Arcadis Geraghty-miller, Inc.

Geraghty & Miller, Inc.

Arcadis G & M Inc.

Case Logic, Inc.

Arcadis Corporate Services, Inc.

Suthan S Suthersan

David K Vance

Gary Keyes

Kent O'Brien

Peter Palmer

Boris Dynkin

John F Horst

Jeff B Gillow

Richard Cushing

The invention relates to a system and method for the substantially permanent biogeochemical stabilization of solids impacted with hexavalent chromium/Cr(VI), including chromite ore processing residue ('COPR'). The invention comprises a novel treatment method of adding amendment(s) to COPR or other chromate impacted solids for the purpose of (1) weathering COPR minerals (when present) to convert the minerals that control alkalinity of the COPR to non-alkaline forms and liberate incorporated hexavalent chromium (Cr(VI)) in the process; (2) providing a chemical reductant (ferrous iron) to rapidly and permanently reduce the available Cr(VI) to trivalent form (Cr(III)); and/or (3) supporting longer-term biogeochemical Cr(VI) reduction enhanced by recycling of the chemical reductant, ultimately rendering the material non-hazardous as measured by acceptable methods. Amendments include but are not limited to acids; sources of ferrous iron; fermentable organic carbon source(s); and/or a source of active anaerobic microbes.

Method for biogeochemical stabilization of chromate-impacted solids

Methods of treating ground water and methods for reducing contaminants (e.g., chlorinated compounds in contaminated ground water) to harmless compounds in the presence of an elemental metal treatment composition. Said methods comprise injecting a treatment solution comprising a colloidal suspension of elemental metal particles (e.g., iron, a tin, a zinc, a palladium and mixtures thereof) having a nanoscale particle size and a carbohydrate in an organic liquid (e.g., dodecane, butyl acetate and polypropylene glycol ethyl ether acetate and mixtures thereof) into the ground, proximate to the contaminated ground water.

Method of making and using nanoscale metal

When elemental iron is in the presence of chlorinated compounds (contaminants) a naturally occurring reaction takes place and the chlorinated compounds are reduced and form harmless compounds. The production of extremely small metal particles containing elemental iron or a mixture of elemental iron and a second metal is imperative to this method of treating contaminants and is the subject of the present invention. When the particle is made small enough a surfactant is not required for the particle to do its job. The elemental metal may be kept in an elemental state by keeping it in an oxygen-scavenging environment. This is achieved by either suspending the nanoscale metal in a carbohydrate solution or by injecting a carbohydrate solution in atomized form into the gas used to inject the metal into the subsurface soil. Additionally, the present invention is to a method of using elemental metal to reductively dehalogenate halogenated hydrocarbons, to reduce soluble metals and to treat metalloids in subsurface soil.

Engineered in situ anaerobic reactive zones

An in situ method and system for reductive dechlorination, the precipitation of chromium, the precipitation of heavy metals, and microbial denitrification. The invention comprises the formation of in situ anaerobic reactive zones to precipitate and filter out dissolved heavy metals as metallic sulfides, to degrade nitrate to nitrogen gas, to reduce chlorinated hydrocarbons to ethene, and to precipitate and filter out chromium. The invention is comprised of an injection well or wells that extend into a contaminated groundwater. A conduit located within the injection well conveys carbohydrates and sulfates to the contaminated groundwater. Microbes digest the carbohydrates to produce sulfate reducing and methanogenic conditions within the reactive zone that include a dissolved oxygen level less than about 0.5 mg/l, a redox potential less than about &minus;250 mv, and a dissolved organic carbon to contaminant ratio of greater than about 50:1. These biogeochemical conditions lead to the reduction of PCE to TCE to DCE to VC and eventually to ethene. These biogeochemical conditions also lead to the precipitation of heavy metals, the precipitation of chromium, and microbial denitrification.

A method and system for removing contaminants for the phreatic zone, also known as the saturation zone, or groundwater. The technique involves gas sparging and oxidation while increasing the surface area for mass transfer by the placing of packing balls into the eductor tube. The system is comprised of a means for supplying gas/ozone mixture to the lower extent of a well which induces a flow of groundwater and gas bubbles up the well. The system contains a conduit within the well, which extends below the water table The conduit has a lower fluid-permeable section which is located below the water table and an upper fluid-permeable section which is adjacent the water table.

In-well air stripping, oxidation, and adsorption

A method and system are described for removing contaminants from the phreatic zone, also known as the saturation zone, or groundwater. A barrier wall is constructed below the ground surface and in the path of flow of a contaminated groundwater plume. A well is constructed in advance of the barrier wall and is connected to the barrier wall via a pipe. Various remediation media may be lowered into the well to perform remediation on the contaminated groundwater before it passes through the barrier wall.

In situ reactive gate

A method and system for removing contaminants from the phreatic zone, also known as the saturation zone, or groundwater. The technique preferably involves gas sparging while slowing down the sparging process by placing packing balls into an eductor tube. A preferred embodiment of the system is comprised of a means for supplying gas to the lower extent of a well which induces a flow of groundwater and gas bubbles up the well. The system may also contain a conduit within the well which extends below the water table. The conduit has a lower fluid-permeable section which is located below the water table and an upper fluid-permeable section which is adjacent to the water table. The system may further comprise an eductor tube contained in the conduit which extends from the top extent of the conduit to the saturation zone. Packing balls may be located between the eductor tube and the means for supplying gas to the lower extent of the well. The system may also include separating the gas bubbles from the groundwater at the top of the conduit.

In-well air stripping and adsorption

A system for removing contaminants from the phreatic zone, also known as the saturation zone, or groundwater. The technique preferably involves gas sparging while slowing down the sparging process by placing packing balls into the eductor tube. A preferred embodiment of the system is comprised of a means for supplying gas to the lower extent of a well which induces a flow of groundwater and gas bubbles up the well. The system may also contain a conduit within the well which extends below the water table The conduit has a lower fluid-permeable section which is located below the water table and an upper fluid-permeable section which is adjacent to the water table the system may further comprise an eductor tube contained in the conduit which extends from the top extent of the conduit to the saturation zone. Packing balls may be located between the eductor tube and the means for supplying gas to the lower extends of the well. The present invention may also contain a means located at the top of the conduit for separating the gas bubbles from the groundwater.

In-well air stripping and gas adsorption

An in situ method and system for reductive dechlorination, the precipitation of chromium, the precipitation of heavy metals, and microbial denitrification. The invention comprises the formation of in situ anaerobic reactive zones to precipitate and filter out dissolved heavy metals as metallic sulfides, to degrade nitrate to nitrogen gas, to reduce chlorinated hydrocarbons to ethene, and to precipitate and filter out chromium. The invention is comprised of an injection well or wells that extend into a contaminated saturated zone. A conduit located within the injection well conveys carbohydrates and sulfates to the contaminated saturated zone. Microbes digest the carbohydrates to produce sulfate reducing and methanogenic conditions within the reactive zone that include a dissolved oxygen level less than about 0.5 mg/l, a redox potential less than about -250 mv, and a dissolved organic carbon to contaminant ratio of greater than about 50:1. These biogeochemical conditions lead to the reduction of PCE to TCE to DCE to VC and eventually to ethene. These biogeochemical conditions also lead to the precipitation of heavy metals, the precipitation of chromium, and microbial denitrification.

In situ reactive gate for groundwater remediation

A method and system for removing contaminants for the phreatic zone, also known as the saturation zone, or groundwater. The technique involves gas sparging and oxidation while increasing the surface area for mass transfer by the placing of packing balls into the eductor tube. The system is comprised of a means for supplying gas/ozone mixture to the lower extent of a well which induces a flow of groundwater and gas bubbles up the well. The system contains a conduit within the well, which extends below the water table. The conduit has a lower fluid-permeable section which is located below the water table and an upper fluid-permeable section which is adjacent the water table.

A method and apparatus for removing volatile contaminants from the phreatic zone of contaminated ground. The apparatus is a system comprised of at least one air injection well and at least two pressure relief wells arranged in a line. Air is injected into the contaminated ground water to allow sparging of the volatile contaminants from a linear region between injection and relief wells. The volatile contaminants are captured by the injected air and carried to the extraction line for removal and treatment.

Method and system to achieve two dimensional air sparging

A method and apparatus for removing volatile contaminants from the phreatic zone of a contaminated region in the ground. The apparatus is a system comprised of a trench cut into the phreatic zone of contaminated ground containing fluid-permeable fill material, an air injection line submerged in the lower portion of the trench and an air/contaminant gas extraction line in the trench above the water table. Air is injected into the contaminated ground water to allow sparging of the volatile contaminants. The volatile contaminants are captured by the injected air and carded to the extraction line for removal and/or treatment.

Growing community of inventors

Yardley, PA, United States of America

Suthan S Suthersan