Mitsui Petrochemical Industries, Ltd.

Takashi Hayashi

Masahide Tanaka

Tetsuo Hayashi

Hiroo Wamura

Shunyo Uesugi

Kinya Mizui

Kazunori Takahata

Tadaaki Fujimoto

Hajime Oyoshi

Masayasu Ishibashi

Hidenori Kaya

Kenji Shimamoto

Kazuyuki Watanabe

Kunihiko Takeuchi

A monocarbonate represented by the formula (R.sup.1).sub.n Ph--O(R.sup.2 O).sub.m --CO--O--CH.sub.2 --C(R.sup.3)(R.sup.4)(R.sup.5), a lubricating oil containing this monocarbonate, and a process for preparing a composition of this monocarbonate, a monocarbonate to which are bonded, via carbonic acid, two (R.sup.5)(R.sup.4)(R.sup.3)C--CH.sub.2 -- groups and a monocarbonate to which are bonded, via carbonic acid, two (R.sup.1).sub.n Ph--(OR.sup.2).sub.m -- groups. The monocarbonate exhibits excellent lubricating property, cleaning property and electrically insulating property, exhibits excellent compatibility with hydrogenated fluorocarbons such as R-134a, and can be favorably used as a lubricating oil for refrigerators such as electric refrigerators and air conditioners for room.

Monocarbonates, use thereof and process for the preparation of

Lubricating oil containing aromatic ether compounds

The polycarbonates of the present invention include those of sucrose series having a specific cyclic structure, those of oligosaccharide and monosaccharide series other than the sucrose series, those derived from specific saccharides having no cyclic structure, those having a skeletal structure of pentaerythritol, neopentyl glycol or trimethylolmethane, and specific dicarbonates. The lubricating oil and electrical insulating oil of the invention contain the above-mentioned polycarbonates. The polycarbonates of the invention are excellent in compatibility with Freon R-134a (HFC) as well as in lubricating properties, detergency and electrical insulating properties, and are capable of providing lubricating oil for refrigerator, automotive engine oil, automotive gear oil, lubricating oil for rolling and lubricating oil for fiber, especially lubricating oil for which electrical insulating properties are required, and electrical insulating oil.

Polycarbonates, uses thereof, processes for preparing and purifying same

The polycarbonates of the present invention include those of sucrose series having a specific cyclic structure, those of oligosaccharide and monosaccharide series other than the sucrose series, those derived from specific saccharides having no cyclic structure, those having a skeletal structure of pentaerythritol, neopentyl glycol or trimethylolmethane, and specific dicarbonates. The lubricating oil and electrical insulating oil of the invention contain the above-mentioned polycarbonates. The polycarbonates of tile invention are excellent in compatibility with Freon R-134a (HFC) as well as in lubricating properties, detergency and electrical insulating properties, and are capable of providing lubricating oil for refrigerator, automotive engine oil, automotive gear oil, lubricating oil for rolling and lubricating oil for fiber, especially lubricating oil for which electrical insulating properties are required, and electrical insulating oil.

A polycarbonate lubricating oil composition which is resistant to decomposition of the polycarbonate and the generation of carbon dioxide gas. The lubricating oil composition contains a polycarbonate lubricant, at least one compound selected from the group of epoxy compound, phenol compound, sulfur compound and amine compound, and optionally a triester phosphite or a triester phosphate compound as inhibitors to the generation of carbon dioxide gas. The lubricating oil composition are stable, have excellent lubricating properties, cleaning properties, and electrical insulating properties, and their viscosity at low temperature can readily be lowered.

Lubricating oil composition

Disclosed herein is a process for the production of cycloolefin random copolymers comprising flash drying a solution of a cylcoolefin random copolymer in a hydrocarbon, said solution being obtained by copolymerization of ethylene and a specific cycloolefin in said hydrocarbon in the presence of a catalyst. Further proposed herein is a process for the production of cycloolefin random copolymers by copolymerization of ethylene with a specific cycloolefin of the in a hydrocarbon in the presence of a catalyst wherein said copolymerization is carried out in a polymerization reactor where a gas phase is not substantially present.

Process for producing cycloolefin random copolymers

Disclosed herein is a process for the production of cycloolefin random copolymers comprising flash drying a solution of a cylcoolefin random copolymer in a hydrocarbon, said solution being obtained by copolymerization of ethylene and a specific cycloolefin in said hydocarbon in the presence of a catalyst. Further proposed herein is a process for the production of cycloolefin random copolymers by copolymerization of ethylene with a specific cycloolefin of the in a hydrocarbon in the presence of a catalyst wherein said copolymerization is carried out in a polymerization reactor where a gas phase is not substantially present.

Disclosed herein is a process for the production of cycloolefin random copolymers comprising flash drying a solution of a cylcoolefin random copolymer in a hydrocarbon, said solution being obtained by copolymerization of ethylene and a specific cycloolefin in said hydrocarbon in the prsence of a catalyst. Further proposed herein is a process for the production of cycloolefin random copolymers by copolymerization of ethylene with a specific cycloolefin of the in a hydrocarbon in the presence of a catalyst wherein said copolymerization is carried out in a polymerization reactor where a gas phase is not substantially present.

Process for producing cycloolefin random copolymer

Disclosed herein is a process for the production of cycloolefin random copolymers comprising copolymerizing ethylene with at least one specific cyclooloefin in a liquid phase in the presence of a catalyst and a solvent in a polymerization vessel, wherein ethylene is copolymerized with the cycloolefin while feeding the cycloolefin or a mixture of the cycloolefin and the solvent onto inside circumferential wall of the polymerization vessel above the gas-liquid interface in the polymerization vessel. The proposed process ensures a smooth copolymerization reaction and a continuous and stable running of the apparatus for a prolonged period of time, and is productive of ethylene-cycloolefin random copolymers which have a uniform quaility and are excellent in heat resistance, heat aging property and various mechanical properties.

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Yamaguchi, Japan

Takashi Hayashi