Sekisui Kaseihin Kogyo Kabushiki Kaisha

Sekisui Plastics Co., Ltd.

Takaaki Hirai

Norio Amano

Motoshige Hayashi

Takeshi Taki

Masahiro Tsubone

Kiyoshi Yoshioka

Masatoshi Ishibashi

Nobuyuki Tsujiwaki

Masahiro Shindo

Susumu Ishiwatari

Tekeshi Taki

Hideyasu Matsumura

Ikuo Morioka

Hiroyuki Yamagata

Yukio Aramomi

Hiroyuki Ueno

Minoru Fujishima

Tetsuya Ochiai

Katsunori Nishijima

The present invention provides a method for producing polylactic acid-based resin foamed particles for in-mold foam-molding from which a polylactic acid-based resin foam-molded article excellent in heat resistance and mechanical strength can be obtained by in-mold foam-molding. In the method of the present invention for producing polylactic acid-based resin foamed particles for in-mold foam-molding, a rotary blade is rotated at a given rotation speed while being always in contact with the front end surface of a nozzle and a polylactic acid-based resin extrudate extrusion-foamed through a nozzle is cut with the rotary blade, so that it is possible to cut the polylactic acid-based resin extrudate surely to obtain substantially spherical polylactic acid-based resin foamed particles. Therefore, when polylactic acid-based resin foamed particles are used for in-mold foam-molding, the polylactic acid-based resin foamed particles foam uniformly in all directions and, as a result, the foamed particles are thermal fusin bonded to unite together strongly in all direction.

Polylactic acid-based resin foamed particles for in-mold foam-molding and method for producing the same, as well as method for producing polylactic acid-based resin foam-molded article

A thermoplastic polyester resin is fed into a twin extruder, wherein a resin is heated for melting, thereby removing moisture in the resin by evacuating and sucking from a vent port thereof, injecting a foaming agent into the resin to which is pushed out as a foaming sheet and, after that, forming the foaming sheet which is divided into a forming body and a trimming loss, whereby the trimming loss is crushed to obtain crushed materials which are provided so as to put the materials into the twin extruder as collection materials and recycle them.

Continuous manufacturing method and manufacturing apparatus of thermoplastic polyester resin foam

The present invention provides a process for producing a molded foam article of a crystalline aromatic polyester resin. The process is characterized by heating the surface temperature of a mold for cavity-molding to the temperature within a range of from (td&plus;35) to (Tg&plus;57)&deg;C. (Tg is a glass transition temperature of the crystalline aromatic polyester resin prepuffs), thereby to mold prepuffs, and cooling the surface of the mold to a temperature not lowered than Tg for at least 20 seconds.

Method for producing foamed-in-mold product of aromatic polyester based resin

High molecular weight thermoplastic polyester resin foam

Method of manufacturing thermoplastic polyester resin foam by extrusion

A leather-like thermoplastic polyester series resin sheet is disclosed, including a uniformly and finely foamed sheet comprising a thermoplastic polyester series resin, wherein said foamed sheet has cells having a diameter of substantially not longer than 1 mm, the cell walls thereof have a thickness of substantially not thicker than 100 .mu.m, and the cell wall constructing each cell extends with irregular bending so as to make a flexibility of not more than 20,000 mg in the Gurley flexibility test. A process for production of the leather-like thermoplastic polyester series resin sheet is also disclosed.

Process for producing leather-like thermoplastic polyester series resin

A method of forming a thermoplastic polyester series foamed material having a thickness of at least 3 mm and an apparent density of from 0.05 to 0.7 g/cm.sup.3, wherein the crystallinity of the resin in the surface portion within 0.5 mm from the surface of the foamed material is not more than 30% and at least 1% lower than the crystallinity of the resin in the central portion of the foamed material.

Process for producing thermoplastic polyester series resin foamed

A thermoplastic polyester series foamed material having a thickness of at least 3 mm and an apparent density of from 0.05 to 0.7 g/cm.sup.3 is diclosed, wherein the crystallinity of the resin in the surface portion within 0.5 mm from the surface of the foamed material is not more than 30% and at least 1% lower than the crystallinity of the resin in the central portion of the foamed material.

Thermoplastic polyester series resin foamed material and production

A process of producing a thermoplastic polyester series resin foamed material is disclosed, which comprises heating and further foaming a thermoplastic polyester resin foamed material having a crystallinity of not higher than 30% by bringing it into contact with water or steam of at least 60.degree. C. and then heating the foamed material by bringing it into contact with a heating medium other than water of at least 100.degree. C. to further foam the foamed material. A process of producing a thermoplastic polyester series resin foamed material is also disclosed, which comprises heating and further foaming a thermoplastic polyester series resin foamed material having a crystallinity of not higher than 30% by bringing it into contact with water or steam of at least 60.degree. C., heating and further foaming the foamed material by bringing it into contact with a heating medium other than water of at least 100.degree. C., and molding the foamed material by a mold.

Process of producing thermoplastic polyester series resin foamed

A thermoplastic polyester series foamed material having a thickness of at least 3 mm and an apparent density of from 0.05 to 0.7 g/cm.sup.3 is disclosed, wherein the crystallinity of the resin in the surface portion within 0.5 mm from the surface of the foamed material is not more than 30% and at least 1% lower than the crystallinity of the resin in the central portion of the foamed material.

A process of producing a thermoplastic polyester series resin foamed material is disclosed, which comprises heating and further foaming a thermoplastic polyester resin foamed material having a crystallinity of not higher than 30% by bringing into contact with water or steam of at least 60.degree. C. and then heating the foamed material by bringing into contact with a heating medium other than water of at least 100.degree. C. to further foaming the foamed material. A process of producing a thermoplastic polyester series resin foamed material is also disclosed, which comprises heating and further foaming a thermoplastic polyester series resin foamed material having a crystallinity of not higher than 30% by bringing into contact with water to steam of at least 60.degree. C., heating and further foaming the foamed material by bringing into contact with a heating medium other than water of at least 100.degree. C., and molding the foamed material by a mold.

Process of producing thermoplastic polyester series resin foamed material

A leather-like thermoplastic polyester series resin sheet is disclosed, comprising a uniformly and finely formed sheet comprising a thermoplastic polyester series resin, wherein said foamed sheet has cells having a diameter of substantially not longer than 1 mm, the cell walls thereof have a thickness of substantially not thicker than 100 .mu.m, and the cell wall constructing each cell extends with irregular bending so as to make a flexibility of not more than 20,000 mg in the Gurley flexibility test. A process for production of the leather-like thermoplastic polyester series resin sheet is also disclosed.

Leather-like thermoplastic polyester series resin sheet and process for

A process for producing a thermoplastic polyester resin foam comprising melting a thermoplastic polyester resin, mixing the molten resin with a blowing agent and extruding the mixture into a low-pressure zone to carry out expansion molding, characterized in that a compound having two or more acid anhydride groups per molecule, optionally together with a compound of a metal of Group I, II or III elements of the Periodic Table is added to the thermoplastic polyester resin. There is also disclosed a process for producing a thermoplastic polyester resin foam comprising cooling a high-temperature foam immediately after expansion and then re-heating the foam. Further, a thermoplastic polyester resin foam sheet and a food container prepared from the foam sheet are also disclosed.

Growing community of inventors

Nara, Japan

Takaaki Hirai