Sumitomo Electric Industries, Limited

Takaharu Yamamoto

Akio Hara

Tsuyoshi Asai

Masaya Miyake

Naoji Fujimori

Masaaki Tobioka

Minol Nakano

Toshio Nomura

Mitsuo Kodama

Mitsunori Kobayashi

Yoshihiko Doi

Kunihiro Takahashi

Takeshi Asai

Masa-aki Tobioka

The invention relates to sintered hard metals having high cutting properties, particularly plastic deformation resistance at high temperatures, crater resistance and the like, suitable for use as cutting tools, wear resistant tools and materials for dies, and the method for producing the same. The invention has for an object to obtain both sintered hard metals having the aforesaid high properties by sintering metallic components comprising IVa group metals, VIa group metals or metals of both groups substituted by Va group metals up to 60 mol % respectively, a B-1 type solid solution hard phase consisting of non-metallic components of C, N and O, and a metallic bonding phase, in a CO gas atmosphere, and to sintered hard metals in which an uniform hardness is imparted to the surface and interior thereof by the method of sintering the said sintered hard metal in a CO gas atmosphere.

Sintered hard metals and the method for producing the same

This invention relates to a hard alloy consisting of a metallic phase and a hard phase having a B1 type crystal structure, and being represented by the following general formula,

Hard alloy and a process for the production of the same

The invention relates to a sintered hard metal having a high wear resistance and heat resistance as material for cutting tools and wear resistant tools and the method for producing the same. The sintered hard metal has a hard phase comprising a phase having a B-1 type crystal structure containing more than one kind of IVa, Va and VIa group metals in the Periodic Table and also the elements, carbon, nitrogen and oxygen and a WC phase, the hard phase and a bonding phase chiefly consisting of a ferrous metal which is sintered by a powder metallurgy technique, whereas the oxygen in particular is added thereto making it possible to obtain a sintered hard metal having said excellent properties.

Sintered hard metal and the method for producing the same

This invention relates to a sintered hard metal for cutting tools and having excellent wear resistance, resistance to thermal deformation, mechanical strength and the like. The present invention resides in the fact that the substrate metal consists of a rich content of the B-1 type hard phase and the surface thin layer consists of a rich content of the ordinary tungsten carbide. B-1 type crystal structure contains one or more Group IVa, Va and VIa metals, carbon, nitrogen and, moreover, tungsten. The thin layer structure has the layer of 5 to 200.mu. thickness on the surface thereof.

This invention relates to a hard alloy comprising a hard phase consisting of at least one compound having a crystal structure of simple hexagonal MC type (M: metal; C: carbon) selected from the group consisting of mixed carbides, carbonitrides and carboxynitrides of molybdenum and tungsten as a predominant component, and a binder phase consisting of at least one element selected from the group consisting of iron, cobalt, nickel and chromium, in which a hard phase consisting of a compound of M.sub.2 C type having a crystal structure of hexagonal type is evenly dispersed.

Hard alloy containing molybdenum and tungsten

This invention relates to a surface-coated sintered hard body comprising an alloy consisting of at least one of carbides and carbonitrides of Group IVa, Va and VIa transition metals, cemented by at least one of metals and alloys, and two interior and exterior coated layers, the interior layer being a monolayer or multilayer consisting of at least one of carbides, carbonitrides and nitrides of Group IVa, Va and VIa transition metals, in which a part of the non-metallic element or elements are optionally replaced by oxygen, and at least one layer of the interior layer consisting of at least one of carbides, carbonitrides and nitrides of Group IVa, Va and VIa transition metals, in which a part or all of the non-metallic element or elements are replaced by boron, and the exterior layer consisting of at least one of aluminum oxide, zirconium oxide and mixtures or compounds thereof.

Surface-coated sintered hard body

This invention relates to a process for producing sintered hard metals which comprises sintering a compact for the sintered hard metals or sintering a formed body obtained from the compact through a presintering treatment and, if necessary, a machining treatment, a part or all of the heating steps and cooling steps being carried out in an atmospheres of hydrogen and an atmosphere of carbon monoxide.

Process for producing sintered hard metals and an apparatus therefor

The present invention relates to a process for the production of an alloy powder (Mo, W) for powder metallurgy, which comprises chemically or mechanically mixing molybdenum and tungsten in the form of compounds and reducing the mixed powder with hydrogen, and a process for the production of a hard solid solution (Mo, W)C from the alloy powder (Mo, W), which comprises carburizing the alloy powder (Mo, W).

Method of making alloy and carbide powders of molybdenum and tungsten

This invention relates to a process for the production of a solid solution of compounds consisting of, in combination, at least 10 mol %, based on all metallic components, of molybdenum, at least one metallic element selected from the Group IVa, Va and VIa elements of the Periodic Table and at least one of non-metallic elements, which comprises mixing the metallic elements in the form of compounds or solutions thereof, adding carbon, optionally with at least one of non-metallic elements to the mixture, subjecting the resulting mixture to a reducing reaction with carbon and then subjecting to a solid solution-forming treatment in a reducing, carburizing or nitriding atmosphere.

Process for the production of a hard solid solution

There is provided a coated tool steel having a tool steel substrate and at least one layer of a hard film overcoated on the substrate. The film consists of a B-1 type solid solution selected from carbides, nitrides and carbonitrides of at least one of titanium, zirconium or hafnium, and the breadth of the peak, at half maximum intensity, of Cu-K.alpha. diffraction from the (200) plane of the film, being not less than 0.4 degree on a 2 .theta. scale. The invention further provides a machine tool having at least one cutting part thereof formed from the coated tool steel described above. The coated steel provided herein has excellent wear resistance.

Coated tool steel and machining tool formed therefrom

This invention relates to surface-coated cemented carbide articles having a monolayer or multilayer consisting of one or more materials selected from oxides, carbides, nitrides and mixtures or compounds thereof, the most interior layer, in contact with the surface of the cemented carbide substrate, consisting of one or more materials selected from carbides and carbonitrides of Group IVa, Va and VIa elements, wherein the thickness of a decarburized layer (.eta. phase) present between the cemented carbide substrate and most interior coating layer is 0.5 micron or less in a case where the curvature of the interface is zero and the lattice constant of the binder metal of the coated cemented carbide article, as a mean value from the interface to 50 microns, is not more than that of the iron group metal solid solution by 0.005 A or more.

Surface-coated cemented carbide article and a process for the production

The present invention relates to a hard cemented carbonitride alloy for cutting tools, which comprises 97 to 75% by weight of a hard phase and 3 to 25% by weight of a binder metal, the hard phase consisting of metallic components of titanium as a main component, 5 to 40% by weight of one or more of tungsten and molybdenum and 3 to 40% by weight of tantalum and non-metallic components of carbon and nitrogen, the proportion of nitrogen being 5 to 40% by weight of the non-metallic components and the binder metal being at least one element selected from the group consisting of iron, cobalt and nickel.

Cemented carbonitride alloys containing tantalum

This invention relates to a cemented carbonitride alloy in which the hard phase consists of

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Itami, Japan

Takaharu Yamamoto