Bridgestone Corporation

Bridgestone Sports Co., Ltd.

Takahiro Iwai

Tsuyoshi Nakajima

Yuichiro Ozawa

Yusuke Yamagata

Teppei Mori

The invention provides a rubber composition for golf balls which includes (A) a base rubber containing a polybutadiene having a cis-1,4 bond content of at least 60 wt %, (B) an unsaturated carboxylic acid and/or a metal salt thereof, and (C) a benzimidazole of general formula (1) or (2) below wherein R is a hydrogen atom or a hydrocarbon group of 1 to 20 carbons, and m is an integer from 1 to 4, with the proviso that if m is 2 or more, each occurrence of R may be the same or different. The golf ball rubber composition of the invention enables a high-quality molded and crosslinked product having a suitable hardness and a high resilience to be obtained.

Rubber composition for golf ball

The invention provides a rubber composition for golf balls which includes (A) a base rubber containing a polybutadiene having a cis-1,4 bond content of at least 60 wt %, (B) an unsaturated carboxylic acid and/or a metal salt thereof, and (C) a diphenylamine of the general formula wherein Rand Rare each independently a hydrogen atom or a hydrocarbon group of 1 to 20 carbons, m is an integer from 1 to 5, and n is an integer from 1 to 4, with the proviso that if m and/or n is 2 or more, each occurrence of Rand Rmay be the same or different. The golf ball rubber composition of the invention enables a high-quality molded and crosslinked product having a suitable hardness and a high resilience to be obtained.

The invention provides a rubber composition for golf balls which includes: (A) a base rubber containing a polybutadiene having a cis-1,4 bond content of at least 60 wt %; (B) an unsaturated carboxylic acid and/or a metal salt thereof; (C) an anthranilic acid derivative of the general formula wherein Rand Rare each independently a hydrogen atom or a hydrocarbon group of 1 to 20 carbons, m is an integer from 1 to 4, and n is an integer from 1 to 3, with the proviso that if m and/or n is 2 or more, each occurrence of Rand Rmay be the same or different; and (D) sulfur. The rubber composition for golf balls of the invention enables a high-quality molded and crosslinked product having a suitable hardness and a high resilience to be obtained.

Rubber composition for golf balls which includes: (A) a base rubber containing a polybutadiene having a cis-1,4 bond content of at least 60 wt %; (B) an unsaturated carboxylic acid and/or a metal salt thereof; (C) an anthranilic acid derivative of the general formula wherein Rand Rare each independently a hydrogen atom or a hydrocarbon group of 1 to 20 carbons, m is an integer from 1 to 4, and n is an integer from 1 to 3, with the proviso that if m and/or n is 2 or more, each occurrence of Rand Rmay be the same or different; and (D) an organic peroxide having a one-minute half-life temperature which is at least 158&#xb0; C. and less than 175&#xb0; C. The rubber composition for golf balls of the invention enables a high-quality molded and crosslinked product having a suitable hardness and a high resilience to be obtained.

The invention provides a rubber composition for golf balls which includes (A) a base rubber containing a polybutadiene having a cis-1,4 bond content of at least 60 wt %, (B) an unsaturated carboxylic acid and/or a metal salt thereof, and (C) a thiourea of the general formula wherein R is independently at each occurrence a hydrogen atom or a hydrocarbon group of 1 to 20 carbons. The golf ball rubber composition of the invention enables a high-quality molded and crosslinked product having a suitable hardness and a high resilience to be obtained.

The invention provides a rubber composition for golf balls which includes (A) a base rubber containing a polybutadiene having a cis-1,4 bond content of at least 60 wt %, (B) an unsaturated carboxylic acid and/or a metal salt thereof, and (C) an anthranilic acid derivative of the general formula wherein Rand Rare each independently a hydrogen atom or a hydrocarbon group of 1 to 20 carbons, m is an integer from 1 to 4, and n is an integer from 1 to 3, with the proviso that if m and/or n is 2 or more, each occurrence of Rand Rmay be the same or different. The golf ball rubber composition of the invention enables a high-quality molded and crosslinked product having a suitable hardness and a high resilience to be obtained.

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Kodaira, Japan

Takahiro Iwai