Nitto-denko Corporation

Takao Yoshikawa

Shigeki Muta

Masahiro Ohura

Masahiro Oura

Hitoshi Takahira

Takaaki Moriyama

Kazuyuki Kitakura

Hiroaki Kishioka

Kazuhito Hosokawa

Mitsuhiko Hori

Takuya Shishido

Yuji Toyota

Tetsuo Inoue

Yasuyuki Tokunaga

Chie Matsumoto

Yoshinao Kitamura

Sachiko Sakamoto

Katsunari Oji

Yoshimitsu Shimomura

The present invention aims to provide a method and an apparatus for producing a lyophilized body, each of which can achieve energy saving, low cost, and a reduction in processing time and can provide a lyophilized body less damaged by a freezing process and a drying process. The present invention relates to a method for lyophilizing a substance using an electromagnetic wave, and the lyophilization method includes freezing the substance under irradiation of at least an electromagnetic wave and reduced-pressure drying the frozen substance under irradiation of at least an electromagnetic wave.

Method for manufacturing freeze-dried body and manufacturing device for same

A pressure-sensitive adhesive sheets comprising a layer of a crosslinked pressure-sensitive adhesive, which is formed by an acrylic polymer made of a homopolymer or copolymer of a monomer containing a (meth)acrylate as a principal component, a silane coupling agent and a crosslinking agent, wherein a sol component of the crosslinked pressure-sensitive adhesive has a weight-average molecular weight of not less than 300,000 and a proportion of a low-molecular component having a molecular weight of not more than 100,000 in the sol component is not more than 15% by weight in the measurement of the molecular weight by the gel permeation chromatography method, which the sheet cause neither lifting nor formation of bubbles at the bonding interface even when exposed to severe conditions such as high temperature or high temperature and humidity in case a functional film is bonded/fixed to a display device, thus making it possible to maintain good appearance for a long period.

Pressure-sensitive adhesive sheets and method of fixing functional film

The present invention provides a pressure-sensitive adhesion sheet being excellent in moisture and heat resistance and having a high adhesion to inorganic materials such as glass and tile, particularly a high adhesion even under high temperature and high humidity conditions, without using a silane coupling agent. The pressure-sensitive adhesion sheet for a silicone oxide-containing material comprises a base material having formed on at least one surface thereof a layer composed of an acrylic pressure-sensitive adhesive, wherein the base material is selected from a foamed base material having a water absorption rate less than 15% by weight after having been immersed in warm water having a temperature of 40&deg; C. for 24 hours and a plastic film having a water vapor permeability of 500 g or less/m /24 hours, and the acrylic pressure-sensitive adhesive to be used in combination with the base material selected is specified.

Pressure-sensitive adhesion sheets for silicone oxide-containing material

A pressure-sensitive adhesive sheet prepared by coating a composition containing a) 100 parts by weight of monomers composed of from 70 to 100% by weight of a (meth)acrylic acid alkyl ester, said alkyl group having from 2 to 14 carbon atoms, and from 0 to 30% by weight of a monoethylenically unsaturated monomer copolymerizing therewith, b) from 0.1 to 5 parts by weight of a radical chain inhibitor, c) from 0.02 to 5 parts by weight of a polyfunctional (meth)acrylate as a crosslinking agent, d) from 0.005 to 1 part by weight of a photopolymerization initiator, and e) from 0.01 to 10 parts by weight of a silane coupling agent, on a releasing-treated film having a good surface smoothness and photopolymerizing the coated layer to form a pressure-sensitive adhesive layer having a haze value of 1% or lower and a total light transmission of at least 90%. The pressure-sensitive adhesive sheet is excellent in the transparency, the foaming resistance, the low out-gas property, and the discoloring resistance (heat resistance and weather resistance).

Pressure-sensitive adhesive sheets comprising photo-polymerization product and production method thereof

Adhesive sheets using an acrylic pressure-sensitive flame-retardant adhesive having excellent properties such as adhesive force and holding power at high temperature and also having a self fire-extinguishing property which instantaneously extinguishes fire, i.e., a flame-retardance, are provided. A photopolymerizable composition comprising a) 100 parts by weight of a monomer (or the oligomer thereof) comprising 70 to 100% by weight of a (meth)acrylic acid alkyl ester having on the average a carbon number of 2 to 14 in the alkyl group and 30 to 0% by weight of a monoethylenically unsaturated monomer copolymerizable with the ester, b) 0.02 to 5 parts by weight of a polyfunctional (meth)acrylate as a crosslinking agent, c) 0.01 to 5 parts by weight of a photopolymerization initiator, and d) 10 to 180 parts by weight of a flame retardant having a melting point of at least 60&deg; C. is prepared, a pressure-sensitive flame-retardant adhesive is prepared from the photopolymerized product of the composition, and the adhesive is formed on one or both surfaces of a substrate.

Photopolymerizable composition, pressure-sensitive flame-retardant adhesive, and adhesive sheets

An adhesive sheet (,) in which heat-conductive and pressure-sensitive adhesive layers (,) which comprise a) a copolymer of a monomer mixture containing main monomers comprising as main component an alkyl (meth)acrylate carrying an alkyl group having from 2 to 14 carbon atoms on average and from 1 to 30% by weight, based on the above main monomers, of a polar monomer having a glass transition point, as a homo-polymer, of &deg; C. or lower; and b) from 10 to 300 parts by weight, per 100 parts by weight of the copolymer, of a heat-conductive filler are formed on both surfaces of a heat-conductive base material (,) is inserted between an electronic part (,) and a heat-radiating member (,) to thereby adhere and fix the heat-radiating member (,) to the electronic part (,) while providing a high heat-conductivity with the heat-conductive and pressure-sensitive adhesive layers (,).

Thermally conductive pressure-sensitive adhesive and adhesive sheet containing the same

A peelable heat-conductive and pressure-sensitive adhesive is disclosed, which comprises: (a) 100 parts by weight of a polymer produced from a monomer mixture comprising from 70 to 100% by weight of one or more alkyl (meth)acrylates in which the alkyl groups on the average have 2 to 14 carbon atoms and from 0 to 30% by weight of one or more monoethylenic monomers copolymerizable therewith, each based on the amount of the monomer mixture; (b) from 20 to 400 parts by weight of a plasticizer having a boiling point of 150&deg; C. or higher; and (c) from 10 to 1,000 parts by weight of a heat-conductive filler. Also disclosed is an adhesive sheet comprising a substrate and, formed on one or each side thereof, a layer of the adhesive. The pressure-sensitive adhesive can exhibit tight adhesion during use and easy peeling after use.

Peelable heat-conductive and pressure-sensitive adhesive and adhesive sheet containing the same

The present invention provides a heat-conductive and pressure-sensitive adhesive sheet comprising an electrical insulating plastic film having formed on one or both of the surfaces thereof (1) at least one thin layer composed of an inorganic material selected from the group consisting of ceramics, metals and metal oxides other than ceramics, and (2) a pressure-sensitive adhesive composition layer formed on the thin layer. The heat-conductive and pressure-sensitive adhesive sheet is excellent in heat-conductivity and pressure-sensitivity, results in no trouble such as complicated procedures in the production process or worsened working environment, exhibits good adhesion between the base material and the pressure-sensitive adhesive composition layer, scarcely undergoes anchoring fracture between the base material even after allowing to stand at high temperatures for a long time, and has good heat resistance.

Heat-conductive and pressure-sensitive adhesive sheets and method for fixing electronic parts to heat-radiating members with the use of the same

Pressure-sensitive adhesive having excellent heat resistance and heat

Pressure-sensitive adhesive of (meth)acrylate, unsaturated acid,

Thermally conductive pressure-sensitive adhesive, adhesive sheet

Heat-conductive and pressure-sensitive adhesive sheets which are excellent in heat resistance, scarcely undergo anchoring fracture between the base material and the adhesive layer and, therefore, are usable in fixing electronic parts to heat-radiating members or fixing members in various fields including constructive materials, vehicles, aircrafts and ships. the heat-conductive and pressure-sensitive adhesive sheets are in the form of sheets, tapes, etc. wherein a layer of a heat-conductive and pressure-sensitive adhesive composition, which contains an alkyl (meth)acrylate polymer having hydrophilic groups, is formed on the high frequency sputter-etched surface(s) of a plastic film containing 2 to 50% by volume of a heat-conductive, electrical insulating filler.

Heat-conductive and pressure-sensitive adhesive sheets and method for

A pressure-sensitive adhesive having excellent heat resistance, comprising a photopolymerization product of a composition comprising;

Pressure-sensitive adhesive having excellent heat-resistance, adhesive

A photopolymerized acrylic pressure-sensitive adhesive having excellent heat-resistance, an adhesive sheet using the adhesive, and methods for producing the adhesive and the adhesive sheet, are disclosed. The pressure-sensitive adhesive sheet having excellent heat resistance comprising a photopolymerization product of a composition comprising;

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Osaka, Japan

Takao Yoshikawa