Panasonic Intellectual Property Management Co., Ltd.

Sanyo Electric Co., Ltd.

Takao Kokubu

Takeshi Ogasawara

Atsushi Ogata

Taizou Sunano

Fumiharu Niina

Tomoki Tsuji

Taiki Satow

This positive electrode active material for nonaqueous electrolyte secondary batteries comprises composite oxide particles which contain Ni, Co and Li, while containing at least one of Mn and Al, and wherein the ratio of Ni to the total number of moles of the metal elements other than Li is 80% by mole or more. The composite oxide particles are composed of particles in an aggregated state and particles in a non-aggregated state; and the content ratio of the particles in an aggregated state to the particles in a non-aggregated state is from 5:95 to 50:50 in terms of the mass ratio.

Positive electrode active material for nonaqueous electrolyte secondary batteries, and nonaqueous electrolyte secondary battery

The present disclosure is directed to a positive electrode active material for non-aqueous electrolyte secondary batteries that is capable of suppressing an increase in battery direct current resistance due to high-temperature storage (e.g., storage at 60&#xb0; C. or higher). Positive electrode active material particles in one aspect of the present disclosure include secondary particles formed by aggregation of primary particles of a lithium transition metal oxide containing Ni and Mn and include a boron compound present in the inner part and surface of the secondary particles. The difference in composition ratio between Ni and Mn in the lithium transition metal oxide is more than 0.2. The proportion of the boron element content in the inner part of the secondary particles to the total boron element content in the inner part and surface of the secondary particles is in the range from 5% by mass to 60% by mass.

Positive electrode active material for non-aqueous electrolyte secondary batteries

A positive electrode active material for a secondary battery contains second particles which are produced by aggregation of primary particles of a lithium transition metal oxide containing Ni and W, and a boron compound present inside and on the surfaces of the secondary particles.

Positive electrode active material for secondary battery and secondary battery

A positive electrode for nonaqueous electrolyte secondary batteries and a nonaqueous electrolyte secondary battery are provided with which loss of initial efficiency can be limited even if a positive electrode exposed to air is used. An aspect of a positive electrode according to the present invention for nonaqueous electrolyte secondary batteries is a positive electrode for nonaqueous electrolyte secondary batteries incorporating a lithium transition metal oxide, wherein the positive electrode for nonaqueous electrolyte secondary batteries contains a tungsten compound and a boron compound. It is particularly preferred that the tungsten compound be a tungsten-containing oxide.

Positive electrode for nonaqueous electrolyte secondary battery and nonaqueous electrolyte secondary battery

There is provided a positive electrode for nonaqueous electrolyte secondary batteries in which a decrease in the initial discharge voltage can be suppressed even when a positive electrode exposed to the air is used. The positive electrode for a nonaqueous electrolyte secondary battery according to an aspect of the present invention contains a lithium transition metal oxide constituted by a secondary particle formed by aggregation of primary particles. A rare-earth compound adheres to at least part of a surface of the secondary particle, and a compound containing lithium and boron adheres to at least part of the surface of the secondary particle and at least part of an interface between primary particles aggregated at the surface of the secondary particle.

Positive electrode for nonaqueous electrolyte secondary battery and nonaqueous electrolyte secondary battery using the same

A positive electrode for a nonaqueous electrolyte secondary battery that does not undergo a decrease in discharge capacity in low-temperature discharge during charge and discharge after the battery is left standing at high temperature in a charged state, for example. The positive electrode for a nonaqueous electrolyte secondary battery includes a positive electrode active material. The positive electrode active material includes a mixture of lithium nickel cobalt manganate and lithium cobaltate having a compound adhered to part of a surface thereof, the compound containing fluorine and at least one selected from zirconium, magnesium, titanium, aluminum, and a rare earth element; and a ratio of the lithium nickel cobalt manganate relative to a total amount of the positive electrode active material is 1% by mass or more and less than 70% by mass.

Growing community of inventors

Osaka, Japan

Takao Kokubu