Shin-etsu Chemical Co., Ltd.

Takehiko Fukumoto

Ryuichi Saguchi

Naoki Ishibashi

Miyoshi Yamashita

Kinya Ogawa

Akira Yamamoto

Tatsuya Hojo

Takeshi Kinsho

Hiroshi Suzuki

Yuki Miyake

Noboru Aiba

Mitsuyoshi Oshima

Satoshi Ogitani

Daisuke Iwai

Fumiaki Mochizuki

Shigeo Okano

Kazushi Hirokawa

Toyohisa Sakurada

Tatsuya Fujii

Yasutoshi Tanaka

Masaomi Azuma

Tatsuya Ito

Koichi Ogura

Takanobu Terauchi

Tsugio Ogata

Kurao Okada

Sadahiro Tatsuki

Mamoru Terayama

Provided is an annular sustained release preparation to be used by opening a center portion thereof, the preparation having a strength enough to avoid cleaving at a welded end portion. More specifically, provided is an annular sustained release preparation having at least two polymer tubes having both ends sealed and integrated by pressure-welding or at least one polymer tube and at least one polymer rod having both ends sealed and integrated by pressure-welding; and a sex pheromone liquid contained by at least one of the tubes or the tube; wherein an annular space can be formed by pulling the tubes or the tube and the rod apart from each other at a center portion therebetween, the central portion not having been pressure-welded; and an angle formed between a line connecting respective centers of diameters of the tubes welded to each other or the tube and the rod welded to each other and the pressure application direction is from 0 to 45&#xb0;.

Annular sustained release preparation and production method thereof

Provided are an insect pest-targeting gel composition causing neither leakage nor reaction of a volatile substance and capable of releasing the volatile substance at a constant rate; and a sustained release preparation including the insect pest-targeting gel composition. More specifically, provided is an insect pest-targeting gel composition including one or more volatile substances and an oil gelling agent, wherein the volatile substance is included in an amount of from 70.0 to 99.0% by weight by the insect pest-targeting gel composition.

Insect pest-targeting gel composition and sustained release preparation comprising that

Provided is an annular sustained release preparation having at least two polymer tubes having both ends sealed and integrated by pressure-welding or at least one polymer tube and at least one polymer rod having both ends sealed and integrated by pressure-welding; and a sex pheromone liquid contained by at least one of the tubes or the tube; wherein an annular space can be formed by pulling the tubes or the tube and the rod apart from each other at a center portion therebetween, the central portion not having been pressure-welded; and an angle formed between a line connecting respective centers of diameters of the tubes welded to each other or the tube and the rod welded to each other and the pressure application direction is from 0 to 45&#xb0;.

A sustained release pheromone formulation is provided in which once it is secured to a branch or other support, the likelihood of falling off is significantly reduced, and which is capable of being quickly attached to a small or large branch. The sustained release pheromone formulation includes a first and second sheet parts which are provided by bending a single polymer sheet so that they are arranged in a face-to-face manner, the sheet parts each having an engaging hole therethrough; a bend part located between the sheet parts; at least one sex pheromone substance carried on at least a part of the sheet parts; and slits each extending from the bend part to the engaging hole in each one of the sheet parts. This formulation can be secured to the rod-shaped support by guiding the rod-shaped support to the engaging holes via the slits and engaging with the holes.

Sustained release pheromone formulation

Provided is a method for producing a chlorohydrocarbon having conjugated double bonds by stereoselectively chlorinating an alcohol having conjugated double bonds. More specifically, provided is a method for producing a chlorohydrocarbon having conjugated double bonds, the method including a step of chlorinating an alcohol having conjugated double bonds with a chlorinating agent in a solvent in the presence of a base and in the absence of metal salt for chlorination of the alcohol, and the alcohol being represented by the formula (1):RCH&#x2550;CHCH&#x2550;CH&#x2014;Z&#x2014;OH&#x2003;&#x2003;(1)wherein R represents a hydrogen atom or a linear, branched or cyclic Cmonovalent hydrocarbon group which may have at least one double bond or at least one triple bond; and Z represents a linear, branched or cyclic Cdivalent hydrocarbon group which may have at least one double bond or at least one triple bond.

Method for producing chlorohydrocarbon having conjugated double bonds

Provided is a method for industrially producing a conjugated Z-alken-yn-yl acetate such as Z-13-hexadecen-11-yn-yl acetate which is a sex pheromone component of a pine processionary moth, and an intermediate for the conjugated Z-alken-yn-yl acetate under mild conditions at a high yield. More specifically, provided is a method for producing a conjugated Z-alken-yn-yl acetate (5) comprising the steps of: reacting an &#x3c9;-halo-2-alkynal (1) with an alkylidene triphenylphosphorane (3) through a Wittig reaction to obtain a conjugated Z-alken-yn-yl halide (4), and acetoxylating the conjugated Z-alken-yn-yl halide (4) into a conjugated Z-alken-yn-yl acetate (5). 

Method for producing an &#x3c9;-halo-2-alkynal

Targeting an insect pest having a carboxylic acid compound as a pheromone substance, provided is a sustained release pheromone preparation enabling a high amount of pheromone to be released during the control period. More specifically, provided is a sustained release pheromone preparation, comprising: a carboxylic acid compound to be released, and an ethylene-vinyl acetate copolymer membrane through which the carboxylic acid compound can permeate, wherein the preparation is targeted for an insect pest having the carboxylic acid compound as a pheromone substance.

Sustained release pheromone preparation targeting insect pest having carboxylic acid as pheromone substance

Method for producing a conjugated Z-alken-yn-yl acetate

Omega-halo-2-alkynal

Provided is a sustained release preparation capable of uniformly releasing therefrom a volatile chemical for a long period of time even if the amount of a liquid chemical remaining in a tubular container of the sustained release preparation becomes small. Also provided is a container for sustained release preparation, the container being tubular and comprising two layers of outer and inner layers, the inner layer having a thickness of 0.12 to 1.2 mm and having a foamed structure permitting the soaking-up of a liquid chemical to a height of at least 25 mm by capillarity. Also provided is a container unit for sustained release preparation, the unit comprising two or more of the container combined.

Sustained release preparation comprising a foamed capillary tube

Provided are 5-acetoxy-(E3)-3-pentenyl methoxymethyl ether which can be prepared in conventional reaction equipment and a method for preparing an (E3)-3-alkenyl acetate by using it. More specifically, 5-hydroxy-(E3)-3-pentenyl methoxymethyl ether obtained by reacting 4-formyl-(E3)-3-butenyl methoxymethyl ether with a reductant is reacted with an acetylating agent to prepare 5-acetoxy-(E3)-3-pentenyl methoxymethyl ether. (E3)-3-alkenyl methoxymethyl ether obtained by a coupling reaction between the 5-acetoxy-(E3)-3-pentenyl methoxymethyl ether and a Grignard reagent is treated with an acid, and then reacted with an acetylating agent to prepare the (E3)-3-alkenyl acetate.

5-acetoxy-(E3)-3-pentenyl methoxymethyl ether and method for preparing (E3)-3-alkenyl acetate using the same

Provided are a sustained releaser of sex pheromone substances and a method for controlling insect pest by using the releaser, each enabling to control the simultaneous release of a mixture of sex pheromone substances having different chemical structures of one insect pest or a mixture of sex pheromone substances of insect pests, and each enabling to release the sex pheromone substances at a fixed rate or greater during the infestation period or periods of the respective insect pest or pests. More specifically, provided is a sustained releaser of sex pheromone substances comprising one or more first sex pheromone substances selected from linear aliphatic aldehyde having 10 to 18 carbon atoms, one or more second sex pheromone substances selected from aldehyde-free aliphatic derivatives having 7 to 20 carbon atoms, and first and second chambers each made of polymer material, wherein all of the first sex pheromone substances or all of the first sex pheromone substances and some of the second sex pheromone substances are enclosed in the first chamber and the remainder of the sex pheromone substances is enclosed in the second chamber.

Sustained releaser comprising sex pheromone substances

Provided are a sustained release dispenser which can control the release of sex pheromone simultaneously toward two or more species of insect pests and can also release the sex pheromone in response to the generation period of insect pest and the pest control method toward two or more insect pests. Provided specifically is a sex pheromone sustained release dispenser comprising two or more sex pheromone substances, each substance being aliphatic derivative having 10 to 20 carbons, and first and second chambers wherein some or all of the sex pheromone substance having a smallest carbon number excluding a carbon number in a functional group is contained in a first polymer chamber and the remainder is contained in a second polymer chamber. Provided also is a pest control method for using the sex pheromone sustained release dispenser.

Sustained release dispenser comprising two or more sex pheromone substances

Provided are (Z,Z,E)-1-chloro-6,10,12-pentadecatriene that can be synthesized without an oxidation reaction and a method for preparing (Z,Z,E)-7,11,13-hexadecatrienal by using (Z,Z,E)-1-chloro-6,10,12-pentadecatriene while not using an oxidation reaction. More specifically, provided is a method for preparing (Z,Z,E)-7,11,13-hexadecatrienal including a step of reacting a Grignard reagent into which (Z,Z,E)-1-chloro-6,10,12-pentadecatriene is converted with ethyl orthoformate to obtain (Z,Z,E)-1,1-diethoxy-7,11,13-hexadecatriene, and a step of treating the (Z,Z,E)-1,1-diethoxy-7,11,13-hexadecatriene with an acid to obtain (Z,Z,E)-7,11,13-hexadecatrienal.

(Z,Z,E)-1-chloro-6,10,12-pentadecatriene and method for preparing (Z,Z,E)-7,11,13-hexadecatrienal by using same

Provided is a sustained releaser of a sex pheromone having a high release rate, especially preferably of a sex pheromone of an aliphatic acetate compound having 10 to 16 carbon atoms, wherein the release of the sex pheromone is controlled so that it can be released at a constant rate over a control period of a pest insect. More specifically, provided is a sustained pheromone releaser comprising a polymer container and having, enclosed therein, a mixture having a melting point of 15 to 35&#xb0; C. and being obtained by mixing a sex pheromone substance and a compound having a melting point of 10 to 40&#xb0; C.

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Joetsu, Japan

Takehiko Fukumoto