Canon Kabushiki Kaisha

Takehiko Aoyama

Takeshi Murakami

Yuki Yamamoto

Masahiro Watanabe

Tomohito Taniguchi

Taichi Sato

Noboru Miyagawa

Atsushi Uematsu

Arihiro Yamamoto

Shota Segawa

Masanori Yokoyama

Hidekazu Matsuda

Syoji Inoue

Yoshitaka Suzumura

Satoshi Koide

Takeshi Yoshidome

Harunobu Ogaki

Daisuke Miura

Takashi Anezaki

Akihiro Maruyama

Kenya Terada

Masataka Kodama

Kenichi Yamauchi

Hisao Kato

Hirofumi Kumoi

Mitsuhiro Kunieda

Daisuke Tanaka

Youhei Ikeda

A cleaning wiper blade comprises a hand grip part and an elastic part. The elastic part comprises a polyurethane. The polyurethane comprises a reactant of a composition including an isocyanate compound which includes diisocyanate and polyfunctional isocyanate, and an alcohol which includes polyfunctional alcohol. The diisocyanate has an aromatic ring in a molecule. When a molecule of the polyurethane is ionized with a mass spectrometer of a direct sample injection system, then obtained M1, M2 and M3 satisfy the is 0.013 to 0.300, and a concentration of the polyfunctional alcohol in the polyurethane is 0.12 mmol/g to 0.65 mmol/g.

Cleaning wiper blade

A vehicle wiper blade comprises a blade support part and a lip part coupled swingably with the blade support part via a neck. The lip part comprises polyurethane. The polyurethane comprises a reactant of a composition including an isocyanate compound which includes diisocyanate and tri- or higher functional polyfunctional isocyanate, and an alcohol which includes tri- or higher functional polyfunctional alcohol. The diisocyanate has an aromatic ring in a molecule. When a molecule of the polyurethane is ionized with a mass spectrometer of a direct sample injection system, then obtained M1, M2 and M3 satisfy the following relation: M2/M1 is 0.001 to 0.028, M3/M1 is 0.020 to 0.110, and M2/M3 is 0.013 to 0.300, and a concentration of the polyfunctional alcohol in the polyurethane is 0.12 mmol/g to 0.65 mmol/g.

Vehicle wiper blade

Provided is a cleaning member, comprising an elastic member that includes polyurethane, wherein: when tan δ of a test piece sampled from the elastic member is measured in the temperature range of −20° C. to +60° C., the peak temperature of a peak indicating the maximum value of tan δ is at 15.0° C. or below; the maximum value of tan δ is 0.20 to 0.55; tan δ at a temperature of 55° C. is 0.13 or larger; and where the detected quantity of all ions obtained when the test piece is heated at a rate of temperature increase of 10° C./second to 1000° C. using a direct-sampling mass spectrometer is Mand the integrated intensity of a peak in a derived ion thermogram that corresponds to a range of m/z values originating in multifunctional isocyanate with at least three isocyanate groups is M, M/Mis at least 0.001.

Cleaning member and elastic member

A vehicle windshield wiper blade comprising: a blade support portion; and a lip portion, wherein the lip portion has a tapered portion having a cross section that is taken along a direction perpendicular to the longitudinal direction of the wiper blade and that has a width that gradually decreases from a side closer to the blade support portion towards a direction farthest away from the blade support portion, the lip portion has a tip surface and first and second tapered surfaces constituting the tapered portion, and, in a specific observation region of the first and second tapered surfaces, the average value of the elastic modulus measured at a 0.1 μm pitch is 15-470 MPa and the coefficient of variation of the elastic modulus is at most 17.6%.

Vehicle windshield wiper blade

Provided is a charging member capable of suppressing the occurrence of an image defect due to the non-uniform abrasion of a photosensitive member and a stain, in a long-term use. The charging member includes an electro-conductive elastic layer as a surface layer. The electro-conductive elastic layer contains a binder and a bowl-shaped resin particle having an opening. The surface of the charging member has a concavity and a protrusion derived from the bowl-shaped resin particle. The relations represented by the following formulae are satisfied, wherein, when the charging member is pressed onto a glass plate with 100 (g) load, S1 is the average value of contact areas, d1 is the average value of heights of spaces formed in a contact region; and when the load is changed to 500 (g), S5 is the average value of contact areas, d5 is the average value of heights of spaces.

Charging member with electro-conductive elastic layer having exposed bowl-shaped resin particles, process cartridge and electrophotographic apparatus

A roller for electrophotography including a mandrel and an elastic layer on the mandrel is provided. The elastic layer contains a hollow particle in a region from the surface of the elastic layer to a depth of 100 &#x3bc;m. A cross-section of the hollow particle intersected by a first plane and a cross-section of the hollow particle intersected by a second plane each have a ratio of the length of the long axis to the length of the short axis of 1.2 or more and 1.9 or less.

Roller for electrophotography, process cartridge, and image-forming apparatus

The present invention directs to provide a charging member having a protrusion to which smear is difficult to adhere even in a long-term used, and as a result being capable of exhibiting stable charging performance. The charging member has an electro-conductive substrate and an electro-conductive surface layer, wherein the surface layer includes a binder resin and a resin particle including a plurality of electro-conductive domains inside thereof, the surface layer has a protrusion derived from the resin particle, and the electro-conductive domains are localized in the vicinity of the surface of the resin particle.

Charging member, method of producing the same, process cartridge, and electrophotographic apparatus

The electrophotographic member includes an electro-conductive substrate and an electro-conductive resin layer as the surface layer on the substrate. The electro-conductive resin layer contains a binder and a bowl-shaped resin particle; the surface of electrophotographic member has a concavity derived from the opening of the bowl-shaped resin particle, a protrusion derived from the edge portion of the opening and the electro-conductive resin layer; and when the surface of the member is observed using a scanning electron microscope at an accelerating voltage (1 kV) and a magnification (&#xd7;2000) while applying a DC voltage (50 to 100 V) between an electrode disposed opposite to the electrophotographic member and the substrate, the brightness of the protrusion, K, the brightness of the bottom of the concavity, K, and the brightness of the exposed surface of the electro-conductive resin layer, K, satisfy K&#x3c;K, K&#x3c;Kand 0.8&#x2266;K/K&#x2266;1.2.

Electrophotographic member having bow-shaped resin particles defining concavity and protrusion at surface thereof

There are provided an image forming apparatus in which the generation of lateral streak images due to a decrease in the in-nip discharge intensity is suppressed while at the same time the generation of spot-like images due to abnormal discharge caused by smudges on the surface of a charging member is suppressed, and a process cartridge. The image forming apparatus and the process cartridge each has:

Image forming apparatus and process cartridge utilizing a porous charging member

A charging member includes an electro-conductive substrate and an electro-conductive resin layer. The electro-conductive resin layer contains a binder, a plurality of bowl-shaped resin particles, and a plurality of hollow particles. The charging member has a surface having recesses due to openings of the bowl-shaped resin particles and protrusions due to edges of the openings of the bowl-shaped resin particles, where the positional relationship between one bowl-shaped resin particle and the hollow particles lying in the vicinity of the bowl-shaped resin particle is that the number of the hollow particles being in the space under the bowl-shaped resin particle in a predetermined depth is at least four in average.

Charging member, process cartridge, and electrophotographic apparatus

There are provided an image-forming apparatus that inhibit the occurrence of a longitudinal streak image attributed to a cleaning failure, and a process cartridge. The image-forming apparatus and the process cartridge each have a charging member with a surface having a concavities derived from an opening of the bowl-shaped resin particle, and a protrusions derived from an edge of the opening of the bowl-shaped resin particle, the coverage ratio X1 of a surface of the toner with the silica fine particles is 50.0 area % or more and 75.0 area % or less, and when a theoretical coverage ratio of the toner by the silica fine particles is X2, a diffusion index represented by the formula 1 satisfies the formula 2:diffusion index=&#x2003;&#x2003;(formula)diffusion index&#x2267;&#x2212;0.0042&#xd7;&#x2003;&#x2003;(formula)

Image-forming apparatus with electro-conductive resin layer having resin particles and process cartridge

Provided an electrophotographic image forming apparatus comprising an electrophotographic photosensitive member and a charging member. The electrophotographic photosensitive member includes a charge transport layer as a surface layer having a matrix-domain structure including specific resins. The charging member comprises an electro-conductive substrate, and an electro-conductive elastic layer. The electro-conductive elastic layer comprises a binder, and holding a bowl-shaped resin particle having an opening, so that at least a part of the bowl-shaped resin particle is exposed, and the charging member has a concavity derived from the opening of the bowl-shaped resin particle on the surface thereof, and a protrusion derived from an edge of the opening of the bowl-shaped resin particle on the surface thereof.

Electrophotographic image forming apparatus having charge transport layer with matrix-domain structure and charging member having concavity and protrusion

Uneven charging is improved, and production of a banding image attributed to a slip between the charging member and the electrophotographic photosensitive member is suppressed. An electrophotographic process cartridge including a charging member and an electrophotographic photosensitive member which is electrically charged upon being brought into contact with the charging member, wherein the charging member includes a electro-conductive substrate and a surface layer formed on the electro-conductive substrate; the surface layer contains at least a binder resin, an electron conductive agent, and a resin particle having a plurality of pores inside thereof; the surface of the surface layer has a protrusion derived from the resin particle; the electrophotographic photosensitive member includes a support and a photosensitive layer formed on the support; and the surface layer of the electrophotographic photosensitive member contains a specific component.

Electrophotographic process cartridge and electrophotographic apparatus

Provided is an electrophotographic member for an electrophotographic apparatus, which suppresses the occurrence of a banding image caused by uneven charging. The electrophotographic member includes: an electroconductive substrate; and a surface layer, in which: the surface layer includes a binder resin and an aggregate of at least one crystal particle selected from the group consisting of a flaky crystal particle of magnesium carbonate and a flaky crystal particle of calcium carbonate; an edge face of a card house structure formed of the crystal particle is exposed at a surface of the aggregate; a surface of the surface layer includes a convex portion derived from the aggregate; and a surface of the convex portion has unevenness reflecting a shape of the edge face of the card house structure exposed at the surface of the aggregate.

Electrophotographic member, process cartridge, and electrophotographic apparatus

Provided a charging member including an electro-conductive substrate and a surface layer. The surface layer includes a binder resin, and a resin particle that roughens the surface layer. A surface of the charging member has a plurality of protrusions each derived from the resin particle. The resin particle has a pore inside thereof, has a porosity Vt of 1.5% by volume or more and 45.0% by volume or less, and has a first and second regions. The first region has a porosity V, the second region thereof has a porosity V, and Vis larger than V

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Suntou-gun, Japan

Takehiko Aoyama