Mitsui Toatsu Chemicals, Incorporated

Unitika Ltd.

Shimizu Seiko Kabushiki Gaisha

Taisaku Kano

Kazuyuki Kuroda

Kouzou Hayashi

Kiyoshi Shikai

Ryuji Haseyama

Katsuyoshi Sasagawa

Takayoshi Sekido

Masatoshi Takagi

Eiichiro Miyazaki

Hiroshi Nomura

Makoto Nishimori

Yoshinobu Ichihara

Masashi Seki

Shingo Sasaki

Takafumi Kageyama

Koichi Hirai

Nobuki Kobayahsi

Kazuyuki Wakamura

Katsushi Watanabe

There is disclosed a resin composition for powder coatings, which comprises a blend of two acrylic resins obtained by polymerizing a prescribed amount of monomer component (a-1) represented by formula (I) and a prescribed amount of another monomer component (a-2), respectively, and having different polymerization degrees represented by viscosities at 140.degree. C. and a polybasic acid compound in 1.5 to 0.5 equivalent ratio of the glycidyl groups in said acrylic resins to the acid groups in the polybasic acid compound. ##STR1## wherein R.sub.1 and R.sub.2 each represent a hydrogen atom or a lower alkyl group. The resin composition for powder coatings that can form a coating film having a mat smooth appearance and being excellent in flexibility as shown by Du Pont impact resistance and the Ericksen test as well as being excellent in nail scratch resistance.

Resin composition for powder coatings

A resin composition for thermosetting coating, which comprises (a.sub.1) an acrylic copolymer having a particular acid value and/or (a.sub.2) an acrylic copolymer having a particular acid value and a particular hydroxyl value, (b) an acrylic copolymer having a particular epoxy equivalent, (c) a monobasic acid having a dissociation constant (pKa) of 3 or less, and, as necessary, (d) an amino resin and (e) a quaternary phosphoium salt, and wherein the equivalent ratio of the acid groups of (a.sub.1) and/or (a.sub.2) and the epoxy groups of (b) is 1:0.5 to 0.5:1 and the amounts of (c), (d) and (e) are 0.01-5 parts by weight, 1-25 parts by weight and 0.01-3 parts by weight, respectively, per 100 parts by weight of the total of (a.sub.1) and/or (a.sub.2) and (b). The resin composition, when used as a clear coating for automobiles, is superior in film appearance, acid resistance, solvent resistance water resistance, weatherability, storage stability and low temperature curing.

Resin composition for thermosetting coating

Herein disclosed are an .alpha.-(aminocyclohexyl)alkylamine represented by the following general formula (II): ##STR1## wherein R represents hydrogen atom or a lower alkyl group having 1 to 5 carbon atoms, provided that the amino group bonded to the cyclohexyl group may be in either of the 2-, 3- and 4-positions and a method for preparing it; an .alpha.-(isocyanatocyclohexyl)alkylisocyanate of Formula (II) wherein the amino groups are replaced with isocyanato groups and a method for preparing it; polyisocyanato-isocyanurate represented by the following general formula (IV): ##STR2## wherein R.sub.1, R.sub.2 and R.sub.3 may be the same or different and each represents a group represented by the following general formula: ##STR3## wherein R represents hydrogen atom or an alkyl group having 1 to 5 carbon atoms and n is an integer ranging from 1 to 5 and a method for preparing it; and a resin obtained by polymerizing an organic polyisocyanate containing not lower than 10% by weight of the polyisocyanato-isocyanurate represented by Formula (IV) and a compound having at least two active hydrogen atoms as well as a resin composition for coating materials which comprises the resin.

Alicyclic diamines, alicyclic diisocyanates and

A resin composition for powder coatings that comprises a composition (A) and a blocked polyisocyanate compound (B), the composition (A) being based on both a carboxyl group containing polyester resin having a hydroxyl value of 10 to 100 and a softening point of 50.degree. to 150.degree. C. and a glycidyl group containing acrylic resin having a hydroxyl value of 30 to 150 and a softening point of 50.degree. to 150.degree. C., and further containing a copolymer prepared by reaction between said polyester and acrylic resins. This resin composition is capable of providing an ideal paint film that possesses the features of a paint film prepared from polyester resins (high degrees of smoothness, gloss and strength) and those of a paint film prepared from acrylic resins (high levels of hardness, stain resistance and weatherability).

A composition for thermosetting powder coating, which comprises

Composition for thermosetting powder coating

Polyisocyanato-isocyanurate and mixture of the same obtained by trimerizing straight chain aliphatic diisocyanate represented by the formula:

Polyisocyanato-isocyanurate, and preparation process and use of the same

Herein disclosed are a polyisocyanato-isocyanurate represented by the following formula (I): ##STR1## wherein n is an integer ranging 1 to 5 and R.sub.1, R.sub.2 and R.sub.3 may be the same or different and each represents hydrogen atom or a lower alkyl group and a method for preparing it; and a resin containing an organic polyisocyanate containing not lower than 10% by weight of the polyisocyanato-isocyanurate represented by Formula (I) and a compound having at least two active hydrogen atoms as well as a resin composition for coating materials which comprises the resin.

Polyisocyanatoalkylphenyl-isocyanurates, method for the preparation

Herein disclosed are a polyisocyanato-isocyanurate represented by the following formula (I): ##STR1## wherein n is an integer ranging 1 to 5 and R.sub.1, R.sub.2 and R.sub.3, may be the same or different and each represents hydrogen atom or a lower alkyl group and a method for preparing it; and a resin containing an organic polyisocyanate containing not lower than 10% by weight of the polyisocyanato-isocyanurate represented by Formula (I) and a compound having at least two active hydrogen atoms as well as a resin composition for coating materials which comprises the resin.

A chipping-resistant coating resin composition having an active-hydrogen containing compound and a blocked isocyanate. The active-hydrogen containing compound is composed of

Chipping-resistant coating resin composition, chipping-resistant coating

A methyl methacrylate syrup composition comprises an intimate mixture of 1-99 parts by weight of a first polymer-in-monomer syrup (A) and 99-1 parts by weight of a second polymer-in-monomer syrup (B), wherein said syrups (A) and (B) are as follows: (A) a polymer-in-monomer syrup obtained by copolymerizing a mixture of methyl methacrylate monomer, one or more monomers having reactivity with glycidyl groups and containing at least one ethylenically-unsaturated bond, and one or more monomers not having reactivity with glycidyl groups and containing at least one ethylenically-unsaturated bond; (B) a polymer-in-monomer syrup obtained by dissolving a copolymer obtained by copolymerizing one or more monomers containing at least one glycidyl group and one or more monomers copolymerizable with glycidyl-containing monomers, having a number average molecular weight of 1,500-50,000 and containing glycidyl groups, in a mixture of monomers comprising one or more monomers selected from the group consisting of methyl methacrylate and a monomer not having reactivity with glycidyl groups and containing at least one ethylenically-unsaturated bond, and one or more monomers having reactivity with glycidyl groups and containing at least one ethylenically-unsaturated bond, and having the resulting solution react until 1-99% of the glycidyl groups contained in the copolymer are reacted.

Methyl methacrylate syrup composition

A methyl methacrylate syrup composition comprises an intimate mixture of 1-99 parts by weight of a first polymer-in-monomer syrup (A) and 99-1 parts by weight of a second polymer-in-monomer syrup which can be either (B.sub.1) or (B.sub.2), wherein the syrups (A), (B.sub.1) and (B.sub.2) are as follows:

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Kanagawa, Japan

Taisaku Kano