Mitsubishi Gas Chemical Company, Inc.

Takuo Ohshida

Masamichi Mizukami

Hiroaki Ohgi

Hidefumi Harada

Yoshihisa Arai

Takashi Kojima

Katsumi Higuchi

Akio Hashimoto

Koichi Kanno

Toshihiro Nomura

Sachiko Arie

Provided is a production process for a carbon material comprising an alkali activation reaction step in which a carbon precursor containing an activator selected from alkali metal compounds is heated under flow of inert gas. The above alkali activation reaction is carried out while allowing carbon dioxide gas to flow into a downstream part of an alkali activation reaction region on the condition that the carbon dioxide gas is not substantially brought into contact with the carbon precursor and the activator. This makes it possible to carry out alkali activation treatment safely and stably and obtain a carbon material useful for producing an electric double layer capacitor electrode having a high electrostatic capacity.

Process for producing carbon material and alkali activation apparatus

Problems on catalyst production and catalyst performance with respect to conventional 8-oxygen-membered ring micropore-containing crystalline silicoaluminophosphate molecular sieves as non-equilibrium methylamine synthesis catalysts, are resolved. A chabazite type crystalline silicoaluminophosphate molecular sieve having high purity and high crystallinity and having, on a crystal grain surface, an amorphous oxide layer whose Si/Al atomic ratio is greater than that of the whole crystal grain can be stably produced with high yield with the use of a small amount of structure directing agents by the present method characterized in that hydrothermal treatment conducted in the production of 8-oxygen-membered ring micropore-containing crystalline silicoaluminophosphate sieves is controlled under specified treating conditions. The thickness and composition of the amorphous oxide layer, which exert marked influence on the yield of dimethylamine synthesis, can be easily controlled and reproduced under the conditions of catalyst synthesis according to the invention. Thus, the catalyst of high performance can be stably supplied by the present invention at a low cost with reduced output of waste.

Crystalline silicoaluminophosphate salt molecular sieve having octaoxygen-membered ring pore, process for producing the same and process for producing methylamine with the molecular sieve as catalyst

A process for separation between dialkyl carbonate and alkyl carbamate which comprises adding an aromatic hydroxy compound to a liquid comprising alkyl carbamate having an alkyl group having 3 to 6 carbon atoms and dialkyl carbonate having alkyl group having 3 to 6 carbon atoms to obtain a mixed liquid, and distilling the mixed liquid thus obtained in a distillation column to obtain a mixture comprising the dialkyl carbonate and the aromatic hydroxy compound from a top section of the distillation column and a liquid comprising the alkyl carbamate from a bottom section of the distillation column.

Process for separation between dialkyl carbonate and alkyl carbamate

A process for producing a dialkyl carbonate which comprises reacting at least one member selected from the group consisting of urea and alkyl carbamate with alcohol in the presence of both a catalyst and a high boiling point organic compound having a boiling point of 180.degree. C. or above.

Process for producing dialkyl carbonate

A process for producing diaryl carbonate which comprises (A) a step for producing dialkyl carbonate represented by the general formula RO--CO--OR by reacting urea with alkyl alcohol represented by the general formula ROH, (B) a step for producing both alkyl aryl carbonate represented by the general formula RO--CO--OAr and diaryl carbonate represented by the general formula ArO--CO--OAr by reacting dialkyl carbonate produced in the above step (A) with an aromatic hydroxy compound represented by the general formula ArOH, and (C) a step for producing diaryl carbonate represented by the general formula ArO--CO--OAr by allowing to conduct disproportionation reaction of unreacted alkyl aryl carbonate produced in the above step (B), wherein R shows an alkyl group and Ar shows a non-substituted phenyl group or a phenyl group substituted by alkyl group, alkoxy group, aryl group, aryloxy group or halogen.

Process for producing diaryl carbonate

A process for producing an aromatic carbonate which comprises: reacting a dialkyl carbonate represented by general formula (1) with an aromatic carboxylic acid aryl ester represented by general formula (2) in the presence of a catalyst to produce an aromatic carbonate represented by one or both of general formulae (3) and (4):

Growing community of inventors

Kanagawa, Japan

Takuo Ohshida