Nagoya University

Zeon Corporation

Toyota Jidosha Kabushiki Kaisha

Tokai National Higher Education and Research System

Takato Kajita

Atsushi Noro

Yushu Matsushita

Sadaharu Hashimoto

Kousuke Isobe

Haruka Tanaka

Naoki Nakamura

Atsushi Nozawa

Ryoji Kameyama

Takahiro Mori

A main purpose of the present invention is to provide a multi-block copolymer composition having good elasticity and excellent stress relaxation properties, as well as small tension set. The present invention achieves the purpose by providing a multi-block copolymer composition obtained by a modification treatment, the composition including a block copolymer B formed by introducing a functional group capable of forming a non-covalent bond to a block copolymer A; wherein the block copolymer A includes a block copolymer A1 having a specific primary structure and a block copolymer A2 having a specific primary structure, and the mass ratio (A1/A2) of the block copolymer A1 and the block copolymer A2 is 100/0 to 50/50.

Multi-block copolymer composition obtained by modification treatment, and film

A main object of the present invention is to provide a block copolymer composition which has good elasticity, while having excellent stress relaxation properties. The object is achieved by providing a block copolymer composition obtained by a modification treatment, the block copolymer composition comprising a block copolymer B formed by introducing a functional group capable of forming a non-covalent bond into a block copolymer A including at least one aromatic vinyl polymer block and at least one conjugated diene polymer block.

Block copolymer composition obtained by modification treatment, method for producing same, modified block copolymer composition used for same, and method for producing said modified block copolymer composition

The present invention provides a block copolymer composition comprising a block copolymer B formed by introducing a functional group capable of forming a non-covalent bond into a block copolymer A including at least one aromatic vinyl polymer block and at least one conjugated diene polymer block, wherein: the block copolymer B includes an ionic group as the functional group capable of forming a non-covalent bond.

Block copolymer composition including ionic group, and film

A proton conducting film includes a polymer having a first part and a second part which are connected by a covalent bond and a plasticizer. The first parts aggregate with each other to form a domain at an operation temperature of the proton conducting film, and the second part crosslinks the domains. The second part has a proton accepting group, and the plasticizer contains a proton donating compound having a pKa of 2.5 or less, and thus the plasticizer penetrates into the second part, and a glass transition temperature of the polymer is lowered compared to when the plasticizer is not included.

Proton conducting film having crosslinked structure and fuel cell

A proton-conductive membrane is provided, which exhibits high proton conductivity even in an anhydrous environment. The proton-conductive membrane includes a crosslinked polymer and a plasticizer, wherein the crosslinked polymer includes a proton acceptor group in an amount equal to not less than 10 mol % of repeating units constituting the crosslinked polymer, the plasticizer includes a proton donor compound having a pKa value of not more than 2.5, and the plasticizer is a viscoelastic solid in a temperature range of 50&#xb0; C. to 120&#xb0; C.

Proton-conductive membrane and fuel cell

A non-humidified proton-conductive membrane according to the present invention includes a polymer and a proton-conductive substance. The polymer includes a glassy or crystalline first site having a glass-transition temperature or melting temperature higher than the service temperature of the proton-conductive membrane and a second site capable of forming a noncovalent bond. The proton-conductive substance includes a proton-releasing/binding site capable of noncovalently binding to the second site of the polymer and a proton coordination site capable of coordinating to protons, the proton-releasing/binding site and the proton coordination site being included in different molecules that interact with each other or being included in the same molecule. A proton-conductive mixed phase that includes the second site to which the proton-releasing/binding site of the proton-conductive substance is bound and the proton-conductive substance is lower than the service temperature of the proton-conductive membrane. The amount of the proton-releasing/binding site is excessively large compared with the amount of the second site of the polymer.

Growing community of inventors

Nagoya, Japan

Takato Kajita