Nippon Oil Company

Petroleum Energy Center

Petroleum Energy Center Foundation

Takashi Ino

Yasuo Nakatsuka

Koichi Kato

Satoru Ikeda

Iwao Anzai

Minoru Hatayama

Toshiyuki Enomoto

Kazuya Nasuno

Seigou Shibata

Kazumasa Hamatani

Nobuyuki Miyajima

Tadashi Seike

Yuzo Fujino

There is provided a catalyst that is highly resistant to sulfur and nitrogen compounds and active for hydrogenation and shows a low hydrocracking rate and a long service life as well as a method of converting aromatic hydrocarbons in hydrocarbon oil containing sulfur and nitrogen compounds into saturated hydrocarbons by using such a catalyst. A method of hydrogenating aromatic hydrocarbons in hydrocarbon oil containing 80 wt % or more of a fraction having a boiling point of 170 to 390&deg; C. and said aromatic hydrocarbons is characterized in that the hydrocarbon oil is brought into contact with hydrogen in the presence of a catalyst containing clay minerals having principal ingredients of Si and Mg as carrier and at least one of the VIII-group metals of periodic table as active metal.

Method of hydrogenating aromatic hydrocarbons in hydrocarbon oil

A heavy fraction oil is catalytically cracked by contacting the oil with a catalyst containing an ultrastable Y-type zeolite, in a fluid catalytic cracking apparatus having a regenerating zone, a reaction zone, a separation zone and a stripping zone and under conditions that a reaction zone outlet temperature is in a range of 550 to 700.degree. C., a catalyst/oil ratio is in a range of 15 to 100 wt/wt, and a difference between a regenerating zone catalyst concentration phase temperature (1) and the reaction zone outlet temperature (2) is in a range of 5 to 150.degree. C. According to the fluid catalytic cracking process, an amount of dry gases generated by the thermal cracking of the heavy fraction oil can be lessened while a yield of light fraction olefins can be enhanced.

Process for fluid catalytic cracking of heavy fraction oil

A process of producing a fuel gas for fuel cells, which comprises the steps of: a) treating kerosine having a sulfur content not higher than 5 ppm with a desulfurizing agent to reduce the sulfur content of said treated kerosine to 0.2 ppm or less and b) contacting said treated kerosine from step a) with a steam reforming catalyst to provide a fuel gas mainly composed of hydrogen, said desulfurizing agent in step a) comprising a copper-nickel alloy having a copper to nickel ratio by weight of 80:20 to 20:80 and at least one carrier selected from the group consisting of Al.sub.2 O.sub.3, ZnO and MgO, and the total content of copper and nickel in terms of metals in said desulfurizing agent being in the range of 40 to 70% by weight.

Process for producing fuel gas for fuel cell

A process for the fluid catalytic cracking of heavy fraction oils containing heavy metals such as Ni and V, which comprises withdrawing a portion of ferrite-containing catalyst particles circulating in a fluid catalytic cracking apparatus, separating the thus withdrawn catalyst particles into metals-richly deposited catalyst particles and metals-poorly deposited ones by using a magnetic separator and then returning the metals-poorly deposited catalyst particles, together with fresh ferrite-containing catalyst particles, into said cracking apparatus.

Fluid catalytic cracking with a zinc ferrite-containing catalyst

A method of producing a catalyst for converting hydrocarbons involves spray-drying a slurry containing crystalline aluminosilicate zeolite and magnesium silicate mineral. The magnesium silicate mineral functioning as a metal trap contains 10 to 60 wt % of magnesium as an oxide. The magnesium silicate mineral has been treated with a phosphorus-containing solution.

Method of producing catalyst for converting hydrocarbons

A catalyst for the steam reforming of hydrocarbons characterized in that 0.1-2 wt. % of ruthenium is carried on a carrier which comprises 5-40 wt. % of ceria or rare element oxides containing ceria as the main ingredient and 60-95 wt. % of alumina, and that an atomic ratio of cerium to ruthenium (Ce/Ru) in the catalyst is in the range of from more than 10 to 200.

Catalysts for the high-temperature steam reforming of hydrocarbons

This invention provides a method of manufacturing a hydrocarbon conversion catalyst by spray-drying a slurry containing alumina-magnesia and a crystalline aluminosilicate zeolite, which is characterized in that the alumina-magnesia is treated with phosphoric acid containing solution before or after the slurry is subjected to a treatment of spray-drying.

Growing community of inventors

Yokohama, Japan

Takashi Ino