Woongjin Chemical Co., Ltd.

Saehan Industries Incorporation

Sung Pyo Hong

Ja-Young Koo

Jong Hwa Lee

Kwan Young Ryu

Nowon Kim

Jun Suk Kim

Jin Woo Kang

A selective membrane having a high fouling resistance. In one embodiment, the selective membrane is a composite polyamide reverse osmosis membrane in which a hydrophilic coating is applied to the polyamide layer of the membrane, the hydrophilic coating being made by covalently bonding a hydrophilic compound to residual acid chlorides of the polyamide membrane, the hydrophilic compound including (i) at least one reactive group that is adapted to covalently bond directly to the polyamide membrane, the at least one reactive group being at least one of a primary amine and a secondary amine; and (ii) at least one non-terminal hydroxyl group.

Selective membrane having a high fouling resistance

A selective membrane having a high fouling resistance. In one embodiment, the selective membrane is a composite polyamide reverse osmosis membrane in which a hydrophilic coating is applied to the polyamide layer of the membrane, the hydrophilic coating being made by covalently bonding a hydrophilic compound to residual acid chlorides of the polyamide membrane, the hydrophilic compound including (i) at least one reactive group that is adapted to covalently bond directly to the polyamide membrane, the at least one reactive group being at least one of a primary amine and a secondary amine; and (ii) at least one hydrophilic group, the at least one hydrophilic group being selected from the group consisting of a hydroxyl group, a carbonyl group, a trialkoxysilane group, an anionic group and a tertiary amino group; (iii) wherein the hydrophilic compound is devoid of a polyalkylene oxide group.

A composite polyamide reverse osmosis membrane and method of producing same. In a preferred embodiment, the membrane is made by coating a porous polysulfone support with an aqueous solution containing 2 wt % m-phenylenediamine (MPD), and 0.1 wt % di(ethylene glycol) hexyl methyl ether. Next, the excess solution is removed, and the coated support is dipped in 0.1 wt % organic solvent solution of trimesoyl chloride (TMC) in a mixture of alkanes having from 8 to 12 carbon atoms. After draining the TMC solution off, the resulting composite membrane is air dried and then rinsed in a basic aqueous solution. The resultant membrane exhibits a flux of 21.3 gfd and a salt rejection of 98.9% when used at 225 psi for an aqueous solution containing 2000 ppm of NaCl.

Composite polyamide reverse osmosis membrane and method of producing the same

A selective membrane having a high fouling resistance. In one embodiment, the selective membrane is a composite polyamide reverse osmosis membrane in which a hydrophilic coating has been applied to the polyamide layer of the membrane, the hydrophilic coating being made by (i) applying to the membrane a quantity of a polyfunctional epoxy compound, the polyfunctional epoxy compound comprising at least two epoxy groups, and (ii) then, cross-linking the polyfunctional epoxy compound in such a manner as to yield a water-insoluble polymer.

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Kyungbuk, South Korea

Sung Pyo Hong