Gunze Limited

Tadayoshi Tanaka

Naoki Ohno

Masaharu Maruo

Hiroyuki Furukawa

Akira Morikawa

The present invention provides a heat shrinkable multilayer film that has low density, excellent shrinkage properties, and high rigidity, is less likely to suffer delamination, and also has excellent transparency. The present invention relates to a heat shrinkable multilayer film, containing: front and back layers; and an interlayer, the front and back layers each containing 60 to 80% by weight of a cyclic olefin resin and 20 to 40% by weight of an ethylene resin, the interlayer containing 50 to 80% by weight of an olefin resin and 20 to 50% by weight of a plastic resin, the interlayer containing 35 to 70 mol % of a propylene component, 1 to 10 mol % of an ethylene component, and 1 to 10 mol % of a butene component, based on 100 mol % of resin components constituting the interlayer.

Heat-shrinkable multi-layer film

The present invention provides the following multilayer heat-shrinkable styrene-based film having an appropriate surface shape, together with excellent lubricity and blocking resistance, and resistance to ink skipping and like problems during the printing process:

Multilayer heat-shrinkable styrene-based film and method for producing the same

A primary object of the present invention is to provide a multilayer heat-shrinkable styrene-based film that makes it possible, even when the film is transparent, to confirm that the film is correctly applied on a drink bottle and the like as a label. The present invention provides a heat-shrinkable styrene-based film having at least one layer containing a styrene-based resin containing a copolymer b1 of 98 to 40% by weight vinyl aromatic hydrocarbon and 2 to 60% by weight aliphatic unsaturated carboxylic acid ester, and/or a block copolymer b2 of 70 to 85% by weight vinyl aromatic hydrocarbon and 15 to 30% by weight conjugated diene hydrocarbon, and a fluorescent brightening agent in an amount of 100 to 2,000 weight ppm with respect to the total weight of the styrene-based resin. The present invention also provides a heat-shrinkable film having a three-layer structure containing front and back layers and a core layer, wherein the above-mentioned copolymer b1 and/or copolymer b2 forms the core layer.

Growing community of inventors

Moriyama, Japan

Tadayoshi Tanaka