Adeka Corporation

Denso Corporation

Takayuki Taki

Hiroaki Watanabe

Atsuki Shibuya

Yuyu Ohnuma

Manabu Yamada

Akiko Tasaki

Hisashi Umemoto

Eiji Katsuno

Kyohei Usami

Kouhei Yamamoto

Atsuo Tomita

Hiroto Asano

Satoru Suzuki

Atsuski Shibuya

A nonaqueous electrolyte solution for secondary batteries, which maintains small internal resistance and high electrical capacitance in long-term use in a nonaqueous electrolyte secondary battery uses, as an active material, a crystalline carbon material having a high crystallinity, and a negative electrode produced using a polymeric carboxylic compound as a binding agent. The nonaqueous electrolyte solution contains: (A) at least one compound selected from a group consisting of an unsaturated phosphate ester compound represented by a general formula (1) and an unsaturated phosphate ester compound represented by a general formula (2); (B) at least one compound selected from a group consisting of a sulfite ester compound, a sulfonate ester compound, an alkali metal imide salt compound, a fluorosilane compound, an organic disilane compound or an organic disiloxane compound; (C) an organic solvent, and (D) an electrolyte salt. A secondary battery using such nonaqueous electrolyte solution is also described.

Nonaqueous electrolyte solution for batteries, and nonaqueous electrolyte secondary battery using same

An electricity storage device maintains low internal resistance and high electric capacity. The nonaqueous-electrolytic-solution hybrid electricity storage device employs an anode into/from which lithium can be intercalated and deintercalated and a cathode including activated carbon, even after high-temperature storage and/or high-temperature charging/discharging. Specifically, this electricity storage device includes an anode into/from which lithium can be intercalated and deintercalated, a cathode that includes activated carbon, and a nonaqueous electrolytic solution, wherein the electricity storage device employs a nonaqueous electrolytic solution that includes at least one type of compound represented by one of general formulas (1) to (5). Details on the general formulas (1) to (5) are as described in the Description.

Electricity storage device

The invention provides a nonaqueous electrolyte for batteries and a nonaqueous secondary battery using the same which maintains small internal resistance and high electric capacity in high temperature storage. The nonaqueous electrolyte has an electrolyte salt, a compound of general formula (1), and a compound of general formula (2) dissolved in an organic solvent. The ratio of the compound of formula (2) to the sum of the compound of formula (1) and the compound of formula (2) is 0.1 to 8 mass %. In the formulae, R, R, R, and Reach independently represent C1-C8 alkyl.

Nonaqueous electrolyte and nonaqueous secondary battery using same

A non-aqueous electrolyte secondary battery has a negative electrode containing graphite particles as a negative electrode active material, a positive electrode containing a lithium-containing oxide of a transition metal or a lithium-containing phosphate of a transition metal as a positive electrode active material, and a non-aqueous electrolyte in which a lithium salt is dissolved in an organic solvent. The graphite particles have an exposed crystal face and are bonded with each other to be parallel to the orientation plane of each other, and the non-aqueous electrolyte contains a phosphate ester compound represented by the following general formula (1) to which an alkynyl group is bonded and/or an unsaturated phosphate ester compound represented by the following general formula (2): 

Non-aqueous electrolyte secondary battery

Disclosed is a nonaqueous secondary battery using a positive electrode containing a transition metal and lithium. The battery is prevented from deterioration due to elution of the transition metal from the positive electrode and thereby capable of maintaining small internal resistance and high electrical capacity even after high temperature storage or high-temperature charge and discharge cycles. The battery includes a negative electrode capable of intercalating and deintercalating lithium, a positive electrode containing a transition metal and lithium, and a nonaqueous electrolyte having a lithium salt dissolved in an organic solvent, the nonaqueous electrolyte containing a polycarboxylic ester compound represented by general formula (1) or (2).

Nonaqueous secondary battery

Disclosed is a non-aqueous electrolyte secondary battery using a polyanion compound or a lithium nickelate as a positive electrode active material, suppressing the elution of a transition metal from the polyanion compound or ameliorating the deterioration of a binder by a residual alkali component, and provides a non-aqueous electrolyte secondary battery having a negative electrode intercalating and deintercalating lithium ions, a positive electrode containing a lithium-containing compound as a positive electrode active material, and a non-aqueous electrolyte with a lithium salt dissolved in organic solvent. The lithium-containing compound is a polyanion compound or a lithium nickelate. The non-aqueous electrolyte contains a fluorosilane compound:  Rto R: alkyl group having 1-8 carbon(s), an alkenyl group having 2-8 carbons, a cycloalkyl group having 5-8 carbons, an aryl group having 6-8 carbons or a fluorine atom. R: alkylene group having 1-8 carbon(s) or an alkylene group having 4-8 carbons having an ether group.

A non-aqueous electrolyte battery using a lithium-containing metal oxide containing manganese as a positive electrode active material, which can suppress the elution of manganese from the positive electrode active material. The non-aqueous electrolyte secondary battery has a negative electrode capable of intercalating and deintercalating lithium ions, a positive electrode containing a lithium-containing compound as a positive electrode active material, and a non-aqueous electrolyte in which a lithium salt is dissolved in an organic solvent. The lithium-containing compound is a lithium-containing metal oxide containing manganese, and the non-aqueous electrolyte contains a fluorosilane compound: Rto Reach represents a 1-8 carbon alkyl group, a 2-8 carbon alkenyl group, a 5-8 carbon cycloalkyl group, a 6-8 carbon aryl group or a fluorine atom, and Rrepresents a 1-8 carbon alkylene group or a 4-8 carbon alkylene group having an ether group.

A nonaqueous electrolyte solution in which an electrolyte salt is dissolved in an organic solvent includes, includes at least one or more compounds selected from the silicon compounds represented by general formula (1), (2), or (3) below: (In the formulae, each of R, R, and Rindependently represents a Calkyl, Calkenyl, Calkynyl, or Caryl group; Rrepresents a Calkylene, Calkenylene, Calkynylene, or Carylene group; and n represents 1 or 2. When n is 1, X represents a fluorine atom, trifluoromethyl group, Calkoxy group, Calkenyloxy group, Caryloxy group, or Cacyloxy group, Csulfonyloxy group, isocyanato group, isothiocyanato group, or cyano group. When n is 2, X represents a Calkylene group, Calkylenedioxy group, Calkenylene group, Calkenylenedioxy group, Calkynylene group, Calkynylenedioxy group, Carylene group, Carylenedioxy group, Cdiacyloxy group, oxygen atom, or direct bond.)

Nonaqueous electrolyte solution and secondary battery using the electrolyte solution

A conductive material mixed composition obtained by synthesizing a piperidyl group-containing high-molecular-weight polymer or copolymer that is composed of the constitutional unit represented by general formula (1) below and insoluble in tetrahydrofuran (THF) by polymerization in a liquid phase, immediately followed by mixing a conductive material with the polymer or copolymer in the liquid phase: wherein Rrepresents a hydrogen atom, a hydroxyl group, an oxyl radical, an alkyl group having 1 to 18 carbon atoms, or an alkoxy group having 1 to 18 carbon atoms; Rand Reach independently represent a hydrogen atom or a methyl group; Rrepresents a hydrogen atom, an alkali metal atom, an alkyl group having 1 to 50 carbon atoms, an alkenyl group having 1 to 50 carbon atoms, an alkyl group having 1 to 50 carbon atoms, or a haloalkyl group having 1 to 50 carbon atoms; n represents a number of not less than 30; and m represents 0 or a positive number.

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Tokyo, Japan

Takayuki Taki