Research Association for Utilization of Light Oil

Idemitsu Kosan Company, Limited

Takashi Murakawa

Hisashi Katsuno

Toshikazu Yoneda

Michio Sugimoto

Takashi Yamamoto

Nobuyuki Takahashi

Tomoaki Hirano

There is disclosed a process for regenerating a deactivated catalyst containing a zeolite and a noble metal of group VIII of the Periodic Table supported thereon which comprises subjecting the deactivated catalyst to decoking treatment under reductive or oxidative condition and subsequently to contact treatment with a solution containing a halogen or a halogen-containing compound and thereafter calcining the deactivated catalyst. According to the above process, the catalytic activity of a deactivated catalyst is restored to the level comparable to that of a fresh catalyst by the use of an inexpensive regenerating agent and simplified steps. Thus, the regeneration process is expected to find effective use in petroleum refinery, petrochemical industry, etc.

Process for regenerating a deactivated catalyst

The catalyst is an L-type zeolite with platinum supported thereon, which is then treated with a halogen-containing compound. The catalyst has a long catalyst life and is extremely useful for the preparation of aromatic hydrocarbons from aliphatic hydrocarbons. The process using the catalyst provides a production of aromatic hydrocarbons with a high yield.

Catalyst for production of aromatic hydrocarbons and process for

Catalyst for production of aromatic hydrocarbons

A process for producing aromatic hydrocarbons in a high yield by introducing a naphtha fraction the cyclopentane content of which is controlled to not more than 1% by weight, or the methylpentane content is controlled to not more than 10% by weight, in a catalytic reaction tower, and contacting with a catalyst comprising a large pore zeolite containing at least one of Group VII metals of the Periodic Table. In this process, the catalyst cycle is greatly lengthened.

Process for production of aromatic hydrocarbons

A process for restoring deactivated catalysts containing zeolite with a noble metal of Group VIII of the Periodic Table and to be used in the production of aromatic compounds, wherein decoking of the deactivated catalysts is carried out in the presence of halogen or a halogen-containing compound. This restoration process permits effective restoration of deactivated catalysts and thus is expected to be employed in the fields of petroleum purification, petrochemistry and so forth.

Process for restoring deactivated catalysts

A process for producing aromatic hydrocarbons which comprises contacting at least one type of hydrocarbon selected from paraffin, olefin, acetylene, cyclic paraffin and cyclic olefin-based hydrocarbons with a catalyst comprising a L-type zeolite treated with a halogen-containing compound and platinum deposited thereon.

Catalyst for the production of aromatic hydrocarbons and process for the

A catalyst for production of aromatic hydrocarbons and a process for producing aromatic hydrocarbons from various hydrocarbons using said catalyst are disclosed. The catalyst comprises a L-type zeolite treated with a halogen-containing compound and platinum deposited thereon, which is of high activity and then has a long service life. The process of the present invention using the catalyst enables to produce aromatic hydrocarbons in a yield as high as not less than 80% for a long time. The hydrocarbon feedstock is selected from paraffin, olefin, acetylene, cyclic paraffin, and cyclic olefin-based hydrocarbons.

Growing community of inventors

Sodegaura, Japan

Takashi Murakawa