Lg Chem, Ltd

Chungnam National Industry Collaboration Foundation

Sung Kyu Lee

Joon Ho Shin

Tae Woo Kim

Jong Ku Lee

Sung Kyun Kim

Yeon Uk Choo

Hyoung Jun

Hyun Kyu Kim

Chan Hyu Jin

Jae Hun Jeong

Sung June Hwang

Jeong Ju Moon

Joo Ho Kim

Jin Sung Park

Seok Goo Lee

Sa Eun Park

Ha Na Lee

Byung Woo Choi

Jong Suh Park

In Seop Kim

Sik Ki

Ji Hye Kim

Sang Beom Lee

Sung Ho Lee

Si Nae Lee

Yun Gon Heo

Song Hoon Lee

Yong Mann Beyun

Seong Hoon Kang

In Kyu Park

Jong Hyun Chae

Won Ho Lee

Jeong Seok Kim

Dong Il Lee

In Yong Jeong

Yong Jin Choe

Seok Chang Kang

Yong Suk Choi

Yeong Dae Kim

Dae Chul Jung

Ji Sun Im

Young Seak Lee

Tae Moon Park

Hyun Jik Yi

Ho Joon Shin

Yong Hee Jang

Jang Ku Lee

Saeun Park

Inseop Kim

Dong Ha Lee

Hong Soo Joo

Yeonuk Choo

The present invention relates to a method of manufacturing a diester-based compound, and, more particularly, to a method of manufacturing a diester-based compound, which is performed using a continuous process including a reaction part in which a total of n reaction units spanning from a first reaction unit to an nth reaction unit are connected in series, wherein each of the reaction units includes a reactor, and the method includes: supplying a feed stream including a dicarboxylic acid and an alcohol into the first reactor; esterifying the feed stream to prepare a reaction product; and supplying a lower discharge stream including the reaction product into the reactor of the rear reaction unit. In this case, a conversion rate of the esterification reaction in the first reactor is controlled in a range of 50 to 80%.

Method of manufacturing diester-based compound

Provided is a method for preparing synthesis gas, and more particularly, a method for preparing synthesis gas including: supplying a cracked gas stream discharged from a cracking furnace of a naphtha cracking center (NCC) process to a gasoline fractionator, separating a side discharge stream from the gasoline fractionator using a first stripper, and separating a lower discharge stream from the gasoline fractionator using a second stripper, wherein a mixed oil stream of a PGO stream and a PFO stream formed by controlling a flow rate of each stream are used.

Method for preparing synthesis gas

An esterification reaction apparatus and an esterification reaction method, the esterification reaction apparatus comprising a reaction tank having an accommodation part, in which a raw material containing carboxylic acid and alcohol is accommodated, a heating unit configured to individually heat partition regions that are partitioned into N regions in a vertical direction of the accommodation part, and a controller configured to control the heating unit so that only the partition regions in which a liquid is accommodated among the N partition regions are heated, thereby performing an esterification reaction of the raw material.

Apparatus and method for esterification reaction

Provided is a heat integration separation system including a first column, a second column, a compressor, a first heat exchanger and a second heat exchanger, wherein an upper discharge stream of the first column passes through the compressor to be compressed and then heat-exchanged with a lower discharge stream of the second column in the second heat exchanger, wherein an upper discharge stream of the second column is heat-exchanged with a lower discharge stream of the first column in the first heat exchanger, and wherein the heat integration separation system satisfies Equation 1 (refer to the specification).

Heat integration separation system

A method of preparing isopropyl alcohol, where a propylene monomer and water are reacted in a reactor to produce a reaction product including isopropyl alcohol, and the reaction product stream is separated into unreacted propylene monomer and isopropyl alcohol with high purity using an absorption column, a first gas purification column, a second gas purification column, and an inert gas removal column.

Method for preparing isopropyl alcohol

Provided is a method for preparing synthesis gas, and more particularly, a method for preparing synthesis gas including: supplying a pyrolysis fuel oil (PFO) stream including a PFO and a pyrolysis gas oil (PGO) stream including a PGO discharged from a naphtha cracking center (NCC) process to a distillation tower as a feed stream (S); and supplying a lower discharge stream from the distillation tower to a combustion chamber for a gasification process to obtain synthesis gas (S), wherein the PGO stream is supplied to an upper end of the distillation tower and the PFO stream is supplied to a lower end of the distillation tower.

A neutralization/water separation tank for an esterified product including: a neutralization part in which a crude product mixture containing alcohol and an ester compound, a neutralizing agent, and water are put to produce a neutralized mixture; a water separation part which divides the neutralized mixture into a floating layer and an aqueous layer; a first partition wall which extends upward from a bottom surface to provide an upper passage and by which the neutralization part and the water separation part are partitioned; and a second partition wall which extends downward from a ceiling to provide a lower passage, wherein the water separation part includes: a first water separation part into which the neutralized mixture is introduced from the neutralization part through the upper passage; and a second water separation part into which the neutralized mixture is introduced from the first water separation part through the lower passage, wherein the first water separation part and the second water separation part are partitioned by the second partition wall.

Neutralization/water separation tank for esterified product and neutralization/water separation method for esterified product

The present disclosure provides a multi-component mixture separation system including a distillation column including a first section and a second section separated by a partition wall, and a phase separator receiving a lower discharge stream of the second section and separating the stream into an aqueous phase and an oil phase, and refluxing a portion of the separated aqueous phase or oil phase to the first section, in which the first section includes a chimney tray provided on an upper portion, and the first section is fed with a feed stream containing three or more components to separate high-boiling point component to a lower portion, and a gaseous component moves to the second section.

Multi-component mixture separation system

The present disclosure relates to a diester-based material production unit including a reaction device in which an esterification reaction of dicarboxylic acid and a primary alcohol is performed, a column in which the gas-liquid separation of the primary alcohol and the water introduced is performed, a heat exchanger installed on a gas phase line of the column to remove heat of the gas phase line, a flash drum in which separation of a liquid phase and a gas phase is performed in the mixture stream including the primary alcohol and the water, a condenser installed on the flash drum upper line, and a layer separator in which the layer separation of a mixture of a liquefied primary alcohol and water into an organic layer and an aqueous layer is performed, wherein one or more lines through which recirculated primary alcohol from the flash drum and the layer separator flows are connected to an upper portion of the column. According to the present invention, a coolant usage amount can be reduced and a rheological problem can be eliminated since a liquid phase and a gas phase coexist in a pipe.

Diester-based material production unit and diester-based material production system including the same

A diester-based material can be prepared continuously including a reaction part in which a total of n reaction units from a first reaction unit to an nth reaction unit are connected in series, the reaction unit including a reactor which esterifies dicarboxylic acid and alcohol, includes: esterifying dicarboxylic acid and alcohol in a reactor of the first reaction unit to produce a reaction product, and supplying a lower discharge stream including the reaction product to a reaction unit at a rear end, wherein an operating pressure of the reactor of the first reaction unit is 0.4 kg/cmG to 5.5 kg/cmG, an operating pressure is reduced from a reactor of any one reaction unit of reaction units from a second reaction unit to the nth reaction unit, and an operating temperature is increased from the reactor of the first reaction unit to the reactor of the nth reaction unit.

Method of preparing diester-based material

A method of removing a metal substance in a petrochemical product including: supplying a petrochemical product stream to an incoming tank through a supply pipe, circulating the petrochemical product stream through an incoming tank circulation pipe, and removing a metal substance included in the petrochemical product stream using a magnetic filter; transporting the petrochemical product stream to an outgoing tank through an incoming tank discharge pipe which is branched from the incoming tank circulation pipe and connected to an outgoing tank; circulating the petrochemical product stream through an outgoing tank circulation pipe provided in the outgoing tank and removing the metal substance included in the petrochemical product stream using a magnetic filter; and transporting the petrochemical product stream to a branch pipe branched from the outgoing tank circulation pipe to remove the metal substance using an ion exchange resin filter.

Method of removing metal substance in petrochemical product

The present disclosure relates to a method for continuously producing a dicarboxylate-based composition and a production system therefor, the method improving a production yield by optimizing process variables of each reactor of a reaction unit in which a plurality of reactors are connected in series.

System and method for producing diester-based composition

Provided is a method for preparing synthesis gas and aromatic hydrocarbons, and more particularly, a method for preparing synthesis gas and aromatic hydrocarbons including: supplying a pyrolysis fuel oil (PFO) stream containing PFO and a pyrolysis gas oil (PGO) stream containing PGO to a distillation tower as a feed stream (S), the PFO stream and the PGO stream being discharged from a naphtha cracking center (NCC) process; and supplying a lower discharge stream from the distillation tower to a combustion chamber for a gasification process and supplying an upper discharge stream from the distillation tower to an SM/BTX preparation process (S).

Method for preparing synthesis gas and aromatic hydrocarbon

The present disclosure relates to a preparation system and a preparation method of a diester-based composition. A first alcohol which is a reaction raw material is added to waste water as an extracting agent, and layer separation is performed to separate a second alcohol which is another reaction raw material in the waste water. Accordingly, the amount of alcohol discharged as waste water can be reduced, and an eco-friendly process operation is possible. In addition, it is economical and efficiency to use the alcohol separated again as a reaction raw material.

System and method for manufacturing diester-based composition

An apparatus for producing aromatic hydrocarbons including: a C6 separation column; a C7 separation column; a first gasoline hydrogenation unit; a C8 separation column; an extractive distillation column; a hydrodealkylation reaction unit; and a second gasoline hydrogenation unit.

Apparatus for producing aromatic hydrocarbons

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Daejeon, South Korea

Sung Kyu Lee