Sanyo Electric Co., Ltd.

Panasonic Intellectual Property Management Co., Ltd.

Sanyo Electronic Co., Ltd.

Takeshi Ogasawara

Naoki Imachi

Akihiro Kawakita

Mutsumi Yano

Shin Fujitani

Mitsunori Tokuda

Daizo Jito

Yoshinori Aoki

Hiroyuki Matsumoto

Yasunori Baba

Toshinobu Kanai

Nobuyuki Higashiyama

Yasuhiko Itoh

Takaya Tochio

Motoharu Saitou

Mamoru Kimoto

Hiroshi Minami

Yoshinori Kida

Kaoru Nagata

Atsushi Kaiduka

Takao Kokubu

Yuki Morikawa

Taizou Sunano

Yoshifumi Magari

Manabu Takijiri

Atsushi Ogata

Atsushi Fukui

Koji Nishio

Katsunori Yanagida

Fumiharu Niina

Kentaro Takahashi

Masanobu Takeuchi

Junichi Sugaya

Taiki Satow

Katsuya Inoue

Masakazu Togo

Tetsuo Kadohata

Takaaki Oka

Noriko Fukamichi

Yuji Goshima

A positive electrode active material for nonaqueous electrolyte secondary batteries which allows the capacity of nonaqueous electrolyte secondary batteries to be increased and offers a smaller decrease in charge discharge cycle characteristics, and to provide a nonaqueous electrolyte secondary battery having such a positive electrode active material. A positive electrode active material for nonaqueous electrolyte secondary batteries according to the present invention includes a composite oxide containing Li, Ni, Co, Al, W and additive elements M, the proportion of Ni in the composite oxide being not less than 80 mol % relative to the total number of moles of the metal elements except Li, the additive elements M including at least either of an alkaline earth metal element and an alkali metal element except Li, and a tetravalent or higher valent element, the average valence of the additive elements M being not less than 3.6.

Positive electrode active material for nonaqueous electrolyte secondary batteries, and nonaqueous electrolyte secondary battery

This positive electrode active material for non-aqueous electrolyte secondary batteries comprises: lithium transition metal oxide particles; a metal compound which contains a metal element M and adheres to the surfaces of the lithium transition metal oxide particles; and a lithium metal compound which contains lithium (Li) and the metal element M and adheres to the surfaces of the lithium transition metal oxide particles. In this connection, the metal element M is composed of at least one substance that is selected from among aluminum (Al), titanium (Ti), manganese (Mn), gallium (Ga), molybdenum (Mo), tin (Sn), tungsten (W) and bismuth (Bi).

Positive electrode active material for nonaqueous electrolyte secondary batteries, method for producing positive electrode active material for nonaqueous electrolyte secondary batteries, and nonaqueous electrolyte secondary battery

A positive electrode active material to be used in a non-aqueous electrolyte secondary battery and containing a lithium transition metal compound which contains Ni in a proportion constituting 80-94 mol %, inclusive, relative to the total mole number of the metal elements other than Li, and also contains Nb in a proportion constituting 0.1-0.6 mol %, inclusive, relative thereto, the positive electrode active material being characterized in that the Nb amount n1 in a first sample solution obtained by adding 0.2 g of the lithium transition metal compound to a hydrochloric acid aqueous solution comprising 5 mL of pure water/5 mL of 35% hydrochloric acid, and the Nb amount n2 in a second sample solution obtained by immersing a filter used to filter the first sample solution in a fluonitric acid comprising 5 mL of 46% hydrofluoric acid/5 mL of 63% nitric acid satisfy the condition of 50%≤n1/(n1+n2)<75% when converted to molar quantities.

Positive electrode active material for non-aqueous electrolyte secondary battery, non-aqueous electrolyte secondary battery, and method for producing positive electrode active material for non-aqueous electrolyte secondary battery

The positive electrode active material for a non-aqueous electrolyte secondary cell according to an embodiment of the present disclosure is characterized in having a Ni-containing lithium transition metal oxide having a layered structure; the proportion of Ni in the lithium transition metal oxide being 91 to 96 mol % relative to the total number of moles of metal elements excluding Li; a transition metal being present in the Li layer of the layered structure at an amount of 1 to 2.5 mol % relative to the total number of moles of transition metals in the Ni-containing lithium transition metal oxide; and the Ni-containing lithium transition metal oxide being such that the half width n of the diffraction peak for the (208) plane in an X-ray diffraction pattern obtained by X-ray diffraction is 0.30°≤n≤0.50°.

Positive electrode active material for non-aqueous electrolyte secondary cell, and non-aqueous electrolyte secondary cell

A positive electrode active material for non-aqueous electrolyte secondary batteries comprises a lithium transition metal oxide containing Ni, Mn, Co, and Al and having a layered structure, wherein the content ratio of Ni in the lithium transition metal oxide is 75 to 95 mol %, the content ratio of Mn in the lithium transition metal oxide is equal to or greater than the content ratio of Co in the lithium transition metal oxide, the content ratio of Co in the lithium transition metal oxide is 0.5 to 2 mol %, the content ratio of a metal element other than Li in an Li layer in the layered structure is 1 to 2.5 mol %, and, in the lithium transition metal oxide, the half width n of a diffraction peak for (208) plane of an X-ray diffraction pattern as measured by X-ray diffraction is as follows: 0.30°≤n≤0.50°.

Positive electrode active material for non-aqueous electrolyte secondary batteries, and non-aqueous electrolyte secondary battery

A lithium-containing complex transition metal oxide forming the positive electrode active material of a non-aqueous electrolyte secondary cell in one embodiment is a secondary particle obtained by aggregating primary particles and has a BET specific surface area of 0.9 m/g or less. The surface of each primary particle comprises 0.3 to 2.5% lithium carbonate, no more than 0.35% lithium hydroxide, and 2 to 200 ppm of a nitrogen compound relative to the total mass of the lithium-containing complex transition metal oxide.

Positive electrode active material for non-aqueous electrolyte secondary battery, positive electrode for non-aqueous electrolyte secondary battery, and non-aqueous electrolyte secondary battery

This positive electrode active substance for a non-aqueous electrolyte secondary battery contains: a lithium-containing transition metal oxide having secondary particles formed by aggregation of primary particles; and at least a tungsten compound and a boron compound that are present between primary particles. The present invention is characterized in that: the amount of tungsten element eluted when the positive electrode active substance is washed for 5 minutes with a 0.01 mol/L aqueous solution of sodium hydroxide is 60% or less of the amount of tungsten element detected when the positive electrode active substance is dissolved in a mixed acid containing hydrofluoric acid, nitric acid and hydrochloric acid; and the amount of boron element eluted when the positive electrode active substance is washed for 1 minute with ion exchanged water is 80% or more of the amount of boron element detected when the positive electrode active substance is dissolved in hydrochloric acid.

Positive electrode active substance for non-aqueous electrolyte secondary battery, and positive electrode for non-aqueous electrolyte secondary battery

According to one embodiment, a positive electrode active material for a non-aqueous electrolyte secondary battery contains a lithium/transition metal composite oxide that contains 80 mol % or more, relative to the total mol number of metal elements other than Li, of Ni and at least one kind of metal element selected from among Co, Mn, Al, W, Mg, Mo, Nb, Ti, Si and Zr. When a filtrate of a suspension, said suspension being prepared by adding 250 mg of the positive electrode active material to 10 mL of a 17.5 mass % aqueous solution of hydrochloric acid, dissolving by heating at 90° C. for 2 hours and then diluting to 50 mL, is analyzed by inductively coupled plasma mass spectrometry, the elution amount of S in the filtrate is 0.002 mmol or greater.

Positive electrode active material for non-Aqueous electrolyte secondary battery, non-Aqueous electrolyte secondary battery, and method for producing positive electrode active material for non-aqueous electrolyte secondary battery

A lithium-containing complex transition metal oxide forming the positive electrode active material of a non-aqueous electrolyte secondary cell in one embodiment is a secondary particle obtained by aggregating primary particles. Ion chromatography analysis of a sample obtained by adding the positive electrode active material to an alkali solution and absorbing a distillate thereof in sulfuric acid results in detection of 2-200 pm of ammonia relative to the mass of the positive electrode active material. When a filtrate of an aqueous dispersion in which 1 g of the positive electrode active material is dispersed in 70 ml of pure water is titrated with hydrochloric acid, the value of Y−X is 50-300 mol/g and the value of X−(Y−X) is no higher than 150 mol/g, with X mol/g being the acid consumption until a first inflection point on the pH curve and Y mol/g being the acid consumption until a second inflection point.

The positive electrode active material for a non-aqueous electrolyte secondary cell according to an embodiment of the present disclosure is characterized in having a Ni-containing lithium transition metal oxide having a layered structure; the proportion of Ni in the lithium transition metal oxide being 91 to 96 mol % relative to the total number of moles of metal elements excluding Li; a transition metal being present in the Li layer of the layered structure at an amount of 1 to 2.5 mol % relative to the total number of moles of transition metals in the Ni-containing lithium transition metal oxide; and the Ni-containing lithium transition metal oxide being such that the half width n of the diffraction peak for the (208) plane in an X-ray diffraction pattern obtained by X-ray diffraction is 0.30&#xb0;&#x2264;0&#x2264;0.50&#xb0;.

A positive electrode active material or non-aqueous electrolyte secondary batteries comprises a Co-containing lithium transition metal oxide containing Ni, Mn, and an arbitrary element and having a layered structure, wherein the content ratio of Ni in the lithium transition metal oxide is 75 to 95 mol %, the content ratio of Mn in the lithium transition metal oxide is equal to or greater than the content ratio of Co in the lithium transition metal oxide, the content ratio of Co in the lithium transition metal oxide is 0 to 2 mol %, the content ratio of a metal element other than Li in an Li layer in the layered structure is 1 to 2.5 mol %, and, in the lithium transition metal oxide, the half width n of a diffraction peak for (208) plane of an X-ray diffraction pattern as measured by X-ray diffraction is as follows: 0.30&#xb0;&#x2264;n&#x2264;0.50&#xb0;.

The method for manufacturing a positive electrode active material for a non-aqueous electrolyte secondary battery according to one embodiment of the present invention comprises: a first step for adding an alkaline solution having a tungsten compound dissolved therein to a lithium-metal composite oxide powder represented by general formula LiNiCoMO(where 0&#x2264;x&#x2264;0.1, 0&#x2264;y&#x2264;0.1, and 0.97&#x2264;z&#x2264;1.20 are satisfied, and M is at least one type of element selected from among Mn, W, Mg, Mo, Nb, Ti, Si, and Al), and mixing same; and a second step for heating the mixture of the alkaline solution and the lithium-metal composite oxide powder at 100-600&#xb0; C., wherein the amount of the alkaline solution to be added in the first step is 0.1-10 mass % with respect to the amount of the lithium-metal composite oxide powder.

Method for manufacturing positive electrode active material for non-aqueous electrolyte secondary battery

A positive electrode for a non-aqueous electrolyte secondary battery contains a first particle and a second particle. The first particle contains an electrochemically active positive-electrode active material, and the positive-electrode active material contains a lithium transition metal oxide. The second particle contains an electrochemically inactive metal oxide. An electrochemically inactive phosphate adheres to the surface of the second particle.

Positive electrode for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery

A positive electrode active material which predominantly includes lithium transition metal composite oxide particles containing Ni and Al, and which has a low charge transfer resistance and thus allows the battery capacity to be increased. The composite oxide particles contain 5 mol % or more Al relative to the total molar amount of metal elements except Li, include a particle core portion and an Al rich region on or near the surface of the composite oxide particle wherein the Al concentration in the particle core portion is not less than 3 mol % and the Al concentration in the Al rich region is 1.3 times or more greater than the Al concentration in the particle core portion. The composite oxide particles contain 0.04 mol % or more sulfate ions relative to the total molar amount of the particles.

Positive electrode active material for nonaqueous electrolyte secondary batteries, method for producing positive electrode active materials for nonaqueous electrolyte secondary batteries, and nonaqueous electrolyte secondary battery

A positive electrode active material for nonaqueous electrolyte secondary batteries includes: secondary particles composed of aggregated primary particles of a lithium composite oxide containing Ni: a rare earth compound attached to the surfaces of the secondary particles; a tungsten compound attached to the surfaces of the secondary particles: and lithium carbonate attached to the surfaces of the primary particles inside the secondary particles. The rate of Ni in the lithium composite oxide containing Ni with respect to the total number of moles of metal elements other than lithium in the lithium composite oxide containing Ni is 80 percent by mole or more, and the content of the lithium carbonate with respect to the total mass of the lithium composite oxide containing Ni is 0.3 percent by mass or more.

Growing community of inventors

Kobe, Japan

Takeshi Ogasawara