Nippon Shokubai Kagaku Kogyo Co., Ltd.

Nippon Shokubai Co., Ltd.

Nisshin Seifun Kabushiki Kaisha

Ahsu Kurin Kabushiki Kaisha

Nippon Shokubai Kagaku Kabushiki Kaisha

Tadao Shimomura

Kazumasa Kimura

Nobuyuki Harada

Yoshio Irie

Takumi Hatsuda

Kinya Nagasuna

Koji Miyake

Kenji Kadonaga

Tsuneo Tsubakimoto

Takashi Namba

Yoshinori Sano

Kazuhiro Okamura

Hiroya Kobayashi

Teruaki Fujiwara

Kunihiko Ishizaki

Katsuhiro Kajikawa

Yoshihiko Masuda

Yoshihiro Motono

Hitoshi Takahashi

Yoshiyuki Takahashi

Jyunichi Saga

Katsuyuki Wada

Shigeru Sakamoto

Kazuhisa Hitomi

Tomoki Gomi

Hisanori Obara

Kaoru Iwasaki

Naoyuki Shirane

Toshihiro Okuno

Katsumi Terawaki

Masashi Nakaki

A method for the production of (D) an absorbent resin excelling in durability, which method comprises polymerizing (A) 30% by weight to saturated concentration of (A) an aqueous water-soluble ethylenically unsaturated monomer solution containing (B) 0.005 to 5 mol % of a cross-linking agent and (C) 0.001 to 1 mol % of a water-soluble chain transfer agent, both based on the amount of said monomer (A), and if necessary, the surface region of the resultant absorbent resin (D) is cross-linked with (E) a hydrophilic cross-linking agent capable of reacting with the functional group of the absorbent resin and an absorbent resin obtained by such method.

Method for production of absorbent resin excelling in durability

Method of producing a hydrophilic resin

A process for producing water-absorbent resins having an average particle diameter of 100 to 600 .mu.m and a particle diameter distribution of 0.35 or less by polymerizing an aqueous solution of a water-soluble ethylenically unsaturated monomer, pulverizing and sieving the polymer so obtained, and crosslinking the surface of the polymer powder.

Water absorbent resin

Thermal storage agent, manufacturing method thereof, thermal storage

A process for producing a water-absorbing resin, which comprises polymerizing (D) an aqueous solution comprising (A) at least one monomer component selected from the group consisting of an unsaturated carboxylic acid and salts thereof; (B) a compound having two or more unsaturated groups in a molecule; and (C) a compound having two or more functional groups which are capable of reacting with carboxyl groups in a molecule, the polymerization being conducted in such a manner that the following conditions (a) to (c) are simultaneously satisfied: (a) the molar ratio (B)/(C) being in the range of from 2.times.10.sup.-3 to 300, (b) the polymerization being initiated by a redox polymerization initiator, and (c) the maximum reaction temperature being in the range of from 60.degree. to 100.degree. C, and a water-absorbing resin having a degree of reduction in absorption magnification of from 1 to 16, and n absorption magnification under pressure of from 20 to 40.

Water-absorbing resin and process for producing same

An absorbent material produced by mixing 100 parts by weight of an absorbent polymer with 1 to 80 parts by weight of synthetic pulp in the presence of 1 to 40 parts by weight of water, an absorbent body produced by mixing 100 parts by weight of an absorbent polymer with 1 to 80 parts by weight of synthetic pulp in the presence of 1 to 40 parts by weight of water, dry mixing the resultant mixture with 10 to 1,000 parts by weight hydrophilic fibers based on 100 parts by weight of said absorbent polymer, pneumatically molding the resultant mixture in the form of web, and thermally compressing the resultant web to a density in the range of from 0.1 to 1.0 g/cm.sup.3, and a method for production thereof.

Absorbent material, absorbent body, and method for production thereof

The present invention provides a water absorbent matter which is physically and chemically stable, difficult in shifting and falling-off of a water-absorbent resin particle and from a cellulose fiber, and thereby, has superior water-absorbent properties. A water absorbent matter like this is made by containing a water-absorbent resin particle having an acidic group such as a carboxyl group on the surface, a cellulose fiber, and a cationic high-molecular compound having a weight-average molecular weight of 2,000 or more, so that the water-absorbent resin particle is firmly set on the cellulose fiber by a cationic high-molecular compound in the presence of water.

Water absorbent matter and method for producing it as well as water

An absorbent material produced by mixing 100 parts by weight of an absorbent polymer with 1 to 80 parts by weight of synthetic pulp in the presence of 1 to 40 parts by weight of water, an absorbent body produced by mixing 100 parts by weight of an absorbent polymer with 1 to 80 parts by weight of synthetic pulp in the presence of 1 to 40 parts by weight of water, dry mixing the resultant mixture with 10 to 1,000 parts by weight hydrophilic fibers based on 100 parts by weight of the absorbent polymer, pneumatically molding the resultant mixture in the form of web, and thermally compressing the resultant web to a density in the range of from 0.1 to 1.0 g/cm.sup.3, and a method for production thereof.

Absorbent material comprising absorbent polymeric particulate material

A method for the production of an acrylate by the neutralization reaction of acrylic acid and a basic substance, comprising sequentially (A) a step of supplying acrylic acid and said basic substance to water thereby subjecting them to a neutralization reaction while constantly retaining the neutralization ratio of acrylic acid within the neutralization reaction system in the range of 75 to 100 mol %, (B) a step of adjusting the neutralization ratio of acrylic acid within said neutralization reaction system in the range of 100.1 to 110 mol % by supplying said basic substance to said neutralization reaction system, (C) a step of retaining the neutralization ratio of acrylic acid within said neutralization reaction system in the range of 100.1 to 110 mol % for a period in the range of 1 to 120 minutes thereby allowing the neutralization reaction product to age, and (D) a step of adjusting the neutralization ratio of acrylic acid within said neutralization reaction system in the range of 20 to 100 mol % by supplying acrylic acid to said neutralization reaction system, and a method for the production of an acrylate-containing polymer using the acrylate.

Method for production of acrylate and acrylate-containing polymer

A waterproofing agent for an optical or electric cable, formed of a cross-linked macromolecular compound containing a sulfonic acid group or a salt thereof in an amount of not less than 0.5 mg. equivalent/g and a dissociating group in an amount of not less than 1.0 mg. equivalent/g, and a method for waterproofing said cable by packing said waterproofing agent in the sheath of said cables.

Method for waterproofing with a cross-linked macromolecular

Water-absorbent resins having an average particle diameter of 100 to 600 .mu.m and a particle diameter distribution of 0.35 or less are prepared by polymerizing an aqueous solution of a water-soluble ethylenically unsaturated monomer, pulverizing and sieving the gel-like polymer so obtained, and crosslinking the surface of the polymer powder. In an alternative process, an aqueous solution of the monomer having a viscosity greater than 15 cps is dispersed in a hydrophobic organic solvent and polymerized to obtain a polymer powder, and the surface of the polymer powder is crosslinked.

Water-absorbent resin and production process

A cable grade water proofing agent made of a cross-linked polymer produced by polymerizing a monomer mixture comprising at least one (meth)acrylic compound selected from the group consisting of (meth)acrylic acids and (meth)acrylic salts and a (meth)acrylamide in a molar ratio of said (meth)acrylic compound to said (meth)acrylamide in the range of from 1:9 to 5:5, said cross-linked polymer exhibiting a speed of absorption of not more than 8 minutes as expressed by the time required for the absorption of artificial seawater to reach 90% of the maximum, a capacity for absorption of said artificial seawater of not less than 8 times the own weight, and a gel viscosity in the range of from 0.6.times.10.sup.5 to 2.5.times.10.sup.5 dynes.multidot.s/cm.sup.3, and a composite waterproofing material carried on a substrate such as yarns and tape.

Waterproofing agent for cable

An absorbent body having an absorbent polymer and hydrophilic fibers as main components thereof, characterized by the fact that the density of said absorbent body is in the range of from 0.1 to 0.5 g/cm.sup.3 or a ratio of wet swelling is not less than 200%, a capacity of said absorbent body for absorption of physiological saline solution under pressure is in the range of from 11 to 25 g/g, and the ratio of exfoliation of said absorbent polymer is not more than 45%, and an absorbent article comprising a liquid-pervious surface material, a liquid-impervious lining material, and the absorbent body layer interposed therebetween.

Absorbent body and absorbent article

Waterproofing tape comprising ethylenic sulfonate polymers

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Toyonaka, Japan

Tadao Shimomura