Mitsubishi Gas Chemical Company, Inc.

Takanori Miyabe

Jun Mitadera

Takafumi Oda

Tomonori Kato

Jin Nakamura

Kazuya Sato

Nobuhiko Matsumoto

Kenji Kouno

Masaki Yamanaka

Provided is a resin laminate having: a polyester layer containing a polyester resin (A); and a mixed resin layer containing a polyamide resin (B) and a polyester resin (C). The polyamide resin (B) includes a constituent unit derived from a diamine and a constituent unit derived from a dicarboxylic acid, with 70 mol % or greater of the constituent derived from a diamine being a constituent unit derived from xylylenediamine, and 70 mol % or greater of the constituent unit derived from a dicarboxylic acid being a constituent unit derived from an α,ω-linear aliphatic dicarboxylic acid having from 4 to 20 carbons. Further, a radical concentration in the mixed resin layer is 1×10mol/g or greater. Also provided are a multilayered film and a multilayered container formed from the resin laminate.

Resin layered body

Provided is a multilayered article and a multilayered container having excellent delamination resistance while maintaining an excellent oxygen barrier property. The multilayered article includes a polyester resin layer and a barrier layer, wherein a polyamide resin contained in the barrier layer contains from 90 to 10 parts by mass of a polyamide resin (B) per 10 to 90 parts by mass of a polyamide resin (A). In the polyamide resin (A), 70 mol % or more of structural unit derived from a diamine is derived from xylylenediamine, and over 90 mol % of structural unit derived from a dicarboxylic acid is derived from adipic acid. In the polyamide resin (B), 70 mol % or more of structural unit derived from a diamine is derived from xylylenediamine, and of structural unit derived from a dicarboxylic acid, from 30 to 65 mol % is derived from an am-linear aliphatic dicarboxylic acid having from 4 to 20 carbons and from 70 to 35 mol % is derived from isophthalic acid.

Multilayered article and multilayered container

Provided are a multilayered article and a multilayered container excelling in oxygen barrier properties, delamination resistance, and transparency. The multilayered article has a polyester resin layer and a barrier layer. The polyamide resin contained in the barrier layer includes (A) a polyamide resin derived from xylylenediamine and adipic acid, (B) a polyamide resin derived from xylylenediamine, a linear aliphatic dicarboxylic acid, and isophthalic acid, and as necessary, (C) a polyamide resin derived from hexamethylenediamine, isophthalic acid, and terephthalic acid, and (D) an aliphatic polyamide resin. In the barrier layer, a ratio of the mass of the polyamide resin (A) to the total mass of the polyamide resin (B) and the polyamide resin (C) is from 98:2 to 15:85, the total content of the polyamide resin (A) and the polyamide resin (B) is 60 mass % or more, the content of the polyamide resin (B) is from 1 to 65 mass %, and the content of the aliphatic polyamide resin (D) is from 3 to 40 mass %.

Provided is a multilayered container including a polyester layer containing a thermoplastic polyester resin (X) and a polyamide layer containing a polyamide resin (Y), wherein the polyester layer is an innermost layer, and the polyamide layer is an intermediate layer. The polyamide resin (Y) has a constituent unit derived from a diamine and a constituent unit derived from a dicarboxylic acid. At least 70 mol % of the constituent units derived from a diamine are a constituent unit derived from a xylylenediamine, and at least 70 mol % of the constituent units derived from a dicarboxylic acid are a constituent unit derived from an &#x3b1;,&#x3c9;-linear aliphatic dicarboxylic acid having from 4 to 20 carbons. When an overall thickness is 100%, the polyamide layer is present from a position of 5 to 35% from an inner surface, and a thickness of the polyamide layer is from 1 to 15%.

Multilayered container and method for producing same

Object: To provide a resin composition having excellent oxygen barrier properties and transparency, and high tensile elongation at break; a molded article, a film, and a multilayer film. Resolution means: A resin composition including from 20 to 80 parts by mass of a polyamide resin (A) and from 80 to 20 parts by mass of a polyamide resin (B); wherein more than 35 mol % of all the constituent units of the polyamide resin (A) are constituent units including an alkylene chain having from 2 to 6 carbons; the polyamide resin (B) includes constituent units derived from a diamine and constituent units derived from a dicarboxylic acid, wherein 70 mol % or more of the constituent units derived from a diamine are derived from a xylylenediamine; from 30 to 70 mol % of the constituent units derived from a dicarboxylic acid are derived from an &#x3b1;,&#x3c9;-linear aliphatic dicarboxylic acid having from 4 to 8 carbons; from 70 to 30 mol % of the constituent units derived from a dicarboxylic acid are derived from isophthalic acid, with the proviso that the total does not exceed 100 mol %; and the polyamide resin (B) further includes phosphorus atoms in a ratio of 3 to 300 mass ppm, and calcium atoms so as to be the ratio that phosphorus atoms:calcium atoms of 1:0.3 to 0.7.

Resin composition, molded article, film, and multilayer film

A resin composition which has oxygen-barrier properties less apt to depend on humidity and has high transparency; and a formed article and a film which include the resin composition are provided. The resin composition includes from 10 to 90 parts by mass of a polyamide resin (A) and from 90 to 10 parts by mass of a polyamide resin (B), wherein the polyamide resin (A) includes constituent units derived from a diamine and constituent units derived from a dicarboxylic acid, with 70 mol % or more of the constituent units derived from a diamine being derived from xylylenediamine and 90 mol % or more of the constituent units derived from a dicarboxylic acid being derived from adipic acid; the polyamide resin (B) includes constituent units derived from a diamine and constituent units derived from a dicarboxylic acid, 70 mol % or more of the constituent units derived from a diamine being derived from xylylenediamine, from 30 to 65 mol % of the constituent units derived from a dicarboxylic acid being derived from an &#x3b1;,&#x3c9;-linear chain aliphatic dicarboxylic acid having from 4 to 20 carbons, and from 70 to 35 mol % of the constituent units derived from a dicarboxylic acid being derived from isophthalic acid.

Resin composition, formed article, and film

An object of the present invention is to provide an injection blow container that is excellent in moldability and impact resistance and furthermore, excellent in solvent resistance. The injection blow-molded container of the present invention comprises 60 to 95 parts by mass of a polyamide resin (A) and 5 to 40 parts by mass of a polyamide resin (B) (per 100 parts by mass in total of the polyamide resin (A) and the polyamide resin (B)), wherein the polyamide resin (A) comprises a diamine-derived constitutional unit and a dicarboxylic acid-derived constitutional unit, wherein 70 mol % or more of the diamine-derived constitutional unit is a constitutional unit derived from xylylenediamine, 70 mol % or more of the dicarboxylic acid-derived constitutional unit is a constitutional unit derived from &#x3b1;,&#x3c9;-linear aliphatic dicarboxylic acid having 4 to 12 carbon atoms, and 30 mol % or less thereof is a constitutional unit derived from isophthalic acid; and the polyamide resin (B) comprises no constitutional unit derived from xylylenediamine, and is a polyamide resin having an alkylene group having 5 to 12 carbon atoms.

Injection blow-molded container

Provided is a polyester-based resin composition capable of giving a molded article excellent in transparency and gas-barrier property even though the molded article requires stretching treatment, and also provided is a method for producing the composition. The method for producing a polyester-based resin composition includes a step of obtaining a master batch (M) containing a polyester resin (A) having a cyclic acetal structure or an alicyclic hydrocarbon structure, and a polyamide resin (B), and a step of melt-kneading the master batch (M) with a polyester resin (R) in which 70 mol % or more of the dicarboxylic acid unit is derived from an aromatic dicarboxylic acid and 70 mol % or more of the diol unit is derived from an aliphatic diol, thereby giving a polyester-based resin composition, in this order,. The glass transition temperature of the polyester resin (A) is 105&#xb0; C. or lower, the content of the polyester resin (A) in the polyester-based resin composition is 0.5 to 15.0% by mass, and the content of the polyamide resin (B) is 0.5 to 10.0% by mass.

Polyester-based resin composition and production process therefor, molded object and production process therefor, and masterbatch

A polyester-based resin composition containing a polyester resin (A) that has a dicarboxylic acid unit containing units selected from a sulfophthalic acid unit and a sulfophthalic acid metal salt unit in a total amount of 0.01 to 15.0 mol % and a diol unit, a polyester resin (B) having a cyclic acetal structure or an alicyclic hydrocarbon structure, and a polyamide resin (C), wherein the content of the polyester resin (B) in the resin composition is 0.5 to 15.0% by mass.

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Kanagawa, Japan

Takanori Miyabe