Mitsubishi Chemical Corporation

Takeshi Oowada

Teruyuki Mitsumori

Hiroaki Takamura

Kozo Ishio

Shiro Yasutomi

Shiho Sano

Yumi Hirabaru

Masakazu Sugihara

Masaya Oota

Teruki Senokuti

Masaya Ota

Teruki Senokuchi

A method of forming an image including an electrophotographic photoreceptor and a toner, wherein a photosensitive layer in the electrophotographic photoreceptor includes an undercoat layer including metal oxide particles, a charge generation layer including hydroxygallium phthalocyanine, and a charge transport layer, and the toner contains toner matrix particles formed in an aqueous medium; the toner has a volume median diameter (Dv50) of from 4.0 &#x3bc;m to 7.0 &#x3bc;m; and the relationship between the volume median diameter (Dv50) and the percentage in number (Dns) of toner particles having a particle diameter of from 2.00 &#x3bc;m to 3.56 &#x3bc;m satisfies&#x2014;0.0517EXP(22.4/Dv50)&#x2266;Dns&#x2266;0.233EXP(17.3/Dv50) where Dv50 is the volume median diameter (&#x3bc;m) of the toner, and Dns is the percentage in number of toner particles having a particle diameter of from 2.00 &#x3bc;m to 3.56 &#x3bc;m.

Method of image forming with a photoreceptor and toner

A method of forming an image on a substrate with an electrophotographic photoreceptor and a toner, a photosensitive layer of the electrophotographic photoreceptor contains a resin having a structural unit represented by the following formula (A) the toner containing toner matrix particles formed in an aqueous medium; the toner has a volume median diameter (Dv50) of from 4.0 &#x3bc;m to 7.0 &#x3bc;m; and the relationship between the volume median diameter (Dv50) and the percentage in number (Dns) of toner particles having a particle diameter of from 2.00 &#x3bc;m to 3.56 &#x3bc;m satisfies following formula (1)&#x2266;0.233EXP(17.3/50)&#x2003;&#x2003;(1).

Image forming apparatus

An image forming apparatus comprising an electrophotographic photoreceptor having a photosensitive layer on an electroconductive substrate, and a toner for developing an electrostatic charge image, wherein the photosensitive layer of the electrophotographic photoreceptor contains a phthalocyanine obtained via an acid paste step; the toner for developing an electrostatic charge image is a toner for developing an electrostatic charge image containing toner matrix particles formed in an aqueous medium; the toner has a volume median diameter (Dv50) of from 4.0 &#x3bc;m to 7.0 &#x3bc;m; and the relationship between the volume median diameter (Dv50) and the percentage in number (Dns) of toner particles having a particle diameter of from 2.00 &#x3bc;m to 3.56 &#x3bc;m satisfies the following formula (1):&#x2266;0.233 EXP(17.3/50)&#x2003;&#x2003;(1).

To provide an image forming apparatus which is able to improve image quality while suppressing soiling of image white parts, scattering in the apparatus, streaks, fading, etc. due to non-uniformity in the particle size distribution of a toner or mismatching between a toner and a photoreceptor, and which has good cleaning properties, and even when a high speed printing machine is used, is able to reduce a problem of soiling, etc. in long-term use and provide excellent image stability. An image forming apparatus comprising an electrophotographic photoreceptor having a photosensitive layer on an electroconductive substrate, and a toner for developing an electrostatic charge image, wherein the photosensitive layer of the electrophotographic photoreceptor contains a phthalocyanine obtained via an acid paste step; the toner for developing an electrostatic charge image is a toner for developing an electrostatic charge image containing toner matrix particles formed in an aqueous medium; the toner has a volume median diameter (Dv50) of from 4.0 &#x3bc;m to 7.0 &#x3bc;m; and the relationship between the volume median diameter (Dv50) and the percentage in number (Dns) of toner particles having a particle diameter of from 2.00 &#x3bc;m to 3.56 &#x3bc;m satisfies the following formula (1):&#x2266;0.233 EXP(17.3/50)&#x2003;&#x2003;(1).

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Joetsu, Japan

Takeshi Oowada