Shinko Pantec Co., Ltd.

Mitsubishi Corporation

Takashi Sasaki

Hiroyuki Harada

Kiyoshi Hirai

Shinichi Yasui

Hiroko Kobayashi

Mamoru Nagao

Akira Asari

Akihiko Hogetsu

Masanori Sugisawa

Yoshihito Nishimoto

A simple and efficient apparatus for producing hydrogen and oxygen is disclosed, wherein resistance to the flow of deionized water, oxygen gas, and hydrogen gas does not increase, and the amount of electric energy required for electrolysis can be reduced. A bipolar-type apparatus for producing hydrogen and oxygen, wherein a main water feeding path is formed in the approximate center of electrode plates in the axial direction, and an anode chamber and a cathode chamber are formed on opposing surfaces of the electrode plates to store porous conductors. A secondary water feeding path for the anode chamber directs water from the main water feeding path to the anode chamber. On the cathode side of the apparatus, a hydrogen gas collecting chamber is formed, a plurality of radial hydrogen gas paths are formed from the cathode chamber to the hydrogen gas collecting chamber, and a hydrogen gas discharging path are formed to axially hydrogen gas collecting chambers in each electrode plate. On the anode side of the apparatus, an oxygen gas path is formed from the anode chamber to the oxygen gas collecting chamber, and an oxygen gas discharging path is formed to axially connect to the oxygen gas collecting chambers in each electrode plate.

Apparatus for producing hydrogen and oxygen

An apparatus for controlling dissolved oxygen concentration in primary and secondary cooling water in boiling water and pressurized water atomic reactors is disclosed. The apparatus contains an electrolytic cell having an anode chamber and a cathode chamber separated from one another by a diaphragm of a solid polymer electrolyte membrane. The diaphragm contains: (a) an ion exchange membrane and (b) a pair of multilayered electrodes chemically plated to both surfaces of the ion exchange membrane. The electrolytic cell is operatively connected to a circular route for cooling water in the reactor, and hydrogen gas generated through electrolysis of deionized water in the cathode side of the cell is introduced into the circular route for the cooling water to control the dissolved oxygen concentration of the cooling water.

Control apparatus for oxygen concentration of water in atomic reactor

An apparatus for producing hydrogen and oxygen having a pressure vessel surrounding a bipolar-type water electrolytic cell The electrolytic cell contains a plurality of joined solid electrolyte membrane units, and each solid electrolyte membrane unit contains a solid electrolyte membrane, porous conductors in contact with opposing surfaces of the solid electrolyte membrane, and bipolar-type electrode plates in contact with each porous conductor, wherein each electrode plate is capable of performing as an anode and a cathode. A gap is present between the interior of the pressure vessel and the exterior of the water electrolytic cell to form a water pressure regulating chamber, and water of a preselected pressure can be fed into the water pressure regulating chamber such that the pressure differential between the pressure inside the water electrolytic cell and the pressure inside the water pressure regulating chamber is maintained within the pressure differential tolerance range of the water electrolytic cell.

A hydrogen/oxygen gas generating system includes a deionized water container and a cell for water electrolysis having anode and cathode compartments, the cell being submerged in deionized water in the container. Oxygen gas generated in the anode compartment is channeled to an oxygen gas separating chamber defined in the container at its top whereas hydrogen gas generated in the cathode compartment is channeled to a gas/liquid separator. The pressures of these gases are detected, and in accordance with the detected gas pressures, a first gas piping line for delivering oxygen gas outward from the oxygen gas separating chamber and a second gas piping line for delivering hydrogen gas outward from the separator are controlled such that the differential pressure between the gases may fall in a limited range. Water level in the oxygen gas separating chamber and water level in the gas/liquid separator are detected, and the detected levels are utilized to control the pressures and the supply of deionized water into the container. The system can generate hydrogen and oxygen gases of high purity under high pressure in a safe manner without a need for gas compressors.

Hydrogen and oxygen gas generating system

An electrolytic solution prepared by dissolving an electrolyte such as KOH in pure water is fed into a membrane electrolytic cell of a membrane electrolyzer membrane electrolysis, made while the membrane electrolytic cell is provided intermittently or continuously with pure water. Oxygen generated at the anode and hydrogen generated at the cathode are purified individually by purifiers to produce oxygen and hydrogen of high purity. Also disclosed are methods of producing oxygen and hydrogen of high purity and their corresponding apparatuses in which a membrane degassing module is employed in conjunction with a solid polymer electrolyte electrolytic cell for effecting membrane electrolysis of the pure water, and in conjunction with a molecular sieve for individually dehumidifying oxygen generated at the anode and hydrogen at the cathode of the electrolytic cell.

Methods and apparatuses for producing high purity oxygen and hydrogen

A method for regenerating a waste liquor containing nitric acid and hydrofluoric acid to recover highly pure nitric and hydrofluoric acids therefrom. The method comprises adding hydrofluoric acid, or an acid mixture of nitric and hydrofluoric acids having a major content of the hydrofluoric acid, to a nitric acid and hydrofluoric acid waste liquor, and subjecting the resulting mixture to dialysis with an ion-exchange electrodialyzer to recover the dialyzed acids. The acid-removed solution is neutralized to cause a precipitate to form and the precipitate is separated. The resultant solution is subjected to an ion-exchange membrane electrodialyzer using a combination of a bipolar membrane, an anion-exchange membrane and a cation-exchange membrane for separation into the acids and the alkali, which are subsequently recovered. The process has a high current efficiency and high recovery rates for acids.

Growing community of inventors

Hyogo, Japan

Takashi Sasaki