacturing process control can be simplified by use of the lactone resin. Furthermore, a method for producing a metallic sintered body using such composition is also disclosed.

Composition and method for producing a metallic sintered body

A process for producing a lactone polymer which comprises reacting an ester compound synthesized from an alcohol and an acid or acid anhydride thereof with a lactone and a ring-opening polymerization initiator without being accompanied by condensation. The thus produced lactone polymer is effective for preventing shrinkage of thermosetting resins, particularly unsaturated polyester resins.

Process for producing lactone polymer and an anti-shrinking

A polyurethane comprises (a) organic diisocyanate units and (b) polycaprolactone polyol units having a narrow molecular weight distribution in which a ratio of the weight average molecular weight to the number average molecular weight is in the range of from 1.1 to 2.0 and the average molecular weight is 500 to 5,000, the units (a) and (b) being connected linearly through urethane linkages.

Polyurethane

A polyurethane having excellent elastic recovery is obtained by reacting an organic diisocyanate with a polycaprolactone polyester-diol prepared from a dihydric alcohol, a dibasic acid, an ester thereof or an anhydride thereof and .epsilon.-caprolactone or/and hydroxycaproic acid and having a hydroxyl value of 35 to 150 KOH mg/g and a content of .epsilon.-caprolactone and hydroxycaproic acid of 69 to 95% by weight.

Polyurethane having excellent elastic recovery and elastic filament of

A polyol resin is disclosed which is obtained by reacting 95 to 40% by weight of an aromatic vinyl monomer-allyl alcohol copolymer with 5 to 60% by weight of .epsilon.-caprolactone or .epsilon.-hydroxycaproic acid. The polyol resin can be reacted with a crosslinking agent to form a coating film.

Polyol resin

A lactone polymer has a narrow molecular weight distribution where a ratio of the weight average molecular weight to the number average molecular weight is in the range of from 1.1 to 2.0 and the molecular weight is 500 to 5,000.

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Yamaguchi-ken, Japan

Takuya Miho