Lg Chem, Ltd

Tae Young Won

Chang Hun Han

Hyemin Lee

Kwangin Shin

Junwye Lee

Jungmin Sohn

Seongbeom Heo

Chang Sun Han

Dae Woo Nam

Sung Soo Park

Minsu Kim

Yong Hun Lee

Sang Gi Lee

Jun Kyu Kim

Yun Jin Kim

Chul Hee Ryu

Young Jae Hur

Jun Wye Lee

Jin Hyun Bae

Jong Hyuk Kwon

Jihye Ryu

A polymerization reactor for production of a super absorbent polymer according to the present disclosure includes: a composition supply part for supplying a monomer composition solution; a central pipe connected to the composition supply part; a composition distribution part including a water storage tank located at a discharge port of the central pipe; a distribution pipe connected to the water storage tank; and an ultrasonic device installed inside the water storage tank, a conveyor belt located under the composition distribution part and on which the composition solution is dropped, and an energy supply part for supplying polymerization energy to the composition solution on the conveyor belt, wherein the ultrasonic device supplies bubbles to the composition solution flowing into the water storage tank.

Polymerization reactor for production of super absorbent polymer

According to the method for preparation of a super absorbent polymer according to the present disclosure, fine particles present in the prepared super absorbent polymer are removed, thereby solving a dispersion problem of the fine particles and a problem of reduction in the physical properties of the super absorbent polymer.

Method for preparation of super absorbent polymer

The present disclosure relates to a preparation method of a super absorbent polymer capable of preparing a super absorbent polymer exhibiting an improved absorption rate while reducing an amount of a blowing agent used. The preparation method of a super absorbent polymer includes: preparing a monomer mixture including a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups and an internal cross-linking agent; adjusting a dynamic pressure applied to the monomer mixture being transferred to 140 Pa or more by controlling a transfer rate while transferring the monomer mixture to a polymerization reactor; cross-linking and polymerizing the monomer mixture transferred to the polymerization reactor to form a hydrogel polymer; drying, pulverizing and classifying the hydrogel polymer to form a base resin powder; and further cross-linking a surface of the base resin powder in the presence of a surface cross-linking agent to form a surface cross-linked layer.

Preparation method of super absorbent polymer

The present disclosure relates to a preparation method of a super absorbent polymer having excellent basic absorbency and liquid permeability at the same time by optimizing the degree of cross-linking of a base resin powder and a surface cross-linked layer, and a super absorbent polymer prepared therefrom. The preparation method of a super absorbent polymer includes: forming a hydrogel polymer by cross-linking and polymerizing a monomer composition including a water-soluble ethylene-based unsaturated monomer having a degree of neutralization of less than 72 mol % and an internal cross-linking agent; drying, pulverizing and classifying the hydrogel polymer to form a base resin powder; forming a surface cross-linked layer by further cross-linking a surface of the base resin powder in the presence of a surface cross-linking agent; and further neutralizing the base resin powder by treating the base resin powder with a basic solution during or after forming a surface cross-linked layer.

Preparation method of super absorbent polymer and super absorbent polymer therefrom

The present disclosure relates to a super absorbent polymer and a preparation method of the same, which not only has excellent basic absorption performance, but also exhibits an improved absorption rate, and the like. The super absorbent polymer includes a base resin powder containing a first cross-linked polymer of a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups; and a surface cross-linked layer containing a second cross-linked polymer in which the first cross-linked polymer is additionally cross-linked by a surface cross-linking agent on the base resin powder, wherein the super absorbent polymer contains less than 9.9% by number of super absorbent polymer particles having an aspect ratio, which is defined as shortest diameter/longest diameter of each super absorbent polymer particle, of less than 0.5, a vortex time is 5 to 55 seconds by a vortex method, and a surface tension is 50 to 80 mN/m.

Super absorbent polymer and preparation method thereof

The present disclosure relates to a preparation method of a super absorbent polymer capable of improving absorption performance of the super absorbent polymer by adding a simple additive later. The preparation method includes the steps of: forming a hydrogel polymer by cross-linking and polymerizing a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups in the presence of an internal cross-linking agent; drying, pulverizing and classifying the hydrogel polymer to form a base resin powder; forming a surface cross-linked layer by further cross-linking a surface of the base resin powder in the presence of a surface cross-linking agent, adding a monovalent to trivalent metal cation on the surface cross-linked base resin powder at a temperature of 25&#xb0; C. to 80&#xb0; C., and maintaining and aging the resulting metal cation-added product at a temperature of 40&#xb0; C. to 60&#xb0; C. for 10 to 30 minutes.

Provided are a superabsorbent polymer having a high bulk density value and showing a reduction in unpleasant odors which may be caused by various additives included in a preparation process while basically maintaining excellent absorption performance and absorption rate, and a preparation method thereof.

Superabsorbent polymer and preparation method thereof

A method of preparing a superabsorbent polymer is provided, which is able to improve physical properties and to recycle fine powder generated during the preparation process. Particularly, a method of preparing a superabsorbent polymer capable of improving physical properties by using a base resin including a water-containing gel polymer and a base-treated fine powder regranulated body, which are different from each other in degree of neutralization, during preparation of the superabsorbent polymer, is provided.

Preparation method of superabsorbent polymer

This disclosure relates to a method for preparing superabsorbent polymer. The method for preparing superabsorbent polymer according to one aspect of the invention comprises obtaining hydrogel polymer during the process of preparing superabsorbent polymer, and then, spraying a surface crosslinking solution comprising a surface crosslinker, alcohol, and ionic liquid to crosslink the surface of the pulverized polymer. The method for preparing superabsorbent polymer may use ionic liquid without using lower alcohol, or if lower alcohol is used together, may minimize the amount, and thus, reduce cost and additional drying treatment, and may control swelling of gel to prepare superabsorbent polymer with excellent product properties.

Method of preparing superabsorbent polymer

The present invention relates to a superabsorbent polymer which has excellent initial absorbency and keeps water from flowing out under pressure even after passage of time. The superabsorbent polymer of the present invention is characterized by simultaneously optimizing centrifuge retention capacity (CRC), absorbency under pressure (AUP), liquid permeability (SFC), and gel strength within a predetermined range. The present invention can provide improved physical properties of a final diaper product and apply an ultra-thin technology to the diaper product.

Superabsorbent polymer

The present invention relates to a method of preparing a super absorbent polymer (SAP). The preparation method for SAP according to the present invention includes: preparing a first polymer by carrying out a thermal polymerization or photo polymerization of a monomer composition comprising a water-soluble ethylene-based unsaturated monomer and a polymerization initiator; preparing a second polymer by carrying out a thermal polymerization or photo polymerization of a monomer composition comprising a water-soluble ethylene-based unsaturated monomer and a polymerization initiator; drying the first polymer; milling the dried first polymer; and mixing the milled first polymer with the second polymer in the free swelling state using the crosslinking solution to cause a crosslinking reaction of the first and second polymers. According to the present invention, it is possible to obtain a super absorbent polymer (SAP) having high centrifuge retention capacity and high absorption under pressure.

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Daejeon, South Korea

Tae Young Won