Matsushita Electric Industrial Co., Ltd.

Research Development Corporation of Japan

Tokyo Shibaura Denki Kabushiki Kaisha

Takomoto Oil & Fat Co., Ltd.

Susumu Yoshimura

Mutsuaki Murakami

Sohji Tsuchiya

Yasuo Kudoh

Toshikuni Kojima

Kazuhiro Watanabe

Akio Yamashita

Naomi Nishiki

Masao Fukuyama

Kenji Kuranuki

Isamu Iwai

Katsuyuki Nakamura

Soji Tsuchiya

Junji Ozaki

Masahito Yasuda

Shohzoh Takahashi

Hirohiko Itoh

Yasunari Hoshii

Midori Shinoda

Shozo Takahashi

Functional devices using charge transfer complexes formed as a layer on a substrate. In one embodiment of the invention, the device comprises a substrate, an electrode layer formed on one side of the substrate, at least one layer of a charge transfer complex capable of undergoing a variation in charge transferability by application of external energy, and another electrode layer formed on the complex layer. The charge transfer complex consists essentially of an electron donor and an electron acceptor, at least one of which is an organic compound having a long-chain alkyl substituent. In another embodiment, a charge transfer complex layer is provided on a substrate as polarized in one direction, in which the charge transfer complex does not necessarily contain such a substituted donor or acceptor compound as in the first embodiment but ordinary charge transfer complexes may be used. A pair of electrodes may be provided to sandwich the complex layer therebetween.

Functional devices comprising a charge transfer complex layer

An electroacoustic diaphragm is provided, which diaphragm comprising a pyrolytic graphite film obtained from a polymer selected from polyoxadiazole, an aromatic polyimide obtained by polycondensation or pyromellitic acid and an aromatic diamine, polybenzthiazole, polybenzbisthiazole, polybenzoxazole, polybenzbisoxazole, poly(pyromellitimide), poly(m-phenyleneisophthalamide). poly(m-phenylenebenzoimidazole), poly(m-phenylenebenzobisimidazole), polythiazole and poly-p-phenylenevinylene. The graphite film has a discontinuous layer of a polymeric material formed on and in the film whereby not only good electroacoustic characteristics, but also good mechanical strength and good adhesion of an adhesive applied thereof are obtained. A method for fabricating such diaphragm is also described.

Electroacoustic diaphragm and method for making same

An electroacoustic diaphragm is provided, which diaphragm comprising a pyrolytic graphite film obtained from a polymer selected from polyoxadiazole, an aromatic polyimide obtained by polycondensation of pyromellitic acid and an aromatic diamine, polybenzthiazole, polybenzbisthiazole, polybenzoxazole, polybenzbisoxazole, poly(pyromellitimide), poly(m-phenyleneisophthalamide), poly(m-phenylenebenzoimidazole), poly(m-phenylenebenzobisimidazole), polythiazole and poly(m-phenylenevinylene. The graphite film has a discontinuous layer of a polymeric material formed on and in the film whereby not only good electroacoustic characteristics, but also good mechanical strength and good adhesion of an adhesive applied thereof are obtained. A method for fabricating such diaphragm is also described.

Method for fabricating a graphite film for use as an electroacoustic

Optical elements for radiation comprising a graphite film obtained from a film of a polymer such as polyphenylene oxadiazole, polybenzothiazole, polybenzobisthiazole, polybenzooxazole, polybenzobisoxazole, polypyromellitimide, polyphenylene isophthalamide, polyphenylene benzoimidazole, polyphenylene benzobisimidazole, polythiazole or poly-p-phenylene-vinylene. The graphite film is obtained by pyrolysis of the polymer film at 2800.degree. C. or higher at a pressure of not lower than 4 kg/cm.sup.2 in vacuum or in an inert gas. Alternatively, the element may be made of a graphite film obtained from the polymers mentioned above and intercalated with a metal halide. The intercalated films are readily bonded by pressing in the form of a thick sheet or block. Still alternatively, the graphite films and the intercalated films may be superposed alternately and bonded by pressing, or the intercalated films may be sandwiched between the graphite films and bonded together to form a thick sheet or block. The optical element has application as a lens, monochromater, filter or analyzer for radiations.

Optical elements for radiation comprising graphite films

A photosensitive material for electrophotography which comprises an electrically conductive support of a desired shape and an organic photoconductive layer formed on the substrate, is provided. The organic photoconductive layer is formed from a solution of an organic charge-generating compound, an organic charge transfer compound and an organic resin in an organic solvent after low temperature treatment thereof wherein the solution is cooled to a temperature sufficient not to cause the solutes to be precipitated or the solution to be coagulated for a time enough to allow interaction between the compounds and the resin binder and is returned to room temperature. This solution is applied to the support and dried to form a photoconductive layer on the support. The photoconductive layer may be of a single-layer structure or a double-layered structure wherein at least one sub-layer should be formed from a solution subjected to the low temperature treatment. A process for making the photosensitive material is also described.

Photosensitive material for electrophotography and method for making same

Graphite blocks are produced by a process wherein one or plural polymer films having a thickness of from 1 to 400 .mu.m and selected from aromatic polyimides, aromatic polyamides and polyoxadiazoles are heat treated to obtain carbonaceous films. A plurality of the carbonaceous films are hot pressure under certain conditions to obtain thick graphite blocks. The blocks have a remarkably improved rocking characteristic and are useful as radiation optical elements such as X-ray or neutron ray monochromators or filters. The blocks may be curved to obtain bent-type graphite articles.

Process for producing graphite blocks

A solid electrolytic capacitor comprising:

Solid electrolytic capacitor and method of manufacturing the same

A method for making a graphite sheet or block with a desired thickness which comprises hot pressing at least two films of a polymer selected from a polyoxadiazole, an aromatic polyamide and an aromatic polyimide at a pressure not lower than 4 kg/cm.sup.2 at temperatures not lower than 2200.degree. C. Prior to the hot pressing, the at least two films may be thermally treated at temperatures of not lower than 2200.degree. C. and subsequently hot pressed at a pressure of not lower than 4 kg/cm.sup.2 at a temperature of not lower than 2000.degree. C. when the at least two films are made of the polyoxadiazole or aromatic polyamide or at a temperature of not lower than 1600.degree. C. when the at least two films are made of the aromatic polyimide.

Method for making a graphite film or sheet

A solid electrolytic capacitor comprising a capacitor element which includes a valve metal member capable of forming a dielectric oxide film thereon, a dielectric oxide film formed on the valve metal member, a manganese oxide layer formed on the dielectric oxide film, a conductive polymer film formed on the manganese oxide film by electrolytic polymerization, and terminals formed on the valve metal member and the conductive polymer film, respectively. The solid electrolytic capacitor is improved in capacitor characteristics. A method for manufacturing the solid electrolyte is also described wherein the conductive polymer film is readily formed on the manganese dioxide layer.

Solid electrolytic capacitor and method for manufacturing the same

A solid electrolytic capacitor uses a solid electrolyte wherein manganese dioxide is uniformly diffused in a polymer made by electrochemical polymerization, and the solid electrolyte is disposed between a first electrode made of valve metal and having an anodic oxide film thereon and a second electrode opposite to the first electrode. The solid electrolytic capacitor shows splendid high frequency characteristics and small leakage current.

Solid electrolyte capacitor

The present invention provides a solid electrolytic capacitor which comprises a first electrode comprising a valve action metal plate one surface of which is covered by an anodic oxidation film, a second electrode which faces the surface of the first electrode having the anodic oxidation film and a layer of a solid electrolyte which is placed between the first and second electrodes and comprises a salt of 7,7,8,8-tetracyanoquinodimethane with a cation of quinoline or isoquinoline the nitrogen atom of which is quarternarized with fluorinated alkyl groups, which has improved reliability at high temperature and increased capacitance, and decreases the formation of poisonous gas during pyrolysis.

Solid electrolytic capacitor

Diffraction elements for penetrating radiation, such as X-rays and neutrons, are prepared by coating a film of poly-(phenyleneoxadiazole) onto a substrate and graphitizing the poly-(phenyleneoxadiazole) to form a flexible graphite monocrystal on the substrate.

Radiation optical element

A data processing apparatus permitting editing of document blocks associated with voice block data, wherein various document blocks, stored in a memory section, are read out and displayed on a display. A desired document block is designated by a cursor, and the corresponding voice data is input, thereby associating the desired document block with the corresponding voice block data which is stored in another memory section. Input sentences are divided into document blocks, to be edited and displayed. Even if the document block displayed is moved during editing, the voice data corresponding to the moved document block can be output, by operating a voice output key.

Apparatus for processing document data including voice data

This invention relates to a graphite intercalation compound in the form of a film, which is obtained by intercalating a donor type, an acceptor type or a covalent type material between the layers of graphite film obtained by thermal treatment of poly(phenylene oxadiazole). The obtained intercalated graphite film has a large scale area and has an extremely improved stability compared with known graphite intercalation compounds.

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Yokohama, Japan

Susumu Yoshimura