Hitachi Chemical Company, Ltd.

Hitachi Maxell, Limited

Central Glass Company, Limited

San-Apro Limited

Takaaki Sonoda

Hiroshi Kobayashi

Jin Nie

Yoshii Morishita

Shigeru Hayashida

Fusaji Kita

Akira Kawakami

Yasushi Sugimoto

Hiroko Ishikawa

Hideki Kimura

Kouji Murakami

Jiro Yamamoto

Koji Murakami

Shinji Yamashita

Mitsuo Kurumaya

To obtain a polymerization initiator (acid generating agent) having excellent power for initiation of cationic polymerization without containing arsenic or antimony. Provided is a specific onium salt or transition metal complex salt of a fluorinated alkyl fluorophosphoric acid.

Fluorinated alkyl fluorophoshoric acid salts of onium and transition metal complex

The invention relates to a first compound which is a first amine or a first salt thereof, and to a second compound which is a second amine or a second salt thereof. The first compound has a fluorocarbon sulfonic acid ester group and is represented by a general formula of M&lsqb;Rf OSO NSO ORf &rsqb; wherein Rf and Rf represent the same or different fluorine-containing monovalent organic groups. The first amine is prepared by reacting bis(chlorosulfonyl)amine with a fluoroalcohol represented by a general formula of Rf OH wherein Rf represents the same of different groups which are identical with Rf and Rf . The second compound has a fluorocarbon sulfonic acid ester group and is represented by a general formula of &mdash;&lsqb;M&lsqb;N&mdash;SO ORf OSO &rsqb; &rsqb; &mdash; wherein Rf represents a fluorine-containing bivalent organic group. The second amine is prepared by reacting bis(chlorosulfonyl)amine with a fluorodiol represented by a general formula of HORf OH wherein Rf represents a bivalent organic group which is identical with Rf . The first and second salts are respectively prepared by reacting the first and second amines with a compound selected from ammonia, quaternary ammonium compounds, hydroxides of, oxides of, carbonates of, halides of, fluorides of, chlorides of, bromides of, iodides of, and acetates of particular elements. The first and second compounds are fully expected to be usable as catalyst and the like, in the synthesis of organic compounds.

Amines or salts thereof and methods of preparing same

The invention relates to a process for the preparation of M&lsqb;Rf,OSO,NSO,ORf,&rsqb;,wherein Rf,and Rf,are as define any the specification by reacting bis(chlorosulfonyl)amine with a fluoroalcohol represented Rf,OH wherein Rf,represents the same of different group which is identical with Rf,and Rf,.

An ion conductive material containing a compound which comprises a resonance structure group which contains an atom of the Vb group in the Periodic Table serving as an anionic site and is bonded to an electron attractive organic group through an atom of the VIb group in the Periodic Table, and a counter ion selected from the group consisting of metal ions and a hydrogen ion. This material is useful as an electrolyte of a cell since it is excellent in high voltage stability.

Ion conductive material and electrochemical device comprising the same

An enamine derivative containing a fluoroalkyl group, a fluoroaryl group or a fluoroaralkyl group is effective as a charge transport material in an electrophotographic member excellent in sensitivity, residual potential, durability and the like electrophotographic properties.

Enamine derivatives

An organic electrolytic solution containing an organic solvent, and a metal salt having at least one electron attractive group and an anion which contains at least one element selected from the elements of the IIIb to VIb group of the Periodic Table and a charge-center atom of which is bonded to the electron attractive group by an intermediate backbone, in which a maximum distance between the center of the charge-center atom and the center of other atom in the anion is at least 4 .ANG.,. and a cell comprising this organic electrolytic solution, both having improved shelf stability.

Organic electrolytic solution and organic electrolytic solution cell

Electrophotographic member comprising enamine derivatives

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Fukuoka, Japan

Takaaki Sonoda