Asahi Kasei Kogyo Kabushiki Kaisha

Tadashi Ikegami

Hisaya Sakurai

Yoshihiko Katayama

Hideo Morita

Masayasu Furusato

Katsuhiko Takaya

Masayoshi Miya

Itsuho Aishima

Shigeo Tsuyama

Yukichi Takashi

Toshio Sato

Kisoo Moriguchi

Shigeru Mizutani

Haruyuki Yoneda

Katsuaki Maeda

Yukitoshi Iwashita

A polyethylene composition comprising three specific types of polyethylenes; polyethylene (A), polyethylene (B) and polyethylene (C) respectively. The polyethylene composition has a melt index not less than 0.001 g/10 min. and not more than 10 g/cm and exhibits excellent processability under variant molding techniques. Molded objects exhibit excellent physical properties such as impact strength environmental stress cracking resistance and uniform thickness distribution. Polyethylene (A) has a molecular weight of from 5,000 to 90,000 and polyethylene (C) has a molecular weight of from 100,000 to 1,500,000 and the ratio of the molecular weight of polyethylene (C)/the molecular weight of polyethylene (A) is from 4 to 200. Polyethylene (B) has a molecular weight of from 50,000 to 500,000, being prepared by a polymerization with use of a chromium compound-supported type catalyst capable of producing a specifically conditioned homopolyethylene with respect to the properties of the polymers in terms of flow ratio and die swell.

Polyethylene composition

A process for polymerizing an .alpha.-olefin which comprises contacting the .alpha.-olefin at a temperature of about 10.degree. C. to about 100.degree. C. with a catalyst comprising a slurry component (A) and an organometallic component (B), the component (A) being obtained, without intermediate or final solids separation, by reacting (1) a slurry reaction mixture produced by reacting one mol of (i) a hydrocarbon-soluble organomagnesium component of the general formula

Polymerization of olefins

A catalyst useful for polymerizing olefins which comprises a solid catalyst component [A] and an organometallic component [B], the solid catalyst component [A] being obtained by reacting (1) an organometallic compound with (2) a transition metal compound selected from the group consisting of a titanium compound, a vanadium compound, a mixture of a titanium compound and a vanadium compound and a mixture of a titanium compound and a zirconium compound, in the presence of (3) a solid reaction product of (a) an organomagnesium compound of the formula

A catalyst suitable for use in the polymerization of olefins is disclosed. This catalyst contains:

Catalyst for polymerization of olefins

A catalyst useful for polymerizing olefins which comprises a solid catalyst component [A] and an organometallic component [B], the solid catalyst component [A] being obtained by reacting (1) a solid inorganic oxide, (2) a hydrocarbon-soluble organomagnesium component of the general formula

Catalyst for polymerization of olefins and polymerization process

Olefin polymerization catalyst and a process for producing polyolefins

A catalyst suitable for polymerizing an .alpha.-olefin, comprising a solid catalyst component [A] and an organometal compound [B], the solid catalyst component [A] being prepared by reacting an organomagnesium compound (1) soluble in a hydrocarbon medium and represented by the general formula,

Catalyst for producing polyolefins

An olefin polymerization catalyst which shows an extremely high activity even at low temperatures and is suited for the production of blow molding polymers, said catalyst comprising a solid component constituted by a chromium compound supported by an inorganic oxide carrier, and an organomagnesium complex compound soluble in the inert hydrocarbons and represented by the general formula: M.sub..alpha. Mg.sub..beta. R.sub.p.sup.1 R.sub.q.sup.2 R.sub.r.sup.3 X.sub.s Y.sub.t (wherein .alpha.&gt;0, .beta.&gt;0, p.gtoreq.0, q.gtoreq.0, r.gtoreq.0, s&gt;0, t.gtoreq.0, 0&lt;(s+t)/(.alpha.+.beta.).ltoreq.1.5 and p+q+r+s+t=m.alpha.+2.beta.; M is an atom selected from the group consisting of aluminum, zinc, boron, beryllium and lithium; m is the valence of M; R.sup.1, R.sup.2 and R.sup.3 may be same or different and represent respectively a hydrocarbon radical having 1 to 20 carbon atoms; X is OSiR.sup.5 R.sup.6 R.sup.7 ; and Y is a radical selected from the group consisting of OR.sup.4, OSiR.sup.5 R.sup.6 R.sup.7, NR.sup.8 R.sup.9 and SR.sup.10, wherein R.sup.5, R.sup.6, R.sup.7, R.sup.8 and R.sup.9 represent respectively a hydrocarbon radical or hydrogen atom, and R.sup.4 and R.sup.10 represent a hydrocarbon radical).

Olefin polymerization catalyst and olefin polymerization method using

Novel hydrocarbon-soluble isopropyl group-containing diorganomagnesium compounds and hydrocarbon solutions thereof are disclosed. The compound of the present invention has a high weight percent of Mg per one mol thereof, and the hydrocarbon solution of the present invention has a very low viscosity as compared with the conventional solutions. The hydrocarbon solution of the present invention can be prepared according any of various processes. If the reaction is carried out in an ether medium, the ether is substituted with a hydrocarbon solvent by removing the ether from the reaction mixture by distillation in the presence of the hydrocarbon solvent.

Hydrocarbon-soluble diorganomagnesium compounds, hydrocarbon solutions

A polyethylene composition comprising a mixture of three kinds of polyethylenes (A), (B) and (C) characterized in that:

Blend of three ethylene polymers

A process for polymerizing an .alpha.-olefin comprising contacting the olefin in liquid phase at a temperature of about 120.degree. to about 320.degree. C. with a catalyst comprising a component (A) and an organometal component (B), the component (A) being produced by reacting a hydrocarbon-soluble organomagnesium component (i) of the formula,

Process for polymerizing an .alpha.-olefin

A catalyst for the solution polymerization of .alpha.-olefins is prepared by admixing component (A) with an organometal component (B), component (A) being prepared by reacting a specific hydrocarbon-soluble organomagnesium compound with an aluminum compound and contacting the obtained product with a titanium and/or vanadium compound.

Polymerization of .alpha.-olefins

A process for polymerizing an .alpha.-olefin comprising contacting the olefin in liquid phase at a temperature of about 120.degree. to about 320.degree. C. with a catalyst comprising a component (A) and an organometal component (B), the component (A) being produced by reacting a hydrocarbon-soluble organomagnesium component (i) of the formula

Polymerization of an .alpha.-olefin

A process for polymerizing an .alpha.-olefin comprising contacting the olefin in liquid phase at a temperature of about 120.degree. to 320.degree. C. with a catalyst comprising a component (A) and an organometal component (B), the component (A) being produced by reacting a hydrocarbon-soluble organomagnesium component (i) of the formula,

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Kurashiki, Japan

Tadashi Ikegami