Toray Industries, Inc.

Takao Sasaki

Masahiro Kimura

Shunsuke Tabayashi

Hiroho Hirozawa

Kentaro Takagi

Yoshiki Okamoto

Hiroyuki Yamada

Shuji Furuno

Takashi Yoshino

Yoshie Marutani

Masakazu Koiwa

Hiroki Minehara

Masaki Higashi

Ryosuke Okanishi

Yuta Amano

Kazuki Sato

Koji Nakatsuji

Takafumi Ogawa

Hiroaki Tanaka

Keisuke Yoneda

Tomoko Mitsuhata

Kiyohiko Takaya

Hiroki Tomioka

Masahiro Henmi

Yuji Tanaka

Harutoki Shimura

Yutaro Suzuki

Jun Okabe

Katsufumi Oto

Akira Katayama

Hiroshi Umetani

Takeharu Inoue

Kumiko Ogawa

Rina Takahashi

The present invention relates to a composite semipermeable membrane including: a support membrane; and a separation functional layer provided on the support membrane, in which the separation functional layer includes a thin membrane, the thin membrane has a fold structure including a plurality of protrusions, an actual length L of the thin membrane per 1 μm length of the support membrane in a cross-sectional direction perpendicular to a membrane surface is 3.0 μm or more, and a thickness of the thin membrane in the protrusion is 15 nm or more.

Composite semipermeable membrane

The present invention relates to a composite semipermeable membrane including: a support membrane; and a separation functional layer provided on the support membrane, in which the separation functional layer includes a thin membrane, the thin membrane has a fold structure including a plurality of protrusions having a height of 10 nm or more, and in the fold structure, a ratio (T100/T25) is less than 0.95, where T25 is a thickness of the thin membrane in a region of 0% to 25% of the height of the protrusion and T100 is a thickness of the thin membrane in a region of 50% to 100% of the height of the protrusion.

The present invention relates to a composite semipermeable membrane including: a support membrane; and a separation functional layer provided on the support membrane, in which the separation functional layer comprises a plurality of protrusions formed of a thin membrane, and at least a part of the plurality of protrusions has a ratio (Wa/Wb) of larger than 1.3 in cross sections at arbitrary ten positions each having a length of 2.0 μm in a membrane surface direction of the support membrane, provided that Wa is a maximum width of the protrusion and Wb is a root width of the protrusion.

Provided is a gas separation membrane that can be used continuously. The gas separation membrane comprises: a porous support membrane that contains an aromatic polyamide in which an aromatic ring has been replaced with a chloro group; and a separation functional layer that is disposed on the surface of the porous support membrane and contains a cross-linked polyamide obtained by polycondensation of a polyfunctional amine and a polyfunctional acid halide.

Gas separation membrane, gas separation membrane element, and gas separation method

The present invention relates to a gas separation membrane including: a supporting membrane; and a separation functional layer which is provided on the supporting membrane and includes a crosslinked polyamide obtained by polycondensation of a polyfunctional amine and a polyfunctional acid halide, in which, in the crosslinked polyamide, the number A of terminal amino groups, the number B of terminal carboxy groups, and the number C of amide groups satisfy (A+B)/C&#x2264;0.66.

A composite semipermeable membrane includes a porous supporting membrane and a separation functional layer, in which, in cross-sections having a length of 2.0 &#x3bc;m in a membrane surface direction, the average number density of projections in the separation functional layer which have a height of one-fifth or more of the 10-point average surface roughness is 10.0-30.0 projections/&#x3bc;m and the projections have an average height less than 100 nm, and in which a water production rate and a salt rejection are predetermined values or more after an aqueous solution is passed through under certain conditions.

In order to provide a composite semipermeable membrane which combines strength and water permeability, the present invention provides a composite semipermeable membrane including: a supporting membrane including a substrate and a porous support; and a separation functional layer disposed on the porous support, in which the substrate has a weight A per unit area, a portion of the porous support which is located within the substrate has a weight B per unit area, and a sum of the weight A and the weight B, (A+B), is 30 to 100 g/m, and a ratio between the weight A and the weight B, B/A, is 0.10 to 0.60.

The purpose of the present invention is to provide a composite semipermeable membrane having achieved both strength and water-permeable properties. This composite semipermeable membrane is provided with a substrate, a porous support body disposed on the substrate, and a separation function layer provided on the porous support body. The substrate has a structure provided with a crimped portion and a non-crimped portion. The porous support body is impregnated inside a crimped portion and inside a non-crimped portion of the substrate.

A composite semipermeable membrane including: a substrate; a porous supporting layer formed on the substrate; and a separation functional layer formed on the porous supporting layer, in which the separation functional layer contains crosslinked wholly aromatic polyamide as a main component and contains a carboxy group, a ratio of (molar equivalent of the carboxy group)/(molar equivalent of an amide group) in functional groups contained in the separation functional layer is 0.40 or more, and an average ratio of oxygen atoms/nitrogen atoms in front and rear sides of the separation functional layer is 0.95 or less.

Composite semipermeable membrane and production thereof

The present invention provides a separation membrane and a separation membrane element capable of exhibiting a good water production performance even at a high temperature and also excellent handleability and quality. The separation membrane of the present invention includes a separation membrane main body having a feed-side face and a permeate-side face; and a permeate-side channel member fixed onto the permeate-side face of the separation membrane main body, and the permeate-side channel member includes polypropylene as a main component and satisfies the following requirements (a) to (c): (a) a softening point temperature is 60&#xb0; C. or higher; (b) a tensile elongation in a standard state is 10% or more; and (c) a yield point stress under a wet condition at 50&#xb0; C. is 2 MPa or more.

Separation membrane, sheet channel material, and separation membrane element

The present invention relates to a composite semipermeable membrane including a supporting membrane and a separation functional layer disposed on the supporting membrane, in which the separation functional layer comprises an aromatic polyamide, the aromatic polyamide has side chains and terminal groups, at least one of the side chains and terminal groups of the aromatic polyamide being an amino group, at least one of the side chains and terminal groups of the aromatic polyamide is a substituent having a structure represented by formula (1): &#x2014;NXY or formula (2): &#x2014;NXYZ, and in the aromatic polyamide, a content A of substituents having structures represented by formula (1) and formula (2) and a content B of amide groups satisfy 0.005&#x2264;A/B&#x2264;0.15.

Provided is a composite semipermeable membrane having a high salt removal rate and a high water permeability. The composite semipermeable membrane comprises a substrate, a porous support layer formed on the substrate, and a separation functional layer formed on the porous support layer, the hydrophilic macromolecule concentration on the substrate-side surface of the porous support layer being higher than that on the separation functional layer-side surface.

A separation membrane element of the present invention includes: a water collection tube; and a plurality of separation membrane leaves stacked on each other and wound around the water collection tube, each of the separation membrane leaves includes one or more separation membranes each having a feed-side face and a permeate-side face and is configured so that the feed-side faces face each other, and a sheet having a plurality of projections fixed thereto is provided between the permeate-side faces of the separation membrane leaves stacked on each other. Regarding a height of the projections, a ratio of the maximum height to the minimum height is from 1.10 to 1.50, and a variation coefficient of the height is from 0.02 to 0.15, and an impregnation ratio of the projections into the sheet is from 10% to 100%.

Separation membrane element

The present invention provides a separation membrane and a separation membrane element which are capable of exhibiting good water production performance and excellent in handleability and process passage. A separation membrane of the present invention is a separation membrane including: a separation membrane main body having a feed-side face and a permeate-side face; and a permeate-side channel member adhered to the permeate-side face of the separation membrane main body, in which the permeate-side channel member includes a composition containing at least a high-crystalline polypropylene (A) and satisfies the following requirements (a) and (b):

Separation membrane, sheet flow path material, and separation membrane element

Provided is a semipermeable membrane having at least a separating functional layer, wherein azo compounds are retained in the separating functional layer, and the separating functional layer has a yellow index of 10 to 40. Also provided is a method of producing the semipermeable membrane. The present invention provides a semipermeable membrane having not only high water permeability but also high rejection performance even for substances that are nondissociative in the neutral range, such as boric acid, and showing high durability and a manufacturing method therefor.

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Shiga, Japan

Takao Sasaki