Engelhard Corporation

Lummus Technology Inc.

Tadeusz W Langner

Steven M Kuznicki

Valerie A Bell

Jacqueline S Curran

Anne Mae Gaffney

Ruozhi Song

Chuen Yuan Yeh

Ruma Ghosh

Richard M Jacubinas

Marshall J Margolis

A catalyst useful for the alkylation or transalkylation of aromatic compounds is disclosed. The catalyst is an acid-treated zeolitic catalyst produced by a process including contacting an acidic zeolitic catalyst comprising surface non-framework aluminum and framework aluminum with an organic dibasic acid at a catalyst to acid weight ratio in the range from about 2:1 to about 20:1 and at a temperature in the range from about 50&#xb0; C. to about 100&#xb0; C. to selectively remove at least a portion of the surface non-framework aluminum. The resulting catalyst may have a measured first-order rate constant, k, for the alkylation of benzene with propylene to form cumene, of at least 2.0 cm/s g.

Catalysts useful for the alkylation of aromatic hydrocarbons

A catalyst for the oxidative dehydrogenation of a paraffin to form an olefin, the catalyst having a general formula MoVXYOwherein: X=at least one of Nb and Ta; Y=at least one of Te, Sb, Ga, Pd, W, Bi and Al; a=1.0; b=0.05 to 1.0; c=0.001 to 1.0; d=0.001 to 1.0; and n is determined by the oxidation states of the other elements. The catalyst may have a selectivity to the olefin of at least 90 mole % at a paraffin conversion of at least 65%.

Catalysts for the conversion of paraffins to olefins and use thereof

A process for forming a catalyst useful for the production of an olefin from a hydrocarbon is disclosed. The process may include: admixing at least one of elemental metals and compounds to form a multi-metal composition comprising Mo, V, Nb, Te and at least one of Ni and Sb; adjusting the pH of the multi-metal composition by adding nitric acid; drying the acidified multi-metal composition; calcining the dried multi-metal composition; and grinding the calcined multi-metal composition. The ground multi-metal composition may then be sized or shaped to form a mixed metal oxide catalyst. Alternatively, the ground multi-metal composition may be treated with an acid, optionally annealed, and sized or shaped to form a mixed metal oxide catalyst.

Process for making catalysts useful for the conversion of paraffins to olefins

Novel morphologies are provided for aluminosilicate zeolite ion-exchange materials useful for static water softening. The zeolites are provided in the form of large aggregates composed of submicron zeolite crystals. Rapid exchange rates, high hardness ion capacity and increased attrition resistance characterize the zeolite ion exchangers.

Macroscopic aggregates of microcrystalline zeolites for static water softening applications

A method of water softening utilizes macrocrystalline aggregates consisting essentially of submicron crystals of aluminosilicate zeolite. The aggregates have a size of greater than 5 microns and are used in a static bed water softening device. Both regenerable and disposable water softening materials can be provided.

Method of static water softening using zeolites of novel morphology

A simplified method of forming a porous crystalline titanium silicate membrane comprises preforming a mass of titanium dioxide particles into a consolidated preform such as by pressing into a thin film, and contacting the thin film of titanium dioxide with an aqueous alkaline silicate synthesis solution at a temperature and for a period of time sufficient to form the titanium silicate in-situ.

Simplified methods of manufacturing titanium silicate membranes

This invention relates to zeolitic molecular sieve compositions and hybrid zeolite-silica compositions characterized by novel morphology in which the zeolite is present as macroscopic aggregates of microcrystalline zeolite. The zeolitic compositions of this invention have outstanding capability to complex multivalent cations, especially calcium due to the high exchange kinetics of the microcrystalline zeolite component and yet have the ease of handling due to the macroscopic aggregate assemblage.

Macroscopic aggregates of microcrystalline zeolites

Aluminosilicate zeolites are formed in a novel reaction medium which contains a silicate source and an aluminum source in an aqueous alkaline solution and which reaction medium further includes an additional electrolyte salt. The addition of the electrolyte salt provides nucleation sites for the zeolite so as to form very small crystals. In high silica reaction environments, it is possible to form high aluminum zeolites which contain occluded silicate and wherein the morphology of the zeolites comprise macroscopic aggregates of microcrystalline zeolites. The addition of the electrolyte salt can also decrease the reaction time or temperature needed for crystallization.

Method of forming aluminosilicate zeolites

The present invention relates to a method of forming an aluminosilicate zeolite having a Si/Al&lE;1.1. The method comprises forming a reaction mixture by mixing a source of silica, and a source of aluminum in an aqueous alkaline solution having a pH of at least 12.0, wherein the Si/Al of said mixture is greater than 1.0.

Method of forming high aluminum aluminosilicate zeolites

Sodalite is treated with acid to transform the surface to provide a highly macroporous material that demonstrates water swing capacities exceeding those of high performance, low temperature desiccants under high latent load at relatively high ambient temperature and humidities.

Macroporaus aluminosilicate desiccant, preparation from sodalite and use in enthalpy energy wheels

This invention relates to zeolitic molecular sieve compositions characterized by outstanding capability to complex multivalent cations, especially calcium. In particular, the invention relates to novel zeolitic molecular sieve compositions, especially those based on molecular sieves having a high alumina-to-silica ratio, in which crystals of the zeolite are modified by the inclusion of occluded silicate.

Growing community of inventors

Linden, NJ, United States of America

Tadeusz W Langner