Toray Industries, Inc.

Takayuki Hase

Satoshi Matsubara

Hideyuki Umetsu

Takuya Shibata

Masanori Kobayashi

Takanori Suga

Toshio Ishikawa

Katsuya Ogawa

Yoshiyasu Naito

Taku Shimozawa

Shingo Fujino

Taku Araki

Taeko Nito

Shinya Kuroda

Kazuaki Hirota

A transparent thermoplastic resin composition containing: based on 100 parts by mass of the transparent thermoplastic resin composition, 10 to 60 parts by mass of a graft copolymer (A) obtained by graft copolymerizing a monomer mixture (a) containing at least an aromatic vinyl-based monomer (a1) and a (meth)acrylic acid ester-based monomer (a2) in the presence of a rubbery polymer (R); 40 to 90 parts by mass of a vinyl copolymer (B) obtained by copolymerizing a monomer mixture (b) containing at least an aromatic vinyl-based monomer (b1) and a (meth)acrylic acid ester-based monomer (b2); 100 to 1,000 ppm of a phenolic compound (C); and a dihydrooxaphosphaphenanthrene-based phosphorus compound (D), wherein a molar ratio (P/OH) of a phosphorus atom (P) of the dihydrooxaphosphaphenanthrene-based phosphorus compound (D) to a hydroxyl group (OH) of the phenolic compound (C) is 0.2 to 5.0.

Transparent thermoplastic resin composition, production method therefor, molded article obtained by molding transparent thermoplastic resin composition, and production method for molded article

A transparent thermoplastic resin composition includes: 100 parts by mass of a transparent thermoplastic resin composition composed of 10 to 60 parts by mass of a graft copolymer (A) obtained by graft-copolymerizing a monomer mixture (a) containing at least an aromatic vinyl-based monomer (a1) and a (meth)acrylic acid ester-based monomer (a2) in the presence of a rubbery polymer (r), and 40 to 90 parts by mass of a vinyl-based copolymer (B) obtained by copolymerizing a monomer mixture (b) containing at least an aromatic vinyl-based monomer (b1), a (meth)acrylic acid ester-based monomer (b2), and a vinyl cyanide-based monomer (b3); and 15 ppm or more and 40 ppm or less of a polydimethyl siloxane gum (C) having a weight-average molecular weight of 300,000 or more.

Transparent thermoplastic resin composition and article molded thereof

A thermoplastic resin composition includes a graft copolymer (A) obtained by graft copolymerization of a monomer mixture (a) that includes at least an aromatic vinyl monomer (a1) and a (meth)acrylate monomer (a2), but does not practically contain a vinyl cyanide monomer (a3), in the presence of a rubbery polymer (r) having a refractive index of not lower than 1.510 and not higher than 1.520; and a vinyl copolymer (B). An acetone insoluble component (C) of the thermoplastic resin composition does not practically contain a vinyl cyanide monomer-derived unit. An acetone soluble component (D) of the thermoplastic resin composition contains the vinyl cyanide monomer-derived unit. The content of the vinyl cyanide monomer-derived unit is not lower than 2% by mass and not higher than 20% by mass relative to 100% by mass of the acetone soluble component (D).

Thermoplastic resin composition, manufacturing method of thermoplastic resin composition, molded product and manufacturing method of molded product

[Problem] To provide a material for fused-deposition-type three-dimensional modeling whereby a warp-free modeled object is obtained without devising a modeling shape and without installing a special apparatus as a 3D printer device, and whereby a modeled article having flexibility as well as excellent surface polishing properties is obtained. [Solution] A material for fused-deposition-type three-dimensional modeling, obtained by blending 10-900 parts by weight of a styrene-based resin (B1) obtained by copolymerization of an aromatic vinyl-monomer (b1) and a cyanated vinyl-monomer (b2), and/or 5-400 parts by weight of a thermoplastic resin (B2) having a glass transition temperature of 20&#xb0; C. or lower and/or 5-30 parts by weight of a plasticizer (B3), with respect to 100 parts by weight of a polylactic resin (A).

Material for fused deposition modeling type three-dimensional modeling, and filament for fused deposition modeling type 3D printing device

A thermoplastic resin composition includes 0.1 to 20 parts by weight of a carbon black relative to 100 parts by weight of a thermoplastic resin, wherein the carbon black is dispersed in the thermoplastic resin composition to have a maximum particle diameter of not greater than 50 &#x3bc;m.

Thermoplastic resin composition and molded product using the same

A monofilament for mowing characterized by being produced by spinning a resin composition, said resin composition comprising 70-97 parts by weight of a polylactic acid resin (A) and 30-3 parts by weight of an adipate plasticizer (B), each relative to 100 parts by weight of the sum of the polylactic acid resin (A) and the adipate plasticizer (B). Thus, the monofilament for mowing, which is biodegradable, shows an excellent mowing performance and has a high breakage resistance and high abrasion resistance, is provided.

Monofilament for mowing

A liquid crystalline polyester composition contains 100 parts by weight of a liquid crystalline polyester (A) and 10 to 100 parts by weight of a mica (B), wherein a rate in number of mica with a ratio (d/d) of a long diameter (d) to a short diameter (d) that is greater than 2.0, to an entire content of the mica (B) contained in the liquid crystalline polyester composition is not higher than 20%.

Liquid crystalline polyester composition and metal composite molded product using the same

A liquid crystalline polyester composition containing at least 100 parts by weight of liquid crystalline polyester (A) and 10 to 100 parts by weight of talc (B). The talc (B) has a ratio (a1/a2) of oil absorption (a1) ml/100 g to specific surface area (a2) m2/g in a range of 14.0 to 26.0 (ml&#xb7;g)/(100 g&#xb7;m2) and has a number-average particle diameter of 10 to 30 &#x3bc;m.

A liquid crystalline polyester composition contains at least 100 parts by weight of liquid crystalline polyester having different structural units and 10 to 100 parts by weight of glass fiber, wherein the glass fiber has a weight-average fiber length (Mw) of 200 to 500 &#x3bc;m, and content of specific glass fiber having fiber length of not less than 1500 &#x3bc;m is 0.1 to 5.0 percent by weight to a total amount of the glass fiber.

Liquid crystalline polyester composition, method of producing the same and molded product manufactured from the same

A liquid crystalline polyester composition contains at least 100 parts by weight of liquid crystalline polyester and 10 to 100 parts by weight of glass fiber, wherein the glass fiber has a weight-average fiber length of 30 to 100 &#x3bc;m, and content of specific glass fiber having fiber length of 300 to 500 &#x3bc;m is 0.1 to 5 percent by weight to a total amount of the glass fiber.

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Nagoya, Japan

Takayuki Hase