Hitachi Software Engineering Company, Ltd.

Susumu Kuwabata

Keiichi Sato

Tsukasa Torimoto

The present invention measures defect fluorescence exhibited from a defect level mainly on a semiconductor nanoparticle surface site which has an energy level existing inside the forbidden band of energy levels inside the semiconductor nanoparticle.

Semiconductor nanoparticle fluorescent reagent and fluorescence determination method

A reaction in which a surface-treating material for providing a semiconductor nanoparticle with one or more kinds of electron-releasing groups is added and in which the electron-releasing groups are arranged on the surface of the semiconductor nanoparticle is accelerated by irradiating the semiconductor nanoparticle with light during surface modification, thereby reducing the reaction time.

Method of manufacturing a semiconductor nanoparticle

This invention provides a method for converting materials for stabilizing surfaces of semiconductor nanoparticles. In this method, surfaces of semiconductor nanoparticles are first modified and then dissolved by photoetching in the presence of materials for stabilization to obtain nanoparticles that are stabilized in an aqueous solution.

Method for converting and purifying materials for modifying surfaces of semiconductor nanoparticles

The invention provides a semiconductor nanoparticle comprising a semiconductor nanoparticle core on the surface of which electron-releasing groups are arranged, the semiconductor nanoparticle having a fluorescent property and water-solubility. The invention also provides a water-soluble semiconductor nanoparticle with an excellent fluorescent property that can be easily prepared by adding a surface-treating material for providing a semiconductor nanoparticle with one or more kinds of electron-releasing groups, and arranging the electron-releasing groups on the surface of the semiconductor nanoparticle core.

Semiconductor nanoparticle, and a process of manufacturing the same

Disclosed is a semiconductor nanoparticle having excellent chemical durability and high luminescence properties. The chemical durability of the particle is provided by coating the semiconductor nanoparticle having high luminescence properties dispersed in an organic solvent using a surface-active agent, an amphipathic molecule, and a lipid composed of a combination of two or more layers selected from a polar group, a hydrophobic group, a hydrophilic group, and a functional group (herein, the hydrophobic group is a necessary element and the hydrophilic group and the functional group are optional).

Semiconductor nanoparticle having high luminescence properties comprising an electron-donor group and a multilayered coating comprising a hydrophobic group

Monodisperse nanoparticles are prepared with a high degree of reproducibility by controlling pH in size-selective photoetching. The nanoparticles have uniform optical properties and other properties.

Monodisperse nanoparticles produced by size-selective photoetching reaction

The resistance of a semiconductor nanoparticle provided with a surface treatment, such as an OH coating or ammonia treatment, against external factors is improved. A semiconductor nanoparticle provided with a surface treatment such as an OH coating or ammonia treatment and having high-emission properties is coated with an organic material, such as hexylamine, dodecylamine, trioctylmethylammonium, tridodecilmethylammonium, and similar organic material, by migrating the semiconductor nanoparticle from an aqueous phase to an organic solvent, such as hexane or toluene, thereby providing it with durability against external factors.

Organic material-coated semiconductor nanoparticle with excellent durability, and method of manufacturing the same

This invention provides a method for producing semiconductor nanoparticles having a monodispersed distribution of particle sizes and the semiconductor nanoparticles produced by the same, which were insufficient in conventional reversed micelle methods. This method for producing semiconductor nanoparticles comprises steps of: forming semiconductor nanoparticles in the reaction field in the micelle or in the reversed micelle; and regulating the particle size of the semiconductor nanoparticles by size-selective photoetching, wherein the reaction field in the micelle or in the reversed micelle serves also as the dissolution field for ions that are produced when the semiconductor nanoparticles are subjected to size-selective photoetching. In this method, particle sizes of the semiconductor nanoparticles are regulated by adjusting the size of the dissolution field for ions and regulating the reactivity of size-selective photoetching.

Method for producing semiconductor nanoparticles and semiconductor nanoparticles produced by the same

This invention provides semiconductor nanoparticles having fluorescence properties and comprising a modifying group represented by the following general formula bound to their surfaces, a method for producing the same, and a fluorescence reagent comprising semiconductor nanoparticles:&#x2014;OYwherein Y is selected from a hydrogen atom, a metal atom, a semimetal atom, an organic group, or an organic group that is intermediated by a metal atom or a semimetal atom. In this method, the surfaces of the semiconductor nanoparticles were modified with a hydroxyl group or the like for stabilization. This realizes the production of semiconductor nanoparticles having fluorescence properties that significantly emit only the band gap fluorescence, the production of which at the industrial level was previously very difficult due to the necessity of many processes and from the viewpoint of technology and safety.

Semiconductor nanoparticles, method for producing the same, and fluorescence reagent comprising semiconductor nanoparticles

Multi-layered semiconductor nanoparticles having a very narrow grain-size distribution and exhibiting a spectrum having a narrow wavelength-width peak are prepared by a manufacturing method combining a monodisperse semiconductor nanoparticle manufacturing method and a multi-layer semiconductor nanoparticle preparation method. The nature of a solution of monodisperse semiconductor nanoparticles that is stabilized by a surface stabilizer is transformed between hydrophilic and lipophilic by substituting the surface stabilizer. The stabilized semiconductor nanoparticles are then shifted between an aqueous layer and an organic layer. The semiconductor nanoparticles are coated with multiple layers in the organic layer, and the organic layer is drawn off to recover the semiconductor nanoparticles therefrom.

Growing community of inventors

Osaka, Japan

Susumu Kuwabata