The Lubrizol Corporation

Syed Q Rizvi

Carmen V Luciani

Stephen A Di Biase

Richard E Gapinski

Joseph L Kostusyk

Richard M Lange

Frederick W Koch

Joseph W Pialet

James N Vinci

Bernard C Roell, Jr

Sean S Bigelow

Jeffrey F Munson

Disclosed is a metal working composition comprising a major amount of water and a minor amount of an additive comprising

Polyethoxylated alcohol-based phosphonates for metal working lubricants

This is invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, (A) an hydrocarbyl phosphite, wherein each hydrocarbyl group is saturated and independently contains from about 12 to about 24 carbon atoms, (B) an organic polysulfide, and (C) (i) a borated overbased metal salt of an acidic organic compound, (ii) a combination of a borated dispersant and a phosphorus antiwear or extreme pressure agent selected from the group consisting of a phosphoric acid ester or salt thereof, a lower alkyl phosphite, and a phosphorus-containing carboxylic acid, ester, ether, or amide, or (iii) a mixture of (i) and (ii). These compositions provide improved frictional properties to lubricating composition while maintaining the extreme pressure protection of the lubricant. The lubricating compositions have good thermal stability.

Lubricating compositions with improved thermal stability and limited

This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (A) a minor amount of at least one hydroxyalkyl dithiocarbamate or at least one borate thereof, wherein the dithiocarbamate is derived from an amine other than an alkyl or alkenylsuccinimide. In another aspect the invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, a hydroxyalkyl dithiocarbamate or a borate thereof, and (B) at least one sulfur compound or (C) at least one phosphorus or boron antiwear or extreme pressure agent. The invention also relates to greases, functional fluids and aqueous fluids containing the hydroxyalkyl dithiocarbamates and borates thereof. The lubricants and fluids have improved antiwear and extreme pressure properties including providing improved antiscuff protection.

Hydroxyalkyl dithiocarbamates, their borated esters and lubricants,

This invention relates to improved grease compositions comprising a major amount of an oil based simple metal soap thickened base grease and a minor amount of at least one phosphorus and boron containing composition, said phosphorus and boron containing composition prepared by reacting a combination of (A) at least one boron compound and (B) at least one phospholipid. In one embodiment, the phosphorus and boron containing composition is present in amounts sufficient to improve the extreme pressure, antiwear and lubricity properties of the base grease. In another embodiment the phosphorus and boron containing composition is present in amounts sufficient to increase the dropping point of the base grease, as determined by ASTM procedure D-2265, by at least 20.degree. C.

Grease compositions

This invention relates to a composition prepared by reacting (A) a boron compound and (B) a phospholipid. These phospholipids are useful as lubricant additives for oil-base and water-base functional fluids. These materials act as anti-wear and/or extreme pressure agents. Further, these materials when incorporated into aqueous compositions have beneficial bacteriostatic effects, i.e., controlling bacterial growth.

Reaction products of a boron compound and a phospholipid, and lubricant

This invention relates to a composition comprising (A) a major amount of an oil of lubricating viscosity and (B) a minor amount of (i) a reaction product of (a) at least one dimercaptothiadiazole, and (b) at least one alpha, beta-unsaturated ester prepared by reacting an alpha, beta-unsaturated carboxylic acylating agent with a hydroxy compound, or (ii) a salt of the reaction product, provided that when the acylating agent is a monocarboxylic acylating agent then the hydroxy compound is a monohydroxy compound, and provided that when the ester is formed from a maleic acylating agent, then the ester is formed from a sulfur-containing hydroxy compound or a combination of a polyhydroxy compound and a monohydroxy. The invention also relates to aqueous fluids, greases, and concentrate compositions containing the reaction products and its salts. These additives generally show an ability to improve antiwear (including extreme pressure) and antioxidation properties of lubricants, aqueous fluids, and greases.

Lubricants, greases, aqueous fluids and concentrates containing

This invention relates to lubricating compositions containing hydroxyalkane phosphonic acids and derivatives thereof. More specifically, this invention relates to hydroxylakane phosphonic acids which can be reacted to form salts with basic materials, including overbased detergents, dispersants and amines. These materials can be particularly useful in lubricating compositions. The hydroxyalkane phosphonic acid is represented by the following formula: ##STR1## wherein X is oxygen, sulfur or a secondary amino group, n is an integer from 1 to 8, Y is hydrogen or a phosphonic acid group and R is an alkyl group having from 1 to about 100 carbon atoms.

Hydroxyalkane phosphonic acids and derivatives thereof and lubricants

This invention relates to lubricating compositions containing hydroxyalkane phosphonic acids and derivatives thereof. Hydroxyalkane phosponic acids in the present invention can be reacted to form salts with basic materials, including detergents, dispersants and amines. These materials can be particularly useful in lubricating compositions to improve anti-wear and extreme pressure properties of lubricating formulations. The hydroxyalkane phosphonic acid is represented by the following formula: ##STR1## wherein Y is a phosphonic acid group or hydrogen, and R is alkyl from 1 to about 100 carbon atoms.

Lubricants containing salts of hydroxyalkane phosphonic acids

Compositions useful as pour point depressants, novel compounds within such compositions, and processes for making same, as well as lubricant oil compositions containing same, are disclosed. The novel compounds are encompassed by the general structural formula (I)

Methylene linked aromatic pour point depressant

A lubricating composition is disclosed. The composition comprises

Low molecular weight viscosity modifying compositions

Compositions useful as pour point depressants, novel compounds within such compositions, and processes for making same, as well as lubricant oil compositions containing same, are disclosed. The novel compounds are encompassed by the general structural formula (I) ##STR1## wherein the Ar, Ar' and Ar' are independently an aromatic moiety containing 1 to 3 aromatic rings and each aromatic moiety is substituted with 0 to 3 substituents, (R) and (R') are independently an alkylene group containing about 1 to 100 carbon atoms with the proviso that at least one of (R) or (R') is CH.sub.2, and n is 0 to about 1000; with the proviso that if n is 0, then (R) is CH.sub.2 and each aromatic moiety is independently substituted with 0 to 3 substituents with one aromatic moiety having at least one substituent, the substituents being selected from the group consisting of a substituent derived from an olefin and a substituent derived from a chlorinated hydrocarbon. The composition of the invention includes compounds varying in molecular weight from about 271 to about 300,000.

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Painesville, OH, United States of America

Syed Q Rizvi