Dentsply Sirona Inc.

Dentsply International Inc.

Dentsply Detrey G.m.b.h.

Dentsply Detry Gmbh

Sven Pohle

Joachim E Klee

Helmut Ritter

Oliver Elsner

Andreas Facher

Christoph P Fik

Huaibing Liu

Dominika Bernert

Julia Gansel

Maximilliam Maier

Mareike Bardts

Christoph Weber

Florian Szillat

Maximilian Maier

Markus Evers

Stefan Brugger

Magnus Schmidt

Markus Ringwald

Marina Barudzija

Tillmann Weber

Christoph Fik

Marina Stojiljkovic

Ernst Andreas Grutzner

Alexandra Eberhardt

Nicole Matt

Ernst Andreas GRÜTZNER

The present invention relates to a dental composition comprising wherein X, Y, Y', Z, L, R, Rand Rare as defined in claimand

Dental composition

The present invention relates to an aqueous dental composition having a pH of at most 7. Furthermore, the present invention relates to the use of a specific composition for the preparation of an aqueous dental composition.

Dental adhesive

Disclosed is a resin modified dental luting cement composition having a polymerizable resin component, a polyacidic polymer component, a filler component, a redox initiator system, and water.

The present invention relates to an aqueous dental composition having a pH of less than 7 as well as to the use of a stabilizer for the preparation of an aqueous dental composition having a pH of less than 7. In particular, the present invention relates to an aqueous dental composition having a pH of less than 7 comprising (i) one or more polymerizable compounds having at least one polymerizable double bond; (ii) a polymerization initiator system containing a) an 1,2-diketone photoinitiator compound having a light absorption maximum in the range from 300 to 500 nm; and b) a coinitiator compound; (iii) a stabilizer of the following formula (I) and/or (II), wherein the Rs, which may be the same or different, independently represent a branched Calkyl or alkenyl group, or a Ccycloalkyl or cycloalkenyl group, R' represents a hydrogen atom, a Calkyl or Calkenyl group, or a Cfluoroalkyl or Cfluoroalkenyl group, X represents a group selected from a Calkyl group or a Ccycloalkyl group, and n is 0, 1 or 2; and a solvent mixture comprising an organic solvent and at least 1 percent by weight of water based on the total weight of the aqueous dental composition. 

A process for producing a water-soluble, hydrolysis-stable, polymerizable polymer, comprising a) a step of copolymerizing a mixture comprising (i) a first copolymerizable monomer comprising at least one optionally protected carboxylic acid group and a first polymerizable organic moiety, and (ii) a second copolymerizable monomer comprising one or more optionally protected primary and/or secondary amino groups and a second polymerizable organic moiety, for obtaining an amino group containing copolymer; b) a step of coupling to the amino group containing copolymer a compound having a polymerizable moiety and a functional group reactive with an amino group of repeating units derived from the second copolymerizable monomer in the amino group containing copolymer obtained in the first step wherein the optionally protected amino group is deprotected, so that polymerizable pendant groups are linked to the backbone by hydrolysis-stable linking groups, and, optionally, a step of deprotecting the protected carboxylic acid group after step (a) or step (b), for obtaining a polymerizable polymer.

Polymer for a glass ionomer cement

A dental cement hardened by a cement reaction involving the specific polymerizable polyacidic polymer and optionally additional crosslinkable groups, has reduced shrinkage and improved mechanical properties, in particular with regard to flexural strength and fracture toughness. Moreover, the specific polymerizable polyacidic polymer of the present invention contains a high number of acidic groups which is not reduced by the presence of polymerizable moieties, whereby water solubility of the uncured polymer is not impaired by the presence of the polymerizable moieties.

An aqueous dental glass ionomer composition comprising (a) a reactive particulate glass, (b) a linear or branched polymer comprising acidic groups, which is reactive with the particulate glass in a cement reaction, whereby the linear or branched polymer comprising acidic groups has a polymer backbone and optionally pendant groups, (c) optionally dispersed nanoparticles comprising grafted linear or branched polymer chains comprising acidic groups, and having a polymer backbone characterized in that a polymer backbone of the linear or branched polymer of component (b) and/or, if present, the grafted linear or branched polymer chains of component (c) are obtainable a process comprising (i) cyclopolymerizing or cyclocopolymerizing one or more compounds of the following formula (I): 

An aqueous dental glass ionomer composition comprising (a) a reactive particulate glass, (b) a linear or branched polymer comprising acidic groups, which is reactive with the particulate glass in a cement reaction, whereby the linear or branched polymer comprising acidic groups has a polymer backbone and optionally pendant groups, (c) optionally dispersed nanoparticles comprising grafted linear or branched polymer chains comprising acidic groups, and having a polymer backbone characterized in that a polymer backbone of the linear or branched polymer of component (b) and/or, if present, the grafted Sinear or branched polymer chains of component (c) are obtainable a process comprising (i) cyclopolymerizing or cyclocopolymerizing one or more compounds of the following formula (I). 

An aqueous dental glass ionomer composition comprising (a) a reactive particulate glass, and (b) a linear or branched polymer comprising acidic groups, which is reactive with the particulate glass in a cement reaction, whereby the linear or branched polymer comprising acidic groups has a polymer backbone and optionally pendant side chains, (c) optionally dispersed nanoparticles, and (d) optionally a low molecular compound, characterized in that the glass ionomer composition comprises&#x2014;S.sub.xH groups, wherein x is an integer of from 1 to 6, which crosslink the particulate glass and/or the linear polycarboxylic acid and/or the optional dispersed nanoparticles and/or the optional low molecular compound.

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Constance, Germany

Sven Pohle