L'air Liquide, Soci&#xe9;t&#xe9; Anonyme Pour L'etude Et L'exploitation Des Proc&#xe9;d&#xe9;s Georges Claude

American Air Liquide, Inc.

Air Liquide Advanced Technologies U.S. LLC

University of Illinois

L'air Liquide Societe Anonyme Pour L'etude

Et L'exploration Des Procedes Georges Claude

Taekyu Kang

Pavol Pranda

James J F McAndrew

Robert A Gagliano

Nicolas Docquier

Vivek Gautam

Hwanho Kim

Remi Tsiava

Jean-Philippe Tadiello

Ryan B Adelman

Rong Fan

Thomas Wenz

Bertrand Leroux

Remi Pierre Tsiava

Benoit Grand

Farrukh Alvi

Youssef Joumani

Henri Chevrel

Magnus Mortberg

Rajeev S Prabhakar

Robert Sokola

Michael G K Grant

Jiefu Ma

Vijaykant Sadasivuni

Yue Chen

Mark A Shannon

Maik Lehmann

Swatantra Kumar Shrivastava

Tao Li

Byunghoon Bae

Benjamin J Jurcik, Jr

Mona L Shannon

Jihyung Kim

Chendhil Periasamy

Yuan Xue

Ashkan Iranshahi

James JF Mcandrew

Ryan Adelman

Jr Benjamin J Jurcik

Chen Yue

A plant for producing a synthesis gas chiefly consisting of hydrogen and carbon monoxide by catalytic steam reformation of a hydrocarbonaceous feed gas, wherein the heat of burners required for the chemical reforming reactions to take place is generated by producing a flue gas and wherein, by utilizing the heat contained in the synthesis gas and in the flue gas, a pure steam is generated from boiler feed water and a process steam is generated from process condensate, wherein for the generation of the pure steam synthesis gas and flue gas are used and for the generation of the process steam a part of the pure steam is used as heat-transfer medium and the remaining part of the pure steam is discharged from the process as export steam.

Process and plant for the production of synthesis gas by means of catalytic steam reformation of a hydrocarbonaceous feed gas

A radiative recuperator preheats oxidant and/or fuel for combustion at one or more burners of a furnace. The recuperator includes a duct, at least portions of which comprise a material having a thermal conductivity of greater than 1 W/(m&#xb7;K), preferably greater than 3 W/(m&#xb7;K), that receives hot flue gas produced by the burner(s). The duct radiatively transfers heat to oxidant or fuel (for preheating) flowing through one or more metallic pipes disposed in between the duct and an insulating wall.

Furnace with integrated heat recovery utilizing radiative recuperator for preheating combustion reactants using heat from flue gas

Plant and process for the generation of hydrogen from a hydrocarbonaceous feed gas and steam by means of catalytic steam reformation, wherein the heat of the synthesis gas and the flue gas is utilized for generating export steam from boiler feed water and process steam from the condensate separated from the synthesis gas, and wherein the gases expelled from the boiler feed water during its degasification and the vapors obtained during the depressurization of the elutriation waters of the steam boilers for the generation of export and process steam are used for preheating the fuel gas for operation of the burners of the steam reformer.

Process and plant for producing hydrogen by means of catalytic steam reformation of a hydrocarbonaceous feed gas

A process and plant for producing a synthesis gas chiefly consisting of hydrogen and carbon monoxide by catalytic steam reformation of a hydrocarbonaceous feed gas, wherein the heat of burners required for the chemical reforming reactions to take place is generated by producing a flue gas and wherein, by utilizing the heat contained in the synthesis gas and in the flue gas, a pure steam is generated from boiler feed water and a process steam is generated from process condensate, wherein for the generation of the pure steam synthesis gas and flue gas are used and for the generation of the process steam a part of the pure steam is used as heat-transfer medium and the remaining part of the pure steam is discharged from the process as export steam.

Disclosed are methods for operating a glass furnace, the method comprises the steps of feeding a non-pre-reformed hydrocarbon fuel gas stream to a pre-reformer forming a pre-reformed hydrocarbon fuel gas stream, feeding the pre-reformed hydrocarbon fuel gas stream to burners of the furnace, combusting oxidant and the pre-reformed hydrocarbon fuel gas with the burners to produce flue gas, heating air through heat exchange with the flue gas at a recuperator, and transferring heat from heated air to pre-reformer tubes of the pre-reformer. A glass furnace system is also disclosed.

Enhanced waste heat recovery using a pre-reformer combined with oxygen and fuel pre-heating for combustion

An improved hydrogen generation system and method for using the same are provided. The system includes an HDS unit configured to remove sulfur, a first and second pre-reformers configured to pre-reform a process gas and fuel gas, respectively, a first and second heat exchangers configured to dry and heat the pre-reformed fuel gas, respectively, and a reformer configured to produce a syngas and flue gas. The method includes using a process stream selected from the group consisting of air, PSA off-gas, hydrocarbon gas, and combinations thereof to dry the fuel gas and using a process stream selected from the group consisting of the flue gas, the syngas, and combinations thereof to heat the dry fuel gas. The second pre-reformer is a low-pressure pre-reformer, so that the heat contents of the fuel gas is increased through converting heavy hydrocarbons in the fuel gas to CO and Hby the second pre-reformer.

Maximizing steam methane reformer combustion efficiency by pre-heating pre-reformed fuel gas

Methods, burner, apparatuses, and systems are provided for controlling a velocity of a jet of gas exiting a burner when the gas is heated or not and at a corresponding second higher temperature or lower first temperature. Through the use of a temperature-sensitive magnetic valve, the flow of a gas can be redirected to maintain velocity of the gas as delivered to a combustion chamber based on the temperature of the gas. The temperature-sensitive magnetic valve can redirect flow of the gas based on the magnetic state of a ferromagnetic material. The state of the temperature-sensitive magnetic valve changes based on the temperature of the gas to maintain the velocity of the gas delivered through an outlet of the burner to the combustion chamber. Thus, heated gases and standard temperature gases can be delivered at approximately equal velocities thus maintaining flame size and shape.

Method and burner using the curie effect for controlling reactant velocity for operation in pre-heated and non-pre-heated modes

An improved hydrogen generation system and method for using the same are provided. The system includes an HDS unit configured to desulfurize hydrocarbons, a pre-reformer configured to convert heavy hydrocarbons within the process gas stream to methane, a reformer configured to produce a syngas stream and a flue gas, a PSA unit configured to produce a product hydrogen stream and a PSA off-gas stream, and means for cooling the flue gas against a combustion air and the PSA off-gas stream to a temperature below the dew point of sulfuric acid.

System and methods for improving natural gas usage in steam methane reformers

A plurality of independently flow rate-controlled flows of oxidant may be preheated at a heat exchanger (or both oxidant and fuel at separate heat exchangers) by heat exchange with a hot shell-side (heat transfer) fluid. The separate flows of hot oxidant are directed to associated separate burners where they combust with flows of fuel to produce hot combustion gases. The hot combustion gases are used to preheat the hot shell-side fluid at a recuperator or regenerator.

Method and system for heat recovery from products of combustion and charge heating installation including the same

Temperature overshoot of internal components of a counter-flow shell and tube heat heat exchange may be reduced or avoided by adjusting the degree to which a tube-side fluid partially bypasses the heat exchanger.

Method and heat exchange system utilizing variable partial bypass

A plurality of independently flow rate-controlled flows of fuel may be preheated at a heat exchanger (or both oxidant and fuel at separate heat exchangers) by heat exchange with a hot shell-side (heat transfer) fluid. The separate flows of hot fuel are directed to associated separate burners where they combust with flows of fuel to produce hot combustion gases. The hot combustion gases are used to preheat the hot shell-side fluid at a recuperator or regenerator.

A portable gas analyzer comprising an integrated micro-flame ionization detector (micro-FID), a micro-gas chromatograph (micro-GC), an electrolyzer, and a flame-shaped electrode are provided. The components of the portable gas analyzer can be integrated into a single 'lunchbox' sized housing with all the peripherals required to operate the micro-GC/FID without an external power and gas supply.

Portable gas analyzer

An apparatus for decreasing steam methane reformer (SMR) tube temperature is provided. The apparatus can include an SMR furnace, a monitoring system in communication with the SMR furnace and a water source in fluid communication with the SMR furnace. The SMR furnace includes a plurality of SMR tubes disposed within the SMR furnace. The monitoring system is configured to monitor the temperature of at least a plurality of SMR tubes and compare the temperature against a first predetermined value, and the water source is configured to introduce water to an SMR tube that has a temperature above the first predetermined value, such that the temperature of the SMR tube is reduced.

Apparatus for decreasing SMR tube temperature

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Newark, DE, United States of America

Taekyu Kang