Dai Nippon Printing Co., Ltd.

Dai Nippon Printingco., Ltd.

Tadahiro Ishida

Katsuyuki Oshima

Takayuki Imai

Kozo Odamura

Etsuo Takasaki

Masato Takao

Mitsuhiro Oota

Hideo Ito

Hiroyuki Yamashita

Daisuke Fukui

Shinya Yoda

Fumihiko Mizukami

Keiji Hirose

Junko Hirokawa

Megumi Ikeda

Toshikazu Kuwabara

Yusuke Narumi

Hirotaka Watanabe

Koichi Shirai

Tetsuya Matsuyama

Makoto Aoyagi

Hiroshi Funada

Norikazu Saito

Yuzu Imakura

The peel-off sheet according to the present disclosure includes a first substrate and a peel-off layer, wherein the peel-off layer contains a vinyl chloride-vinyl acetate copolymer and a crystalline polyester, or the peel-off sheet includes a structural component containing particles, wherein the particle size distribution of the particles contained in the structural component which is determined with a laser diffraction scattering particle size distribution analyzer has a maximum peak at a position of more than 0.2 μm and 5 μm or less.

Peel-off sheet, and combination of peel-off sheet and intermediate transfer medium

Provided is a thermal transfer sheet that can form a good image on both a transfer object made of a polyethylene terephthalate and a transfer object made of a polypropylene, as well as can form an image with high alcohol resistance. The thermal transfer sheet of the present invention includes a substrate, and a transfer layer including a colored layer and an adhesive layer, in which the adhesive layer has a phase-separated structure formed by a polyester and a polyolefin that are incompatible with each other, and in which the percentage of the region formed by one of the polyester and the polyolefin to the total area (100%) of the adhesive layer is 55% or more and 85% or less.

Thermal transfer sheet

An object is to provide a thermal transfer sheet that can prevent the occurrence of layer detachment and has high transferability for preventing the occurrence of transfer defects such as delamination trace and tailing. The thermal transfer sheet of the invention is characterized in that it includes a substrate, a release layer, and a transfer layer in that order, and the release layer contains at least one of alumina and alumina hydrate, and a binder resin.

A thermal transfer sheet is provided, which allows for forming an image favorable to any transfer objects having a poor smoothness or a high smoothness. The thermal transfer sheet according to the present invention includes a substrate, and a transfer layer. The transfer layer includes a release layer, a colorant layer and an adhesive layer. The release layer includes a polyethylene glycol having a number average molecular weight Mn in a range of 8000 or more to 23000 or less, and the colorant layer includes a colorant and a vinyl chloride-vinyl acetate copolymer.

Provided is a combination of a thermal transfer sheet and a seal-type printing sheet, the combination being capable of preventing occurrence of wrinkles in a print. In a combination of a thermal transfer sheet including a substrate and a colorant layer provided on one surface of the substrate and a seal-type printing sheet including a releasing substrate and a printing paper sheet with a pressure-sensitive adhesive layer provided on a portion of one surface of the releasing substrate, the difference between the dynamic friction coefficient between the colorant layer in the thermal transfer sheet and the printing paper sheet with a pressure-sensitive adhesive layer in the seal-type printing sheet and the dynamic friction coefficient between the colorant layer in the thermal transfer sheet and the releasing substrate in the seal-type printing sheet is 1.0 or less.

Combination of thermal transfer sheet and seal-type printing sheet, and thermal transfer sheet

Provided is a thermal transfer sheet which has satisfactory printability and provides a printed matter having excellent boiling resistance. Disclosed is a thermal transfer sheet which is provided with a substrate, at least a transferable protective layer and a transferable color layer in this order on one side of the substrate, and is provided with a back face layer on the other side of the substrate, characterized in that the transferable protective layer contains a cyclic olefin-based polymer having a glass transition temperature of 100&#xb0; C. or more as a main component and further contains an incompatible resin with the cyclic olefin-based polymer, and the transferable color layer contains a colorant and a phenolic resin having a softening point of 100&#xb0; C. or more.

In an intermediate transfer medium, a substrate, protective layers having a layered structure of two or more layers, and a receiving layer are layered in this order. One layer in the protective layers having the layered structure contains, as a main component, one material or a mixture of two or more materials selected from the group consisting of polyesters having a high polymerization degree, a number-average molecular weight (Mn) of not less than 12,000 and a Tg of not less than 60&#xb0; C., polycarbonates and polyester urethanes. Another layer in the protective layers having the layered structure contains one or more materials selected from the group consisting of polyvinyl alcohols, polyvinyl butyrals, polyvinyl acetals and polyvinyl pyrrolidones or includes a cationic resin, and the receiving layer contains a side chain-type aralkyl-modified silicone in an amount of 0.5-5% by weight on a base of the total weight of the receiving layer.

Intermediate transfer medium

A thermal transfer sheet comprising: a substrate; a heat resistant slip layer provided on one side of the substrate; an undercoat layer and a dye layer provided in that order on the other side of the substrate, wherein the undercoat layer is formed by using colloidal inorganic pigment ultrafine particles and a copolymer resin of vinyl pyrrolidone and vinyl acetate as main components.

A film transfer sheet including a sheet substrate provided with a layer via a resin layer and a peelable transparent sheet provided with an adhesive layer. The sheet substrate and the peelable transparent sheet are laminated together such that the layer is overlapped on the peelable transparent sheet and peeling is designed to occur between the layer and the peelable transparent sheet so as to transfer the peelable transparent sheet provided with the adhesive layer to a transfer-receiving member. The resin layer includes as an essential component a pressure-sensitive adhesive having a storage elastic modulus of 3.0 &#xd7;10Pa to 1.2 &#xd7;10Pa at a temperature of 130&#xb0; C. to 150&#xb0; C. Also provided is an intermediate transfer recording medium including a sheet substrate provided with a layer via resin layer and a peelable transparent sheet provided with a dye receptive layer, in which the sheet substrate and the peelable transparent sheet are laminated together.

Film transfer sheet and intermediate transfer recording medium

It is an object of the present invention to provide a thermal transfer sheet which has a high transfer sensitivity in thermal transfer printing to obtain a high density print, has a high sharpness of thermal transfer images, can prevent an abnormal transfer in printing even after being stored at high temperature and high humidity, and can provide a sufficiently satisfactory printed matter. The above object is achieved by a thermal transfer sheet comprising: a substrate; a heat resistant slip layer provided on one side of the substrate; an undercoat layer and a dye layer provided in that order on the other side of the substrate, wherein the undercoat layer is formed by applying and drying a coating liquid which contains, as main components, a water soluble self cross-linking resin and colloidal inorganic pigment ultrafine particles, and cross-linking polymerizing the water soluble self cross-linking resin, or wherein the undercoat layer is formed by using colloidal inorganic pigment ultrafine particles and a copolymer resin of vinyl pyrrolidone and vinyl acetate as main components.

An image forming method is provided to attain a higher security for preventing forgery and falsification of information by using an optical diffraction structure. In a body () whereupon a layer is to be transferred, printing information () is recorded. On the body (), a layer () including a hologram and a diffraction lattice provided on an optical diffraction structure transfer sheet () is transferred, and an image including recorded printing information () and optical diffraction structures () is formed. The layer () including the optical diffraction structure is transferred so that the diffraction lattice () to be transferred forms diffraction lattice information () showing a prescribed regularity in a corresponding relationship between the printing information ().

Image forming method and recorded matter

This invention provides a method for image formation, which can produce a thermally transferred image possessing excellent heat resistance and various fastness properties even under severe service conditions, and an intermediate transfer recording medium and an image formed object.

Growing community of inventors

Tokyo, Japan

Tadahiro Ishida