Fuji Photo Film Company, Limited

Syunichi Kondoh

Fumiaki Shinozaki

Tomoaki Ikeda

Akira Umehara

Sho Nakao

Akihiro Matsufuji

Yasuo Washizawa

Yasuo Washigawa

Akira Ogawa

Akira Sato

Tadao Shishido

Isamu Itoh

Yuji Ohara

Takeshi Takayama

A light-sensitive composition comprising addition polymerizable ethylenically unsaturated double bond-containing compounds and a photopolymerization initiator comprising (1) at least one compound selected from the group consisting of benzanthrone, substituted benzanthrones (the substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms), 1,2-benzanthraquinone and substituted benzanthraquinones (substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms) and (2) at least one compound selected from the group consisting of 4,4'-di-substituted amino-benzophenones represented by the following general formula (a), p-substituted amino-benzaldehyde derivatives represented by the following general formula (b), 2-(p-substituted amino-phenyl)-1,3-dioxolanes represented by the following general formula (c), 4,4'-bis(substituted amino)-N-benzylideneanilines represented by the following general formula (d) and 2-[4-(substituted amino)cinnamoyl]naphthalenes represented by the following general formula (e): ##STR1## wherein R and R', which may be the same or different, each represents a methyl group or an ethyl group, and R.sup.0 represents a hydrogen atom, a hydroxy group, a --CR.sup.1 R.sup.2 R.sup.3 group, where R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, each represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, or an --OR.sup.4 group, where R.sup.4 represents an alkyl group having 1 to 5 carbon atoms.

Light-sensitive ethylenically unsaturated materials containing

Light-sensitive photopolymerizable composition

Light-sensitive composition

A photopolymerizable composition comprising (1) an addition-polymerizable compound having at least one ethylenically unsaturated double bond and (2) a photopolymerization initiator as essential components, the improvement which comprises the photopolymerization initiator comprising a combination of (a) a 5-isoxazolone represented by the general formula (1) and (b) an aromatic carbonyl compound, a dialkylamino aromatic carbonyl compound represented by any of formulae (2) to (5), a compound represented by the formula (6) or 2-(.alpha.-thioxophenetylidene)-3-methylnaphtho[1,2-d][1,3]-thiazoline: ##STR1## wherein in the formula (1), A.sup.1 and A.sup.2 each represent an alkyl group, an alkylcarbonyl group, an alkoxycarbonyl group, an aryl group, an arylcarbonyl group or a hydrogen atom and may be the same or different; in the formulae (2) to (5) R.sup.1 and R.sup.2 each represent an alkyl group and may be the same or different, R.sup.3 represents an alkyl group, an aryl group, an aralkyl group, an alkoxy group, an aryloxy group or a 5- or 6-membered hetero-aromatic ring, and X represents a substituent having a Hammett's .sigma. value in the range of about -0.9 to +0.7; and in the formula (6) R.sup.4 represents an alkyl group, or an alkenyl group, R.sup.5 represents an alkyl group, an aryl group, a thienyl group or a furyl group, and Z represents an atomic group necessaary to form a nitrogen-containing heterocyclic ring; is disclosed.

Photopolymerizable compositions

A photopolymerizable composition is described comprising (1) an addition-polymerizable compound having at least one ethylenically unsaturated double bond, (2) a photopolymerization initiator, and (3) a post-exposure polymerization inhibitor compound including a thioureylene group, such as a compound selected from the group consisting of thiourea and thiourea derivatives represented by the general formula (I), thiosemicarbazide and thiosemicarbazide derivatives represented by the general formula (II), and thiosemicarbazone derivatives represented by the general formula (III): ##STR1## wherein: R.sup.1 and R.sup.2, which may be the same or different each represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, a substituted alkyl group having from 1 to 6 carbon atoms, a phenyl group, a naphthyl group, a substituted phenyl group or a monovalent group derived from an O-, S- or N-containing 5- or 6-member heterocyclic nucleus,

Photopolymerizable compositions containing inhibitor compounds having

In a photopolymerizable composition comprising (1) an addition-polymerizable compound having at least one ethylenically unsaturated double bond and (2) a photopolymerization initiator as essential components, the improvement which comprises that said photopolymerization initiator is a combination of (a) p-dialkylamino aromatic carbonyl compounds represented by the general formulae (1) to (4), (b) 5-isoxazolones represented by the general formula (5) and (c) 2,4,6-substituted-1,3,5-triazines represented by the general formula (6): ##STR1## where R.sup.1, R.sup.2 and R.sup.3 each represents an alkyl group or a substituted alkyl group, which may be the same or different from one another, X represents a substituent having a Hammett's .sigma. value in the range from -0.9 to 0.7, m represents 1 or 2, A.sup.1 and A.sup.2 each represents an alkyl group, a substituted alkyl group, an alkylcarbonyl group, an alkoxycarbonyl group, an aryl group, a substituted aryl group, an arylcarbonyl group or a hydrogen atom, which may be the same or different from each other, and R.sup.4, R.sup.5 and R.sup.6 each represents an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group or an aralkyl group, which may be the same or different from each other, but at least one of them represents a mono-, di- or trihalomethyl group.

Photopolymerizable compositions having combined photoinitiators

A light-sensitive composition comprising addition polymerizable ethylenically unsaturated double bond-containing compounds and a photopolymerization initiator comprising (1) at least one compound selected from the group consisting of benzanthrone, substituted benzanthrones (the substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms), 1,2-benzanthraquinone and substituted benzanthraquinones (substituents of which include halogen atoms, alkyl groups having 1 to 5 carbon atoms and alkoxy groups having 1 to 5 carbon atoms) and (2) at least one compound selected from the group consisting of 4,4'-di-substituted amino-benzophenones represented by the following general formula (a), p-substituted amino-benzaldehyde derivatives represented by the following general formula (b), 2-(p-substituted amino-phenyl)-1,3-dioxolanes represented by the following general formula (c), 4,4'-bis(substituted amino)-N-benzylideneanilines represented by the following general formula (d) and 2-[4-(substituted amino)cinnamoyl]naphthalenes represented by the following general formula (e): ##STR1## where R and R', which may be the same or different, each represents a methyl group or an ethyl group, and R.sup.0 represents a hydrogen atom, a hydroxy group, a --CR.sup.1 R.sup.2 R.sup.3 group, where R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, each represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, or an --OR.sup.4 group, where R.sup.4 represents an alkyl group having 1 to 5 carbon atoms.

A photopolymerizable composition comprising, as essential components, (A) at least one compound having one or more addition polymerizable ethylenically unsaturated double bonds and (B) a photopolymerization initiator composition comprising (i) a combination of at least one compound (a) and at least one compound (b), (ii) a combination of at least one compound (a) and at least one compound (c) or (iii) a combination of at least one compound (a), at least one compound (b) and at least one compound (c);

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Asaka, Japan

Syunichi Kondoh