Nippon Kayaku Kabushiki Kaisha

Taiyo Nippon Sanso Corporation

Takashi Yoneda

Takashi Yoshida

Hiroaki Ohno

Akira Kawaguchi

Yasuo Shirasaki

Takahiko Matsui

Yoshiaki Kawaida

Takafumi Fujii

Yasuo Kuroda

Kenji Ooshima

Koji Hirota

Yoshinori Ito

Takashi Yoshimoto

Toru Yamaguchi

Takaaki Kurata

Tadayuki Kiyoyanagi

Shinsuke Shimizu

Taku Iino

Rima Akanuma

Makoto Teranishi

Junya Masegi

Kazunobu Nagasaki

Tomoki Fujita

Hiroyuki Tsukui

Makoto Sakane

Yuka Shishikura

Provided is an ink set for textile printing giving a good reproducible color gamut. The ink set includes a cyan ink and a violet ink that each contain a water-insoluble colorant and water. The cyan ink contains at least a compound represented by formula (1) below as the water-insoluble colorant, and the violet ink contains at least one selected from the group consisting of C.I. Disperse Violet 27 and C.I. Disperse Violet 28 as the water-insoluble colorant,

Ink set for textile printing and method of textile printing on fiber

An azo compound and an ink composition containing the azo compound are used as inks for ink jet recording and have excellent gas (ozone) resistance when recording is done on special ink jet paper. The azo compound is represented by formula (1) or a tautomer thereof, or a salt of these. In formula (1), Rrepresents a C1-C4 alkyl group, Rrepresents a cyano group, Rand Reach independently represent a C1-C4 alkoxy, R-Reach independently represent a group represented by formula (2), and R-Reach independently represent a nitro group. In formula (2), Ris an anilino group, and Ris a mono- or di-C1-C6 alkylamino group 

Azo compound, ink composition, ink jet recording method, and colored article

Provided is a porphyrazine dye suitable for use in ink-jet recording, the porphyrazine dye giving a cyan ink with a satisfactory hue, having various excellent fastness properties, in particular, ozone resistance, and attaining a high color density. Also provided is an ink composition containing the dye. The porphyrazine dye is a porphyrazine dye represented by formula (1) or a salt thereof. In formula (1), rings A to D each independently represents a benzene ring, a nitrogenous heteroaromatic ring, etc.; E represents an alkylene; X represents sulfoanilino, etc.; R represents a hydrogen atom, sulfo, carboxy, etc.; group F represents phenyl, a nitrogenous heteroaromatic ring, etc.; a is an integer of 1-6; b is 0.00-3.90, excluding 3.90, on average; c is 0.10-4.00, excluding 4.00, on average; and the sum of b and c is 1.00-4.00, excluding 4.00, on average.

Porphyrazine coloring matter, ink composition, recording method, and colored object

The present invention relates to a porphyrazine coloring matter or a salt thereof represented by the following formula (1) [wherein, the rings of A to D are each independently a benzene ring or a 6-membered nitrogen-containing heteroaromatic ring, E is alkylene, X is a sulfo-substituted anilino group or the like which may further have a substituent, Ris a C1-C6 alkyl group, b is 0.00 or more and less than 3.90 as an average value, c is 0.10 or more and less than 4.00 as an average value, and the sum of b and c is 1.00 or more and less than 4.00 as an average value]. The ink composition containing the porphyrazine coloring matter of the present invention has a good hue as a cyan ink, is excellent in various fastness properties, particularly in ozone fastness, allows a high print density, has properties hardly causing bronze phenomenon, and can provide a porphyrazine coloring matter suitable for inkjet recording and an ink composition containing this. 

Porphyrazine coloring matter, ink composition containing the same and colored product

The present invention relates to a porphyrazine coloring matter or a salt thereof represented by the following formula (1): [wherein, the rings A to D are independently a benzene ring or a nitrogen-containing heteroaromatic ring, the number of the nitrogen-containing heteroaromatic ring is more than 0.00 and less than 1.00 as an average value, the rest are benzene rings, E is alkylene, X and Y are a sulfo-substituted anilino group and the like, b is 0.00 or more and less than 3.90 as an average value, c is 0.10 or more and less than 4.00 as an average value, and the sum of b and c is more than 3.00 and less than 4.00 as an average value]. The ink composition containing the porphyrazine coloring matter of the present invention or a salt thereof is an ink composition which has a hue closer to the standard color as a cyan ink, is excellent in various fastnesses, particularly in ozone fastness, and can provide recorded images having a high print density and thus having a good balance, and further it is suitable for inkjet recording.

Azo compounds represented by general formula (1) or salts thereof are provided as highly water-soluble colorants which have hues of yellow, orange, brown or red, and excellent color development properties and which, when used in various recording processes, particularly in an inkjet recording process, ensure various excellent fastnesses such as light fastness, ozone fastness, and fading balance. Ink compositions containing the colorants are also provided. In general formula (1), Rto Rare each independently a hydrogen atom, C1-4 alkyl, C1-4 alkoxy, or the like; and X is C1-8 alkylenediamino, xylylenediamino, or the like. 

Azo compounds, ink compositions, and colored bodies

The present invention relates to a porphyrazine coloring matter represented by the following formula (1) or a salt thereof (wherein, the rings A to D are each independently a benzene ring or a 6-membered ring nitrogen-containing heteroaromatic ring, the number of said heteroaromatic rings is more than 0 and less than 1, E is alkylene, X is an anilino group or the like having at least one sulfo group or the like as a substituent, Y is a substituted monoalkylamino group or the like, b is 0 to 3, c is 0.1 to 3, and the sum of b and c is more than 3 and less than 4). By the present invention, a copper porphyrazine coloring matter suitable for inkjet recording which has a good hue as an cyan ink, is excellent in light fastness, ozone fastness and moisture fastness and does not cause bronze phenomenon can be provided. 

Porphyrazine coloring matter, ink composition and colored product

[Problem] The present invention provides a gas supply method by which a gas in a gas container can be effectively utilized. [Means for Solving the Problem] On the basis of: the maximum flow rate (a first preset flow rate (Q)) and the minimum flow rate (a second preset flow rate (Q)) at the place where the gas is used; a first preset pressure (P) at which the gas can be supplied at a first preset flow rate (Q); a second preset pressure (P) at which the gas can be supplied at a second preset flow rate (Q); a third preset pressure (P) which is higher than the first preset pressure (P); residual pressures (PA, PB) in gas containers (SA, SB); a supplied gas flow rate (Q); and the relationship between the residual pressures (PA, PB) and suppliable gas flow rates (QPA and QPB, respectively), the residual pressures (PA, PB) and the supplied gas flow rate (Q) are monitored and the gas supply is switched between the first gas container (SA) and the second gas container (SB).

Method for supplying gas

The present invention relates to a porphyrazine coloring matter represented by the following formula (1) or a salt thereof: wherein, the rings A, B, C and D shown by broken lines each independently represent a 6-membered ring having aromaticity, at least 1.0 of said rings A to D is a benzene ring and at least 0.5 of them is a nitrogen-containing heteroaromatic ring, when shown as an average value; E represents an alkylene group; X and Y are each independently an anilino group having 1 to 3 carboxy groups; and b is 0 to 3.4, c is 0.1 to 3.5, and the sum of b and c is 1.0 to 3.5, when shown as an average value. The present invention can provide a porphyrazine coloring matter suitable for inkjet recording, which has characteristics of having a good hue as cyan ink, excellent fastnesses, in particular, extremely excellent water fastness when printed on plain paper, and high solubility in water or a water-soluble organic solvent.

Porphyrazine coloring matter and ink composition containing the same

The present invention relates to an aqueous solution composition (water-based ink composition) containing a water-soluble naphthalocyanine coloring matter represented by the following formula (1): wherein, M represents a hydrogen atom, a metal atom, a metal oxide, a metal hydroxide or a metal halide, X represents a carbonyl group or a sulfonyl group, Wto Ware each independently a hydrogen atom, an ionic hydrophilic group or the like, at least one of Wto Wis a group other than a hydrogen atom, and n represents an integer number of 1 to 24, respectively, or a salt thereof, and a novel naphthalocyanine coloring matter, and said compound is useful as a near-infrared ray absorbent because it has a high absorption in the near-infrared region, and it is useful as a near-infrared ray absorbing water-based ink because it has an excellent storage stability in aqueous solution.

Water-soluble naphthalocyanine coloring matter and water-based ink containing the same

The present invention relates to a porphyrazine coloring matter represented by the following formula (1) or a salt thereof; wherein, each of the rings A to D independently represents a benzene ring or a 6-membered nitrogen-containing heteroaromatic ring, at least one or more thereof is a benzene ring, at least one of the rest is a nitrogen-containing heteroaromatic ring, E represents alkylene, X is an anilino group having a substituent and the like, Y represents an amino group; a hydroxy group; a mono- or di-alkylamino group or a nitrogen-containing heterocyclic group which may have a substituent, excepting for the combination in which Y is an amino group or a hydroxy group and X is a substituted anilino group, b is 0 to 2.9, c is 0.1 to 3, and the sum of b and c is 1 to 3. According to the present invention, a porphyrazine coloring matter suitable for inkjet recording which has a good hue as a cyan ink, is excellent in light fastness, ozone fastness and moisture fastness, and causes no bronze phenomenon can be provided.

Porphyrazine coloring matter, ink, ink set, and colored product

The present invention relates to a porphyrazine coloring matter represented by the following formula (1): (wherein, A, B, C and D independently represents a 6-membered ring having aromaticity, at least one or more is a benzene ring, at least one or more contains a nitrogen-containing heteroaromatic ring; in addition, E represents alkylene and each of X and Y independently represents a substituted or unsubstituted anilino group or a substituted or unsubstituted naphthylamino group; and b is 0 to 2.9, c is 0.1 to 3 and the sum of b and c is 1 to 3) which has a good hue as a cyan ink, is excellent in light fastness, ozone fastness and moisture fastness, and does not cause bronze phenomenon, as well as is thus suitable for inkjet recording.

Porphyrazine coloring matter, ink, ink set and colored product

A novel azo compound represented by the following Formula (1) wherein A represents the following Formula (2) and is located preferably in a position meta or para to the azo group; Rand Reach independently represents hydrogen, carboxy, sulfo, nitro, Calkoxy, etc.; Rand Reach independently represents hydrogen, halogeno, cyano, carboxy, sulfo, nitro, Calkyl, hydroxy, or Calkoxy; and n is 0 or 1. [In the Formula (2), Rrepresents cyano, carboxy, Calky, Calkoxycarbonyl, or phenyl; and R, R, and Reach independently represents hydrogen, halogeno, cyano, carboxy, sulfo, nitro, Calkyl, Calkoxy, or acylamino.] The compound is useful as a black dye, especially one for ink compositions for, e.g., inkjet prints. Also provided are: an ink composition which contains the compound and has excellent storage stability; and a print obtained through recording with the ink. The print is excellent in light resistance, ozone resistance, fastness to moisture, etc.

Azo compound, ink composition, and colored object

The present invention relates to a water-based black ink composition comprising a water-soluble black dye (A) exhibiting ozone fastness and a condensate compound (B) of 4,4'-dinitrostilbene-2,2&#x2032;-disulfonic acid and aminobenzenes or a reduction product (C) thereof. Said ink composition is suitable for use in ink-jet recording, and realizes neutral hue and black color of high printing density. Further, a printed matter obtained is excellent in ozone gas fastness, light fastness, moisture fastness and color rendering properties. Still further, storage stability as a recording liquid is excellent.

Water-base black ink composition and colored product

The present invention relates to an azo compound represented by the following formula (1): (wherein, in the formula (1), Rrepresents a hydrogen atom; a hydroxyl group; a carboxyl group; a (C-C)alkyl group which may be substituted by a hydroxyl group or a (C-C)alkoxy group; or the like, and A represents an aliphatic amine residue having a carboxyl group or a sulfo group, respectively;) or a salt thereof; an ink composition containing the same; and an inkjet recording method and a colored object using the same. Said azo compound has a high color value and has a hue between yellow and red or a brown hue. The ink containing said azo compound has satisfactory storage stability, and exhibits, when printed therewith, a stable ejection property even on a thermal type inkjet printer, and gives a print of high quality (superior in light fastness, ozone gas fastness and moisture fastness).

Growing community of inventors

Tokyo, Japan

Takashi Yoneda