Mitsubishi Paper Mills Limited

Susumu Baba

Akio Yoshida

Yasuo Tsubai

Katsuaki Iwaosa

Tatsuhito Taniguchi

Hiroaki Nagamatsu

Akira Tanaka

Yoshikazu Takaya

Seigo Ebato

Hiroshi Nishinoiri

Kunihiro Nakagawa

Kazuhiko Sunada

Hideto Kiyama

Tamotu Iwata

Masao Okushima

Motoshige Yamada

Yoshiya Takahashi

Yukinao Kawamata

Tokitsugu Houjo

Eigi Matsubara

Disclosed is a method for developing silver halide photographic photosensitive materials with a developer containing a sulfite wherein said developer contains 20 mol % or more of potassium ion based on the total alkali metal ions, 0.04 mol/l or more of bromine ion or a compound represented by the following formula (I): ##STR1## wherein R.sub.1 represents a hydroxyalkyl group having 2-10 carbon atoms and R.sub.2 and R.sub.3 each represent a hydrogen atom, an alkyl group having 1-10 carbon atoms or a hydroxyalkyl group having 2-10 carbon atoms and the developer is filtered by a filter containing physical development nuclei before, during or after development of the photosensitive materials with the developer. The method is especially effective in processing using an automatic processor. According to the present method, formation of silver sludges is effectively inhibited and thus, stain of roll and belt of the processors can be prevented. According to the present method, formation of silver sludges is effectively inhibited and thus, stain of roll and belt of the processors can be prevented.

Method for photographic development using a filter to inhibit occurrence

The present invention provides an image receiving material used for silver complex diffusion transfer process in combination with a photosensitive material. This image receiving material comprises a support and, provided thereon at least an image receiving layer containing physical development nuclei and an uppermost layer containing substantially no physical development nuclei, wherein the uppermost layer contains at least 0.8 g/m.sup.2 of hydrophilic colloid in terms of solid content and ratio of solid content of hydrophilic colloid in the uppermost layer to solid content of hydrophilic colloid in the image receiving layer is more than 1.0. Preferably, the image receiving layer contains substantially no hardener and the uppermost layer contains a hardener.

Image receiving material for silver complex diffusion transfer with

Provided is an image receiving material for silver complex diffusion transfer process which comprises a support, an image receiving layer provided on the support and an upper layer provided on the image receiving layer wherein physical development nuclei are distributed densely in the vicinity of the surface of the support and gradually diminishing towards the upper layer and a color toning agent is contained densely in the upper layer and gradually diminishing towards the surface of the support and the physical development nuclei and the color toning agent are thus mutually distributed. The image receiving material is produced by coating on a support a hydrophilic colloid coating solution for image receiving layer which contains physical development nuclei and contains substantially no color toning agent and thereon at least one hydrophilic colloid coating solution which contains at least one color toning agent and contains substantially no physical development nuclei. The physical development nuclei are preferably prepared by reducing or sulfurizing a heavy metal ion in a solution containing low molecular weight gelatin as defined in the specification.

Image receiving material for silver complex diffusion transfer process

The present invention provides a method for producing a photosensitive material for silver complex diffusion transfer process containing a hydroxybenzene developing agent which comprises coating at least one gelatin-containing coating solution on a support to form photographic layers including a photosensitive layer and drying the coat, said drying being carried out by raising surface wet-bulb temperature of the coat to 14.degree. C. or higher before gelatin concentration in the coat reaches at most about 30% by weight.

Method for production of photosensitive material for diffusion transfer

Disclosed is a silver complex diffusion transfer process which comprises processing a photosensitve material comprising a support and at least a silver halide emulsion layer provided thereon and an image receiving material comprising a support and at least an image receiving layer provided thereon which are brought into close contact with each other in a developing processing solution. This process is characterized in that said image receiving layer has 1-3 g/m.sup.2 of a hydrophilic colloid at least 80% by weight of which is gelatin; total amount of hydrophilic colloid present on the emulsion layer side of the photosensitive material is 5-8 g/m.sup.2 ; when the materials are immersed in a 0.1N aqueous sodium hydroxide solution at 20.degree. C. for 1 minute, amount of absorbed solution per 1 g of hydrophilic colloid is 3.5-7 ml of the emulsion layer side of the photosensitive material and is 2-4 ml on the image receiving layer side of the image receiving material and the processing of the materials in the developing processing solution is carried out in the presence of at least one of 1-aryl or aralkyl substiuted-5-mercaptotetrazoles and at least one of 4-amino-3-unsubstituted or C.sub.1-3 alkyl substituted-5-mercapto-1,2,4-triazoles.

Silver complex diffusion transfer process

A photosensitive material for diffusion transfer process is disclosed according to which characteristic such as high maximum density, high contrast and image reproducibility can be stably obtained. This photosensitive material comprises a support and, provided thereon, a silver halide emulsion layer and a hydrophilic colloid layer and which is processed in contact with an image receiving material in a processing solution for silver complex diffusion transfer process wherein at least one of the silver halide emulsion layer and the hydrophillic colloid layer permeable to water contains a hydroxybenzene developing agent; when the layers on the emulsion layer coated side are immersed in a 0.1N aqueous sodium hydroxide solution at 20.degree. C. for 1 minute, amount of solution absorbed in the layers is 3.5-7.0 ml per 1 g of hydrophilic colloid; and the support comprises a paper coated with polyolefin resin on both sides and has a water content of 5.5%-7.5%.

A photosensitive material for diffusion transfer process is disclosed which is superior in image reproducibility and running property of when processed with a processing solution for silver complex diffusion transfer process. This photosensitive material is characterized in that total binder amount on the silver halide emulsion coated side of the photosensitive material is 6-8 g/m.sup.2 and when the silver halide emulsion coated side of the photosensitive material is immersed in a 0.1N aqueous sodium hydroxide solution at 20.degree. C. for 1 minute, amount of the solution absorbed and the total binder amount on the emulsion coated side is 3.5:1-5.5:1.

Photosensitive material for transfer process

Disclosed is a silver halide photographic light sensitive material which has a silver halide emulsion layer optically sensitized with a sensitizing dye having a maximum spectral sensitivity in the region of at least 700 nm, said emulsion layer containing at least one compound represented by the following formula (I) or at least one compound represented by the general formula (I) and at least one compound represented by the general formula (II) in combination: ##STR1## (wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, an alkenyl group, an amino group, an acylamido group or a sulfonamido group and sum of carbon atom numbers of R.sub.1 and R.sub.2 is 3 or more.); ##STR2## (wherein R.sub.3 represents an alkyl group of at least 3 carbon atoms or an aryl group).

Silver halide photographic light sensitive material

A silver halide photographic emulsion comprising as major constituent silver bromide with improved gradation, density and sensitivity and decreased fog is disclosed. This emulsion contains at least one of the compounds represented by the general formula ##STR1## wherein Z represents an aromatic radical, or of the oxidized derivatives thereof, and at least one of the compounds represented by the general formula ##STR2## wherein A represents a hydroxyl group, an amino group, ##STR3## R.sub.1 and R.sub.2 form a ring jointly with the carbon atom to which R.sub.1 and R.sub.2 are attached or one of R.sub.1 and R.sub.2 represents a hydrogen atom and the other represents a hydrogen atom, an alkyl group, an aryl group, or a hydroxyl group; n is 0 or an integer of 1 to 8, and M represents a hydrogen atom or an alkali metal.

Silver halide photographic emulsion containing predominantly silver

Disclosed is a silver halide photographic emulsion supersensitized with at least two sensitizing dyes selected from those represented by the following general formula [I], [II] and [III]:

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Nagaokakyo, Japan

Susumu Baba